We discuss strategies for quantum enhanced estimation of atomic transition frequencies with ions stored in Paul traps or neutral atoms trapped in optical lattices. We show that only marginal quantum improvements can be achieved using standard Ramsey interferometry in the presence of collective dephasing, which is the major source of noise in relevant experimental setups. We therefore analyze methods based on decoherence free subspaces and prove that quantum enhancement can readily be achieved even in the case of significantly imperfect state preparation and faulty detections.
We discuss strategies for quantum enhanced estimation of atomic transition frequencies with ions stored in Paul traps or neutral atoms trapped in optical lattices. We show that only marginal quantum improvements can be achieved using standard Ramsey interferometry in the presence of collective dephasing, which is the major source of noise in relevant experimental setups. We therefore analyze methods based on decoherence free subspaces and prove that quantum enhancement can readily be achieved even in the case of significantly imperfect state preparation and faulty detections.
We quantify the impact of spatiotemporally correlated Gaussian quantum noise on frequency estimation by Ramsey interferometry. While correlations in a classical noise environment can be exploited to reduce uncertainty relative to the uncorrelated case, we show that quantum noise environments with frequency asymmetric spectra generally introduce additional sources of uncertainty due to uncontrolled entanglement of the sensing system mediated by the bath. For the representative case of collective noise from bosonic sources, and experimentally relevant collective spin observables, we find that the uncertainty can increase exponentially with the number of probes. As a concrete application, we show that correlated quantum noise due to a lattice vibrational mode can preclude superclassical precision scaling in current amplitude sensing experiments with trapped ions.
Dephasing noise is a ubiquitous source of decoherence in current atomic sensors. We address the problem of entanglement-assisted frequency estimation subject to classical dephasing noise with full spatial correlations (collective) and arbitrary temporal correlations. Our contributions are threefold. (i) We derive rigorous, state-independent bounds on the achievable estimation precision, showing how they are entirely determined by the short-time behavior of the decoherence function. For temporally uncorrelated (Markovian) dephasing, precision is limited by a probe-independent constant. For temporally correlated stationary noise, the bound approaches the noiseless limit for classical states, precluding any asymptotic quantum advantage. (ii) We show that these scaling bounds are tight, by constructing generalized Ramsey protocols that saturate them. These optimal protocols use squeezing at the input and before readout, both of which are available in state-of-the-art atomic interferometers. Implementing a perfect-echo protocol, which reaches Heisenberg scaling in the absence of noise, remains optimal in this noisy setting, irrespective of the noise temporal correlations. (iii) We prove that arbitrary collective open-loop control cannot lift the no-go for super-classical precision scaling under either Markovian or colored stationary noise, highlighting the detrimental nature of full spatial correlations. In the latter case, temporal correlations may nonetheless enable constant-factor improvements over the standard quantum limit, which may still be important in practical metrological scenarios.
I analyze a metrological strategy for improving the precision of frequency estimation via Ramsey interferometry with strings of atoms in the presence of correlated dephasing. This strategy does not employ entangled states but rather a product state which evolves into a stationary state under the influence of correlated dephasing. It is shown that by using this state an improvement in precision compared to standard Ramsey interferometry can be gained. This improvement is not an improvement in scaling; i.e., the estimation precision has the same scaling with the number of atoms as the standard quantum limit but gains an improvement proportional to the free evolution time in the Ramsey interferometer. Since a stationary state is used, this evolution time can be substantially larger than in standard Ramsey interferometry which is limited by the coherence time of the atoms.
This thesis describes new results on the entanglement of atomic spins in Ramsey interferometry, optical atomic clocks and trapped ions. It is divided into three parts: First, we investigate improvements to conventional Ramsey interferometry with entanglement and adding only rotations of the collective spin to adjust the signal and measurement directions. The geometric degrees of freedom, connected to the rotations, are analytically optimized for a large class of generalized Ramsey protocols to allow efficient optimization of all parameters. Besides a unification of existing approaches, the main result is that there is only one new protocol, where a previously unused double inversion is applied. Studies of the local sensitivity show that this protocol reaches the fundamental quantum Fisher information limit and is yet robust against errors during preparation and measurement. In the second section we investigate the conditions under which optical atomic clocks exhibit increased long-term stability when applying weakly entangled, spin squeezed states. We discuss the common case of an atomic clock with a single ensemble, typical Brownian frequency noise and finite dead time. Theoretical modelling of the servo loop allows quantitative predictions of the optimal stability for given values of dead time and laser noise, in very good agreement with numerical simulations of the closed feedback loop. The main result is that, even with the current most stable lasers, the clock stability can only be improved for ensembles below a critical atom number of about one thousand in optical Sr lattice clocks. Even with a future improvement of the laser performance by one order of magnitude, the critical atom number still remains below 100,000. In contrast, clocks based on smaller, non-scalable ensembles, such as ion clocks, can already benefit from squeezed states with current clock lasers. Thus the last section considers the robust generation of entanglement in ion traps. An error budget including relevant experimental error sources is calculated for state-of-the-art quantum gates, driven by oscillating microwave gradients in surface traps. Amplitude modulation of the driving fields is shown to efficiently counteract the current limitations from motional mode instability. The predicted increase of the gate quality was demonstrated by the group of C. Ospelkaus at PTB Braunschweig, who measured gates with errors as low as ~ 10^(-3). In a similar approach, interactions between spin and motion can also be generated by combining oscillating rf-fields with a static magnetic field gradient. Penning traps designed for precision spectroscopy already feature large magnetic field gradients at the edge of a magnetic bottle configuration. We present parameters and conditions under which laser-free coupling of spin and quantized motion for (anti-)protons is possible at these points, in a step towards quantum logic spectroscopy for (anti-)protons.
Optical atomic clocks have been rapidly developing in recent decades, resulting in major improvements in both precision and accuracy. As a result, they have become instrumental in multiple areas of applied and fundamental research. Despite all atomic frequency references having more than two energy-levels, the commonly used model for evaluating their ultimate limits assumes a two-level atom. This leads to frequency interrogation protocols and theoretical stability bounds that are suboptimal for a true multi-level atom. The most fundamental stability bound assumes two noise sources - quantum projection noise and spontaneous decay from the excited state. In this work, we analyze a model that includes these noise types and is generalized beyond the two-level assumption, where spontaneous decay can branch to more than a single ground state. This model allows for detection and exclusion of atomic frequency interrogations in which the atom decayed, leading to a frequency stability improvement of up to ≈4.5 dB compared with the two-level model. Furthermore, we identify an even greater stability enhancement of ≈5.4 dB for frequency comparisons between atoms in an odd parity Bell state. These enhancements are particularly relevant for the numerous trapped-ion optical clock species that operate close to lifetime-limited stability. We calculate new stability limits for those cases and provide a detailed experimental protocol for frequency interrogation with an 27Al+ optical ion clock.
We advocate a Bayesian approach to optimal quantum frequency estimation—an important issue for future quantum enhanced atomic clock operation. The approach provides a clear insight into the interplay between decoherence and the extent of prior knowledge in determining the optimal interrogation times and optimal estimation strategies. We propose a general framework capable of describing local oscillator noise as well as additional collective atomic dephasing effects. For a Gaussian noise, the average Bayesian cost can be expressed using the quantum Fisher information. Thus we establish a direct link between the two, often competing, approaches to quantum estimation theory.