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arXiv:0903.3875 · Modern Physics Letters B

STATISTICAL QUANTUM OPERATION

SUMIYOSHI ABE, YUICHI ITTO, MAMORU MATSUNAGA

Published Jul 29, 2010• 2 citations
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Abstract

An explicit form of a generic unital quantum operation, which transforms a given stationary pure state to an arbitrary statistical state with perfect decoherence, is presented. This allows one to operationally realize the thermal state as a special case. The loss of information due to randomness generated by the operation is discussed by evaluating the entropy. Realization of the thermal state of a bipartite spin-1/2 system is discussed as an illustrative example.

DOI
10.1142/s0217984910024407

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An explicit form of a generic unital quantum operation, which transforms a given stationary pure state to an arbitrary statistical state with perfect decoherence, is presented. This allows one to operationally realize the thermal state as a special case. The loss of information due to randomness generated by the operation is discussed by evaluating the entropy. Realization of the thermal state of a bipartite spin-1/2 system is discussed as an illustrative example.
Toward the formulation of the operational approach to quantum thermodynamics, the heat-up operator is explicitly constructed. This quantum operation generates for a generic system an irreversible transformation from a pure ground state at zero temperature to a state at finite temperature. The fixed point analysis shows that repeated applications of the operation map from an arbitrary state to the completely random state realized in the high-temperature limit. The change of the von Neumann entropy is evaluated for a simple bipartite spin-1/2 system. It is shown that remarkably, the second law of thermodynamics may be violated along processes generated by the present quantum operation.
An attempt toward the operational formulation of quantum thermodynamics is made by employing the recently proposed operations forming positive operator-valued measures for generating thermodynamic processes. The quantity of heat as well as the von Neumann entropy monotonically increases under the operations. The fixed point analysis shows that repeated applications of these operations to a given system transform from its pure ground state at zero temperature to the completely random state in the high temperature limit with intermediate states being generically out of equilibrium. It is shown that the Clausius inequality can be violated along the processes, in general. A bipartite spin-1/2 system is analyzed as an explicit example.
We formulate statistical mechanics based on a pure quantum state, which we call a ``thermal pure quantum (TPQ) state''. A single TPQ state gives not only equilibrium values of mechanical variables, such as magnetization and correlation functions, but also those of genuine thermodynamic variables and thermodynamic functions, such as entropy and free energy. Among many possible TPQ states, we discuss the canonical TPQ state, the TPQ state whose temperature is specified. % We also propose there are other TPQ states. In the TPQ formulation of statistical mechanics, thermal fluctuations are completely included in quantum-mechanical fluctuations. As a consequence, TPQ states have much larger quantum entanglement than the equilibrium density operators of the ensemble formulation. We also show that the TPQ formulation is very useful in practical computations, by applying the formulation to a frustrated two-dimensional quantum spin system.
We formulate statistical mechanics based on a pure quantum state, which we call a ``thermal pure quantum (TPQ) state''. A single TPQ state gives not only equilibrium values of mechanical variables, such as magnetization and correlation functions, but also those of genuine thermodynamic variables and thermodynamic functions, such as entropy and free energy. Among many possible TPQ states, we discuss the canonical TPQ state, the TPQ state whose temperature is specified. % We also propose there are other TPQ states. In the TPQ formulation of statistical mechanics, thermal fluctuations are completely included in quantum-mechanical fluctuations. As a consequence, TPQ states have much larger quantum entanglement than the equilibrium density operators of the ensemble formulation. We also show that the TPQ formulation is very useful in practical computations, by applying the formulation to a frustrated two-dimensional quantum spin system.
Completely positive quantum operations are frequently discussed in the contexts of statistical mechanics and quantum information. They are customarily given by maps forming positive operator-values measures. To intuitively understand the physical meanings of such abstract operations, the method of phase-space representations is examined. This method enables one to grasp the operations in terms of the classical statistical notions. As an example of physical importance, here, the phase-space representation of the completely positive quantum operation arising from the single-mode subdynamics of the two-mode squeezed vacuum state, which maps from the vacuum state at vanishing temperature to mixed states with perfect decoherence including the thermal state, is studied. It is found in the P representation that remarkably this operation is invertible, implying that coherence lost by the quantum operation can be recovered.
A thermal equilibrium state of a quantum many-body system can be represented by a typical pure state, which we call a thermal pure quantum (TPQ) state. We construct the canonical TPQ state, which corresponds to the canonical ensemble of the conventional statistical mechanics. It is related to the microcanonical TPQ state, which corresponds to the microcanonical ensemble, by simple analytic transformations. Both TPQ states give identical thermodynamic results, if both ensembles do, in the thermodynamic limit. The TPQ states corresponding to other ensembles can also be constructed. We have thus established the TPQ formulation of statistical mechanics, according to which all quantities of statistical-mechanical interest are obtained from a single realization of any TPQ state. We also show that it has great advantages in practical applications. As an illustration, we study the spin-1/2 kagome Heisenberg antiferromagnet.