Recent papers discussing thermodynamic processes in strongly coupled quantum systems claim a violation of Landauer's principle and imply a violation of the second law of thermodynamics. If true, this would have powerful consequences. Perpetuum mobiles could be build as long as the operating temperature is brought close to zero. It would also have serious consequences on thermodynamic derivations of information theoretic results, such as the Holevo bound. Here we argue why these claims are erroneous. Correlations occurring in the strongly coupled, quantum domain require a rethink of how entropy, heat and work are calculated. It is shown that a consistent treatment solves the paradox.
Recent papers discussing thermodynamic processes in strongly coupled quantum systems claim a violation of Landauer's principle and imply a violation of the second law of thermodynamics. If true, this would have powerful consequences. Perpetuum mobiles could be build as long as the operating temperature is brought close to zero. It would also have serious consequences on thermodynamic derivations of information theoretic results, such as the Holevo bound. Here we argue why these claims are erroneous. Correlations occurring in the strongly coupled, quantum domain require a rethink of how entropy, heat and work are calculated. It is shown that a consistent treatment solves the paradox.
It is often claimed, that from a quantum system of d levels, and entropy S and heat bath of temperature T one can draw kT lnd–TS amount of work. However, the usual arguments basing on Szilard engine, are not fully rigorous. Here we prove the formula within Hamiltonian description of drawing work from a quantum system and a heat bath, at the cost of entropy of the system. We base on the derivation of thermodynamical laws and quantities in [10] within weak coupling limit. Our result provides fully physical scenario for extracting thermodynamical work form quantum correlations [4]. We also derive Landauer's principle as a consequence of the second law within the considered model.
It is often claimed, that from a quantum system of d levels, and entropy S and heat bath of temperature T one can draw kT(ln d -S) amount of work. However, the usual arguments based on Szilard engine are not fully rigorous. Here we prove the formula within Hamiltonian description of drawing work from a quantum system and a heat bath, at a cost of entropy of the system. We base on the derivation of thermodynamical laws and quantities in [R. Alicki, J. Phys. A, 12, L103 (1979)] within a weak coupling limit. Our result provides fully physical scenario for extracting thermodynamical work from quantum correlations [J. Oppenheim et al. Phys. Rev. Lett. 89, 180402 (2002)]. We also derive Landauer principle as a consquence of second law within the considered model.
The Brownian motion of a quantum particle in a harmonic confining potential and coupled to harmonic quantum thermal bath is exactly solvable. Though this system presents at high temperatures a pedagogic example to explain the laws of thermodynamics, it is shown that at low enough temperatures the stationary state is non-Gibbsian due to an entanglement with the bath. In physical terms, this happens when the cloud of bath modes around the particle starts to play a nontrivial role, namely, when the bath temperature T is smaller than the coupling energy. Indeed, equilibrium thermodynamics of the total system, particle plus bath, does not imply standard equilibrium thermodynamics for the particle itself at low T. Various formulations of the second law are found to be invalid at low T. First, the Clausius inequality can be violated, because heat can be extracted from the zero point energy of the cloud of bath modes. Second, when the width of the confining potential is suddenly changed, there occurs a relaxation to equilibrium during which the entropy production is partly negative. In this process the energy put on the particle does not relax monotonically, but oscillates between particle and bath, even in the limit of strong damping. Third, for nonadiabatic changes of system parameters the rate of energy dissipation can be negative, and, out of equilibrium, cyclic processes are possible which extract work from the bath. Conditions are put forward under which perpetuum mobility of the second kind, having one or several work extraction cycles, enter the realm of condensed matter physics. Fourth, it follows that the equivalence between different formulations of the second law (e.g., those by Clausius and Thomson) can be violated at low temperatures. These effects are the consequence of quantum entanglement in the presence of the slightly off-equilibrium nature of the thermal bath, and become important when the characteristic quantum time scale variant Planck's over 2pi /k(B)T is larger than or comparable to other time scales of the system. They show that there is no general consensus between standard thermodynamics and quantum mechanics. The known agreements occur only due to the weak coupling limit, which does not pertain to low temperatures. Experimental setups for testing the effects are discussed.
Traditional form of the second law of thermodynamics is strongly restricted by three conditions: One is the initial joint state of the system and surroundings should be a product state, so that there exists no initial correlations. The second is the initial states of surroundings are in equilibrium thermodynamics. And the end is weak couplings between the system and surroundings. This formulation of the second law should be reexamined in order to understand the relations of thermodynamics and information theory, especially, when existing initial correlations. In this work, using the techniques of quantum statistical mechanics for thermodynamics and quantum information science, we recast fundamental laws of thermodynamics from theoretical information point of view. Initial correlations between the system and surroundings are considered, which evolves thermodynamically and result in modifications of the traditional formulations. We obtained improved forms of the entropy increase, Landauer's principle, and the second law of thermodynamics, which are exhibited as equalities rather than inequalities, and through which physical nature of information can be demonstrated precisely. Further, using the language totally belongs to quantum information theory, we give the direction of natural evolution process a new statement: the evolution of an isolated quantum system, where no correlations exist between subsystems, initially, always towards to directions of the correlation information never be decreased. Such result indicates that the traditional principle of entropy increase can be redescribed using information theory, identically.
It is argued using a Gedankenexperiment that a scalable quantum memory could be used as a perpetuum mobile of the second kind and hence cannot be realized in nature. The reasoning is based on the assumption that the Landauer's principle for measurements is a consequence of the second law of thermodynamics and not an independent postulate. This implies a modification of the Landauer's principle when applied for discrimination of equilibrium (metastable) states. While identification of the metastable state can be done at infinitesimally low cost, any change of such state involves dissipation of energy proportional to its stability factor.
We investigate the link between information and thermodynamics embodied by Landauer's principle in the open dynamics of a multipartite quantum system. Such irreversible dynamics is described in terms of a collisional model with a finite temperature reservoir. We demonstrate that Landauer's principle holds, for such a configuration, in a form that involves the flow of heat dissipated into the environment and the rate of change of the entropy of the system. Quite remarkably, such a principle for heat and entropy power can be explicitly linked to the rate of creation of correlations among the elements of the multipartite system and, in turn, the non-Markovian nature of their reduced evolution. Such features are illustrated in two exemplary cases.