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arXiv:1008.0788 · Physical Review A

Number-conserving master equation theory for a dilute Bose-Einstein condensate

Alexej Schelle, Thomas Wellens, Dominique Delande, Andreas Buchleitner

Published Jan 24, 2011• 6 citations
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Abstract

We describe the transition of $N$ weakly interacting atoms into a Bose-Einstein condensate within a number-conserving quantum master equation theory. Based on the separation of time scales for condensate formation and noncondensate thermalization, we derive a master equation for the condensate subsystem in the presence of the noncondensate environment under the inclusion of all two-body interaction processes. We numerically monitor the condensate particle number distribution during condensate formation, and derive a condition under which the unique equilibrium steady state of a dilute, weakly interacting Bose-Einstein condensate is given by a Gibbs-Boltzmann thermal state of $N$ noninteracting atoms.

DOI
10.1103/physreva.83.013615

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We describe the transition of NNN weakly interacting atoms into a Bose-Einstein condensate within a number-conserving quantum master equation theory. Based on the separation of time scales for condensate formation and noncondensate thermalization, we derive a master equation for the condensate subsystem in the presence of the noncondensate environment under the inclusion of all two-body interaction processes. We numerically monitor the condensate particle number distribution during condensate formation, and derive a condition under which the unique equilibrium steady state of a dilute, weakly interacting Bose-Einstein condensate is given by a Gibbs-Boltzmann thermal state of NNN noninteracting atoms.
The formation process of a Bose-Einstein condensate in a trap is described using a master equation based on quantum kinetic theory, which can be well approximated by a description using only the condensate mode in interaction with a thermalized bath of noncondensate atoms. A rate equation of the form $\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{n}{\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}2W}^{+}(n)[\left({1\ensuremath{-}e}^{{{\ensuremath{\mu}}_{n}\ensuremath{-}\ensuremath{\mu}}/\mathrm{kT}}\right)n+1]$ is derived, in which the difference between the condensate chemical potential ${\ensuremath{\mu}}_{n}$ and the bath chemical potential $\ensuremath{\mu}$ gives the essential behavior. Solutions of this equation give a characteristic latency period for condensate formation and appear to be consistent with the observed behavior of both rubidium and sodium condensate formation.
We describe a number-conserving approach to the dynamics of Bose-Einstein condensed dilute atomic gases. This builds upon the works of Gardiner [Phys. Rev. A 56, 1414 (1997)] and Castin and Dum [Phys. Rev. A 57, 3008 (1998)]. We consider what is effectively an expansion in powers of the ratio of noncondensate to condensate particle numbers, rather than inverse powers of the total number of particles. This requires the number of condensate particles to be a majority, but not necessarily almost equal to the total number of particles in the system. We argue that a second-order treatment of the relevant dynamical equations of motion is the minimum order necessary to provide consistent coupled condensate and noncondensate number dynamics for a finite total number of particles, and show that such a second-order treatment is provided by a suitably generalized Gross-Pitaevskii equation, coupled to the Castin-Dum number-conserving formulation of the Bogoliubov--de Gennes equations. The necessary equations of motion can be generated from an approximate third-order Hamiltonian, which effectively reduces to second order in the steady state. Such a treatment as described here is suitable for dynamics occurring at finite temperature, where there is a significant noncondensate fraction from the outset, or dynamics leading to dynamical instabilities, where depletion of the condensate can also lead to a significant noncondensate fraction, even if the noncondensate fraction is initially negligible.
We develop the number-conserving approach, which has previously been used in a single-component Bose-Einstein condensed dilute atomic gas, to describe consistent coupled condensate and noncondensate number dynamics, to an nnn-component condensate. The resulting system of equations is comprised, for each component, of a generalized Gross-Pitaevskii equation coupled to modified Bogoliubov--de Gennes equations. Lower order approximations yield general formulations for multicomponent Gross-Pitaevskii equations, and systems of multicomponent Gross-Pitaevskii equations coupled to multicomponent modified number-conserving Bogoliubov--de Gennes equations. The analysis is left general, such that, in the nnn-component condensate, there may or may not be mutually coherent components. An expansion in powers of the ratio of noncondensate-to-condensate particle numbers for each coherent set is used to derive the self-consistent, second-order, dynamical equations of motion. The advantage of the analysis developed in this article is in its applications to dynamical instabilities that appear when two (or more) components are in conflict and where a significant noncondensed fraction of atoms is expected to appear.
The evolution equation of a weakly interacting boson system is derived. The model includes the interaction between the atoms in the condensate and the surrounding gas of noncondensed particles. The Bogoliubov transformation is introduced in a full quantum context and the scattering kernel between dressed particles and the condensate phase is obtained. The final system is expressed by the Boltzmann evolution equation for noncondensed particles coupled to the Gross-Pitaevskii equation for the condensate. We consider an out-of-equilibrium situation that induces a fast production of condensed particles. We apply our model to study the condensation dynamics of positronium atoms by evaporation.
A quantum kinetic master equation (QKME) for bosonic atoms is formulated. It is a quantum stochastic equation for the kinetics of a dilute quantum Bose gas, and describes the behavior and formation of Bose condensation. The key assumption in deriving the QKME is a Markov approximation for the atomic collision terms. In the present paper the basic structure of the theory is developed, and approximations are stated and justified to delineate the region of validity of the theory. Limiting cases of the QKME include the quantum Boltzmann master equation and the Uehling-Uhlenbeck equation, as well as an equation analogous to the Gross-Pitaevskii equation.