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arXiv:1007.4536

Thermodynamics of classical frustrated spin chain at the ferromagnet-helimagnet transition point

Д. В. Дмитриев, V. Ya. Krivnov

Published Jul 26, 2010• 0 citations
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Abstract

Low-temperature thermodynamics of the classical frustrated ferromagnetic spin chain is studied. Using transfer-matrix method we found the behavior of the correlation function and zero-field susceptibility at the ferromagnetic-helical transition point. It is shown that the critical exponent for the susceptibility is changed from 2 to 4/3 at the transition point.

DOI
10.48550/arxiv.1007.4536

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Low-temperature thermodynamics of the classical frustrated ferromagnetic spin chain is studied. Using transfer-matrix method we found the behavior of the correlation function and zero-field susceptibility at the ferromagnetic-helical transition point. It is shown that the critical exponent for the susceptibility is changed from 2 to 4/3 at the transition point.
Low-temperature magnetization curves of the classical frustrated ferromagnetic chain in the external magnetic field near the transition point between the ferromagnetic and the helical phases is studied. It is shown that the calculation of the partition function in the scaling limit reduces to the solution of the Schr\"odinger equation of the special form for the quantum particle. It is proposed that the magnetization of the classical model in the ferromagnetic part of the phase diagram including the transition point defines the universal scaling function which is valid for the quantum model as well. Explicit analytical formulas for the magnetization are given in the limiting cases of low and high magnetic fields. The influence of the easy-axis anisotropy on the magnetic properties of the model is studied. It is shown that even small anisotropy essentially changes the behavior of the susceptibility in the vicinity of the transition point.
We studied the thermodynamics of the one-dimensional J 1 - J 2 spin-1/2 Heisenberg chain for ferromagnetic nearest-neighbor bonds J 1 < 0 and frustrating antiferromagnetic next- nearest-neighbor bonds J 2 > 0 using full diagonalization of finite rings and a second-order Green-function formalism. Thereby we focus on J 2 < | J 1 |/4 where the ground state is still ferromagnetic, but the frustration influences the thermodynamic properties. We found that their critical indices are not changed by J 2 . The analysis of the low-temperature behavior of the susceptibility χ leads to the conclusion that this behavior changes from χ ∝ T -2 at J 2 < | J 1 |/4 to χ ∝ T -3/2 at the quantum-critical point J 2 = | J 1 |/4. Another effect of the frustration is the appearance of an extra low- T maximum in the specific heat C v ( T ) for J 2 & | J 1 |/8, indicating its strong influence on the low-energy spectrum.
Abstract. We studied the thermodynamics of the one-dimensional J1-J2 spin-1/2 Heisenberg chain for ferromagnetic nearest-neighbor bonds J1 < 0 and frustrating antiferromagnetic nextnearest-neighbor bonds J2> 0 using full diagonalization of finite rings and a second-order Green-function formalism. Thereby we focus on J2 < |J1|/4 where the ground state is still ferromagnetic, but the frustration influences the thermodynamic properties. We found that their critical indices are not changed by J2. The analysis of the low-temperature behavior of the susceptibility χ leads to the conclusion that this behavior changes from χ ∝ T −2 at J2 < |J1|/4 to χ ∝ T −3/2 at the quantum-critical point J2 = |J1|/4. Another effect of the frustration is the appearance of an extra low-T maximum in the specific heat Cv(T) for J2 � |J1|/8, indicating its strong influence on the low-energy spectrum. Introduction: In low-dimensional frustrated quantum magnets thermal and quantum fluctuations strongly influence the low-temperature physics [1,2]. Special attention has been paid to one-dimensional (1D) J1-J2 quantum Heisenberg magnets, see Ref. [3] and references therein. Recent experimental studies have shown that edge-shared chain cuprates, such as LiVCuO4, Li(Na)Cu2O2, Li2ZrCuO4, and Li2CuO2 [4–13], represent a family of quantum magnets for
