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arXiv:1203.6621 · Physical Review Letters

Correlation Functions in SU(2)-Invariant Resonating-Valence-Bond Spin Liquids on Nonbipartite Lattices

Julia Wildeboer, Alexander Seidel

Published Oct 5, 2012• 23 citations
arXivHTMLPDF

Abstract

We introduce a Monte Carlo scheme based on sampling of Pfaffians to investigate Anderson's resonating-valence-bond (RVB) spin liquid wave function on the kagome and the triangular lattice. This eliminates a sign problem that prevents utilization of the valence bond basis in Monte Carlo studies for nonbipartite lattices. Studying lattice sizes of up to 600 sites, we calculate singlet-singlet and spin-spin correlations and demonstrate how the lattice symmetry is restored within each topological sector as the system size is increased. Our findings are consistent with the expectation that the nearest-neighbor RVB states describe a topological spin liquid on these nonbipartite lattices.

DOI
10.1103/physrevlett.109.147208

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We introduce a Monte Carlo scheme based on sampling of Pfaffians to investigate Anderson's resonating-valence-bond (RVB) spin liquid wave function on the kagome and the triangular lattice. This eliminates a sign problem that prevents utilization of the valence bond basis in Monte Carlo studies for nonbipartite lattices. Studying lattice sizes of up to 600 sites, we calculate singlet-singlet and spin-spin correlations and demonstrate how the lattice symmetry is restored within each topological sector as the system size is increased. Our findings are consistent with the expectation that the nearest-neighbor RVB states describe a topological spin liquid on these nonbipartite lattices.
On the triangular and kagome lattices, short-ranged resonating valence-bond wave functions can be sampled without the sign problem using a recently developed Pfaffian Monte Carlo scheme. In this Rapid Communication, we study the Renyi entanglement entropy in these wave functions using a replica-trick method. Using various spatial bipartitions, including the Levin-Wen construction, our finite-size scaled Renyi entropy gives a topological contribution consistent with $\ensuremath{\gamma}=ln(2)$, as expected for a gapped Z2{\mathbb{Z}}_{2}Z2​ quantum spin liquid. We prove that the mutual statistics is consistent with the toric code anyon model and rule out any other quasiparticle statistics such as the double semion model.
We use Monte Carlo simulations to study properties of Anderson's resonating-valence-bond (RVB) spin-liquid state on the square lattice (i.e., the equal superposition of all pairing of spins into nearest-neighbor singlet pairs) and compare with the classical dimer model (CDM). The latter system also corresponds to the ground state of the Rokhsar-Kivelson quantum dimer model at its critical point. We find that, although spin-spin correlations decay exponentially in the RVB, four-spin valence-bond-solid correlations are critical, qualitatively like the well-known dimer-dimer correlations of the CDM, but decaying more slowly (as $1/{r}^{\ensuremath{\alpha}}$ with $\ensuremath{\alpha}\ensuremath{\approx}1.20$, compared with $\ensuremath{\alpha}=2$ for the CDM). We also compute the distribution of monomer (defect) pair separations, which decay by a larger exponent in the RVB than in the CDM. We further study both models in their different winding-number sectors and evaluate the relative weights of different sectors. Like the CDM, all the observed RVB behaviors can be understood in the framework of a mapping to a ``height'' model characterized by a gradient-squared stiffness constant KKK. Four independent measurements consistently show a value ${K}_{\mathrm{RVB}}\ensuremath{\approx}1.6{K}_{\mathrm{CDM}}$, with the same kinds of numerical evaluations of KCDM{K}_{\mathrm{CDM}}KCDM​ giving results in agreement with the rigorously known value ${K}_{\mathrm{CDM}}=\ensuremath{\pi}/16$. The background of a nonzero winding-number gradient W/LW/LW/L introduces spatial anisotropies and an increase in the effective KKK, both of which can be understood as a consequence of anharmonic terms in the height-model free energy, which are of relevance to the recently proposed scenario of ``Cantor deconfinement'' in extended quantum dimer models. In addition to the standard case of short bonds only, we also studied ensembles in which fourth-neighbor (bipartite) bonds are allowed at a density controlled by a tunable fugacity, resulting (as expected) in a smooth reduction of KKK.
