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arXiv:1006.4610 · American Journal of Physics

P. A. M. Dirac and the discovery of quantum mechanics

Kurt Gottfried

Published Feb 16, 2011• 8 citations
arXivHTMLPDF

Abstract

Dirac’s contributions to the discovery of nonrelativistic quantum mechanics and quantum electrodynamics, prior to his discovery of the relativistic wave equation, are described.
DOI
10.1119/1.3536639

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The purpose of this chapter is to introduce the Dirac equation, which will provide us with a basis for developing the relativistic quantum mechanics of electronic systems. Thus far we have reviewed some basic features of the classical relativistic theory, which is the foundation of relativistic quantum theory. As in the nonrelativistic case, quantum mechanical equations may be obtained from the classical relativistic particle equations by use of the correspondence principle, where we replace classical variables by operators. Of particular interest are the substitutions In terms of the momentum four-vector introduced earlier, this yields In going from a classical relativistic description to relativistic quantum mechanics, we require that the equations obtained are invariant under Lorentz transformations. Other basic requirements, such as gauge invariance, must also apply to the equations of relativistic quantum mechanics. We start this chapter by reexamining the quantization of the nonrelativistic Hamiltonian and draw out some features that will be useful in the quantization of the relativistic Hamiltonian. We then turn to the Dirac equation and sketch its derivation. We discuss some properties of the equation and its solutions, and show how going to the nonrelativistic limit reduces it to a Schrödinger-type equation containing spin.
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This paper re-examines the key aspects of Dirac's derivation of his relativistic equation for the electron in order advance our understanding of the nature of quantum field theory. Dirac's derivation, the paper argues, follows the key principles behind Heisenberg's discovery of quantum mechanics, which, the paper also argues, transformed the nature of both theoretical and experimental physics vis-a-vis classical physics and relativity. However, the limit theory (a crucial consideration for both Dirac and Heisenberg) in the case of Dirac's theory was quantum mechanics, specifically, Schrodinger's equation, while in the case of quantum mechanics, in Heisenberg's version, the limit theory was classical mechanics. Dirac had to find a new equation, Dirac's equation, along with a new type of quantum variables, while Heisenberg, to find new theory, was able to use the equations of classical physics, applied to different, quantum-mechanical variables. In this respect, Dirac's task was more similar to that of Schrodinger in his work on his version of quantum mechanics. Dirac's equation reflects a more complex character of quantum electrodynamics or quantum field theory in general and of the corresponding (high-energy) experimental quantum physics vis-a-vis that of quantum mechanics and the (low-energy) experimental quantum physics. The final section examines this greater complexity and its implications for fundamental physics.
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