We calculate the thermodynamic quantities (correlation functions ⟨S0Sn⟩⟨{\mathbf{S}}_{0}{\mathbf{S}}_{n}⟩⟨S0​Sn​⟩, correlation length $\ensuremath{\xi}$, spin susceptibility $\ensuremath{\chi}$, and specific heat CV{C}_{V}CV​) of the frustrated one-dimensional spin-half ${J}_{1}\text{\ensuremath{-}}{J}_{2}$ Heisenberg ferromagnet, i.e., for J2<0.25∣J1∣{J}_{2}<0.25|{J}_{1}|J2​<0.25∣J1​∣, using a rotation-invariant Green's-function formalism and full diagonalization of finite lattices. We find that the critical indices are not changed by J2{J}_{2}J2​, i.e., $\ensuremath{\chi}={y}_{0}{T}^{\ensuremath{-}2}$ and $\ensuremath{\xi}={x}_{0}{T}^{\ensuremath{-}1}$ at $T\ensuremath{\rightarrow}0$. However, the coefficients y0{y}_{0}y0​ and x0{x}_{0}x0​ linearly decrease with increasing J2{J}_{2}J2​ according to the relations ${y}_{0}=(1\ensuremath{-}4{J}_{2}/|{J}_{1}|)/24$ and ${x}_{0}=(1\ensuremath{-}4{J}_{2}/|{J}_{1}|)/4$, i.e., both coefficients vanish at J2=0.25∣J1∣{J}_{2}=0.25|{J}_{1}|J2​=0.25∣J1​∣ indicating the zero-temperature phase transition that is accompanied by a change in the low-temperature behavior of $\ensuremath{\chi}$ $(\ensuremath{\xi})$ from $\ensuremath{\chi}\ensuremath{\propto}{T}^{\ensuremath{-}2}$ $(\ensuremath{\xi}\ensuremath{\propto}{T}^{\ensuremath{-}1})$ at J2<0.25∣J1∣{J}_{2}<0.25|{J}_{1}|J2​<0.25∣J1​∣ to $\ensuremath{\chi}\ensuremath{\propto}{T}^{\ensuremath{-}3/2}$ $(\ensuremath{\xi}\ensuremath{\propto}{T}^{\ensuremath{-}1/2})$ at J2=0.25∣J1∣{J}_{2}=0.25|{J}_{1}|J2​=0.25∣J1​∣. In addition, we detect the existence of an additional low-temperature maximum in the specific heat when approaching the critical point at J2=0.25∣J1∣{J}_{2}=0.25|{J}_{1}|J2​=0.25∣J1​∣.
The properties of the ferromagnetic frustrated spin-SSS one-dimensional Heisenberg model in the vicinity of the transition point from the ferromagnetic to the singlet ground state are studied using the perturbation theory (PT) in small parameter characterizing the deviation from the transition point. The critical exponents defining the behavior of the ground-state energy and spin correlation functions are determined using scaling estimates of infrared divergencies of the PT. It is shown that the quantum fluctuations for s=1∕2s=1∕2s=1∕2 are sufficiently strong to change the classical critical exponents, while for spin systems with $s\ensuremath{\geqslant}1$ the critical exponents remain classical. The dimerization in the singlet phase near the transition point is discussed.
The thermodynamic quantities (spin-spin correlation functions $\ensuremath{\langle}{\mathbf{S}}_{0}{\mathbf{S}}_{n}\ensuremath{\rangle}$, correlation length $\ensuremath{\xi}$, spin susceptibility $\ensuremath{\chi}$, and specific heat CV{C}_{V}CV​) of the frustrated one-dimensional J1{J}_{1}J1​-J2{J}_{2}J2​ Heisenberg ferromagnet with arbitrary spin quantum number SSS below the quantum critical point, i.e., for J2<∣J1∣/4{J}_{2}<|{J}_{1}|/4J2​<∣J1​∣/4, are calculated using a rotation-invariant Green-function formalism and full diagonalization as well as a finite-temperature Lanczos technique for finite chains of up to N=20N=20N=20 sites. The low-temperature behavior of the susceptibility $\ensuremath{\chi}$ and the correlation length $\ensuremath{\xi}$ are well described by $\ensuremath{\chi}=\frac{2}{3}{S}^{4}\left(|{J}_{1}|\ensuremath{-}4{J}_{2}\right){T}^{\ensuremath{-}2}+A{S}^{5/2}{\left(|{J}_{1}|\ensuremath{-}4{J}_{2}\right)}^{1/2}{T}^{\ensuremath{-}3/2}$ and $\ensuremath{\xi}={S}^{2}\left(|{J}_{1}|\ensuremath{-}4{J}_{2}\right){T}^{\ensuremath{-}1}+B{S}^{1/2}{\left(|{J}_{1}|\ensuremath{-}4{J}_{2}\right)}^{1/2}{T}^{\ensuremath{-}1/2}$ with $A\ensuremath{\approx}1.1\ensuremath{\cdots}1.2$ and $B\ensuremath{\approx}0.84\ensuremath{\cdots}0.89$. The vanishing of the factors in front of the temperature at J2=∣J1∣/4{J}_{2}=|{J}_{1}|/4J2​=∣J1​∣/4 indicates a change of the critical behavior of $\ensuremath{\chi}$ and $\ensuremath{\xi}$ at $T\ensuremath{\rightarrow}0$. The specific heat may exhibit an additional frustration-induced low-temperature maximum when approaching the quantum critical point. Such a maximum appears for S=1/2S=1/2S=1/2 and S=1S=1S=1, but was not found for S>1S>1S>1.