Anderson's idea of a (short-ranged) resonating valence bond (RVB) spin liquid has been the first ever proposal of what we now call a topologically ordered phase. Since then, a wealth of exactly solvable lattice models have been constructed that have topologically ordered ground states. For a long time, however, it has been difficult to realize Anderson's original vision in such solvable models, according to which the ground state has an unbroken SU(2) spin rotational symmetry and is dominated by fluctuation of singlet bonds. The kagome lattice is the simplest lattice geometry for which parent Hamiltonians stabilizing a prototypical spin-1$/$2 short-ranged RVB wave function has been constructed and strong evidence has been given that this state belongs to a topological phase. The uniqueness of the desired RVB-type ground states has, however, not been rigorously proven for the simplest possible such Hamiltonian, which acts on 12 spins at a time. Rather, this uniqueness has been demonstrated for a longer ranged (19-site) variant of this Hamiltonian by Schuch et al., via making contact with powerful results for projected entangled-pair states. In this paper, we extend this result to the 12-site Hamiltonian. Our result is based on numerical studies on finite clusters, for which we demonstrate a ``ground state intersection property'' with implications for arbitrary system size. We also review the relations between various constructions schemes for RVB parent Hamiltonians found in the literature.
We construct a short-range resonating-valence-bond (RVB) state on the ruby lattice, using projected entangled-pair states with bond dimension D=3D=3D=3. By introducing nonlocal moves to the dimer patterns on the torus, we distinguish four distinct sectors in the space of dimer coverings, which is a signature of the topological nature of the RVB wave function. Furthermore, by calculating the reduced density matrix of a bipartition of the RVB state on an infinite cylinder and exploring its entanglement entropy, we confirm the topological nature of the RVB wave function by obtaining a nonzero topological contribution, $\ensuremath{\gamma}=\ensuremath{-}\mathrm{ln}\phantom{\rule{4pt}{0ex}}2$, consistent with that of a Z2{\mathbb{Z}}_{2}Z2​ topological quantum spin liquid. We also calculate the ground-state energy of the spin-12\frac{1}{2}21​ antiferromagnetic Heisenberg model on the ruby lattice and compare it with the RVB energy. Finally, we construct a quantum dimer model for the ruby lattice and discuss it as a possible parent Hamiltonian for the RVB wave function.
We investigate the arguably simplest SU(2)SU(2)SU(2)-invariant wave functions capable of accounting for spin-liquid behavior, expressed in terms of nearest-neighbor valence-bond states on the square lattice and characterized by different topological invariants. While such wave functions are known to exhibit short-range spin correlations, we perform Monte Carlo simulations and show that four-point correlations decay algebraically with an exponent 1.16(4). This is reminiscent of the classical dimer problem, albeit with a slower decay. Furthermore, these correlators are found to be spatially modulated according to a wave vector related to the topological invariants. We conclude that a recently proposed spin Hamiltonian that stabilizes the here considered wave function(s) as its (degenerate) ground state(s) should exhibit gapped spin and gapless nonmagnetic excitations.
Gapped Z2{\mathbb{Z}}_{2}Z2​ spin liquids have been proposed as candidates for the ground state of the S=1/2S=1/2S=1/2 quantum antiferromagnet on the kagome lattice. We extend the use of projected entangled pair states to construct (on the cylinder) resonating valence bond (RVB) states including both nearest-neighbor and next-nearest-neighbor singlet bonds. Our ansatz---dubbed ``simplex spin liquid''---allows for an asymmetry between the two types of triangles (of order 22%--3%2 in the energy density after optimization) leading to the breaking of inversion symmetry. We show that the topological Z2{\mathbb{Z}}_{2}Z2​ structure is still preserved and, by considering the presence or the absence of spinon and vison lines along an infinite cylinder, we explicitly construct four orthogonal RVB minimally entangled states. The spinon and vison coherence lengths are extracted from a finite size scaling with regard to the cylinder perimeter of the energy splittings of the four sectors and are found to be of the order of the lattice spacing. The entanglement spectrum of a partitioned (infinite) cylinder is found to be gapless, suggesting the occurrence, on a cylinder with real open boundaries, of gapless edge modes formally similar to Luttinger liquid (nonchiral) spin and charge modes. When inversion symmetry is spontaneously broken, the RVB spin liquid exhibits an extra Ising degeneracy, which might have been observed in recent exact diagonalization studies.