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arXiv:1007.1789 · Physical Review A

Time-averaged quantum dynamics and the validity of the effective Hamiltonian model

Omar Gamel, Daniel F. V. James

Published Nov 8, 2010• 107 citations
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Abstract

We develop a technique for finding the dynamical evolution in time of an averaged density matrix. The result is an equation of evolution that includes an effective Hamiltonian, as well as decoherence terms in Lindblad form. Applying the general equation to harmonic Hamiltonians, we confirm a previous formula for the effective Hamiltonian together with a additional decoherence term which should, in general, be included and whose vanishing provides the criteria for validity of the effective Hamiltonian approach. Finally, we apply the theory to examples of the ac Stark shift and three-level Raman transitions, recovering a decoherence effect in the latter.

DOI
10.1103/physreva.82.052106

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•Jan 9, 2014•0 citations
We develop a technique for finding the dynamical evolution in time of an averaged density matrix. The result is an equation of evolution that includes an effective Hamiltonian, as well as decoherence terms in Lindblad form. Applying the general equation to harmonic Hamiltonians, we confirm a previous formula for the effective Hamiltonian together with a additional decoherence term which should, in general, be included and whose vanishing provides the criteria for validity of the effective Hamiltonian approach. Finally, we apply the theory to examples of the ac Stark shift and three-level Raman transitions, recovering a decoherence effect in the latter.
We develop a formally exact master equation to describe the evolution of the average density matrix of a closed quantum system driven by a stochastic Hamiltonian. The average over stochastic processes generally results in decoherence effects in closed system dynamics, in addition to the unitary evolution. We then show that, for an important class of problems in which the Hamiltonian is proportional to a Gaussian random process, the 2nd-order master equation yields exact dynamics. The general formalism is applied to study the examples of a two-level system, two atoms in a stochastic magnetic field and the heating of a trapped ion, where we find phenomena such as decoherence-induced disentanglement.
Evolution of quantum mechanical systems under time-dependent Hamiltonians has remained a challenging problem of interest across all disciplines. Through suitable approximations, different averaging methods have emerged in the past for modeling the time-evolution under time-dependent Hamiltonians. To this end, the development of analytic methods in the form of time-averaged effective Hamiltonians has gained prominence over other methods. In particular, the advancement of spectroscopic methods for probing molecular structures has benefited enormously from such theoretical pursuits. Nonetheless, the validity of the approximations and the exactness of the proposed effective Hamiltonians have always remained a contentious issue. Here, in this report, we reexamine the equivalence between the effective Hamiltonians derived from the Magnus formula and Floquet theory through suitable examples in magnetic resonance.
Dissipation and decoherence, and the evolution from pure to mixed states in quantum physics, are handled through master equations for the density matrix. Master equations such as the Lindblad equation preserve the trace of this matrix. Viewing them as first-order time-dependent operator equations for the elements of the density matrix, a unitary integration procedure can be adapted to solve for these elements. A simple model for decoherence preserves the Hermiticity of the density matrix. A single, classical Riccati equation is the only one requiring numerical handling to obtain a full solution of the quantum evolution. The procedure is general, valid for any number of levels, but is illustrated here for a three-level system with two driving fields. For various choices of the initial state, we study the evolution of the system as a function of the amplitudes, relative frequencies, and phases of the driven fields and of the strength of the decoherence. The monotonic growth of the entropy is followed as the system evolves from a pure to a mixed state. An example is provided by the n=3n=3n=3 states of the hydrogen atom in a time-dependent electric field, such degenerate manifolds affording an analytical solution.
We pursue topics in optics that follow three major themes; time averaged dynamics with the associated Effective Hamiltonian theory, quantification and transformation of polarization, and periodicity within quantum circuits.\n\nWithin the first theme, we develop a technique for finding the dynamical evolution in time of a time averaged density matrix. The result is an equation of evolution that includes an Effective Hamiltonian, as well as decoherence terms that sometimes manifest in a Lindblad-like form. We also apply the theory to examples of the AC Stark Shift and Three-Level Raman Transitions.\n\nIn the theme of polarization, the most general physical transformation on the polarization state has been represented as an ensemble of Jones matrix transformations, equivalent to a completely positive map on the polarization matrix. This has been directly assumed without proof by most authors. We follow a novel approach to derive this expression from simple physical principles, basic coherence optics and the matrix theory of positive maps. \n\nAddressing polarization measurement, we first establish the equivalence of classical polarization and quantum purity, which leads to the identical structure of the Poincar\\'{e} and Bloch spheres. We analyze and compare various measures of polarization / purity for general dimensionality proposed in the literature, with a focus on the three dimensional case. % entanglement?\n\nIn pursuit of the final theme of periodic quantum circuits, we introduce a procedure that synthesizes the circuit for the simplest periodic function that is one-to-one within a single period, of a given period p. Applying this procedure, we synthesize these circuits for p up to five bits. We conjecture that such a circuit will need at most n Toffoli gates, where p is an n-bit number. \n\nMoreover, we apply our circuit synthesis to compiled versions of Shor's algorithm, showing that it can create more efficient circuits than ones previously proposed. We provide some new compiled circuits for experimentalists to use in the near future. A layer of "classical compilation" is pointed out as a method to further simplify circuits. Periodic and compiled circuits should be helpful for creating experimental milestones, and for the purposes of validation.