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arXiv:0901.1453 · Physical Review E

Dynamical evolution of quantum oscillators toward equilibrium

A. R. Usha Devi, A. K. Rajagopal

Published Jul 27, 2009• 8 citations
arXivHTMLPDF

Abstract

A pure quantum state of large number N of oscillators, interacting via harmonic coupling, evolves such that any small subsystem n<<N of the global state approaches equilibrium. This provides a different example where stability emerges as natural phenomena under quantum dynamics alone, with no necessity to bring in any additional statistical postulates. Mixing of equilibrated subsystems consisting of 1,2,...,n<<N clearly indicates that small subsystems are entangled with the rest of the state, i.e., the bath. Every single mode oscillator is found to relax in a mixed density matrix of the Boltzmann canonical form. In two oscillator stationary subsystems, intraentanglement within the "system" oscillators is found to exist when the magnitude of the squeezing parameter of the bath is comparable in magnitude with that of the coupling strength.

DOI
10.1103/physreve.80.011136

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A pure quantum state of large number N of oscillators, interacting via harmonic coupling, evolves such that any small subsystem n<<N of the global state approaches equilibrium. This provides a different example where stability emerges as natural phenomena under quantum dynamics alone, with no necessity to bring in any additional statistical postulates. Mixing of equilibrated subsystems consisting of 1,2,...,n<<N clearly indicates that small subsystems are entangled with the rest of the state, i.e., the bath. Every single mode oscillator is found to relax in a mixed density matrix of the Boltzmann canonical form. In two oscillator stationary subsystems, intraentanglement within the "system" oscillators is found to exist when the magnitude of the squeezing parameter of the bath is comparable in magnitude with that of the coupling strength.
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The circumstances under which a system reaches thermal equilibrium, and how to derive this from basic dynamical laws, has been a major question from the very beginning of thermodynamics and statistical mechanics. Despite considerable progress, it remains an open problem. Motivated by this issue, we address the more general question of equilibration. We prove, with virtually full generality, that reaching equilibrium is a universal property of quantum systems: almost any subsystem in interaction with a large enough bath will reach an equilibrium state and remain close to it for almost all times. We also prove several general results about other aspects of thermalization besides equilibration, for example, that the equilibrium state does not depend on the detailed microstate of the bath.
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Our normal understanding of the dissipative relaxation of a quantum system interacting with a reservoir or heat bath leads us to expect that the final state of the quantum system is a mixed state characteristic of one subsystem in equilibrium with the larger reservoir. We show that the broadband squeezed vacuum has such strong correlations in its quantum noise that, although it represents a true reservoir, the decay of subsystems, such as pairs of atoms or oscillators interacting with a squeezed reservoir, relaxes to a pure state that reflects these strong correlations.
Time evolution of a harmonic oscillator linearly coupled to a heat bath is compared for three classes of initial states for the bath modes-grand canonical ensemble, number states, and coherent states. It is shown that for a wide class of number states the behavior of the oscillator is similar to the case of the equilibrium bath. If the bath modes are initially in coherent states, then the variances of the oscillator coordinate and momentum, as well as its entanglement to the bath, asymptotically approach the same values as for the oscillator at zero temperature and the average coordinate and momentum show a Brownian-like behavior. We derive an exact master equation for the characteristic function of the oscillator valid for arbitrary factorized initial conditions. In the case of the equilibrium bath this equation reduces to an equation of the Hu-Paz-Zhang type, while for the coherent states bath it leads to an exact stochastic master equation with a multiplicative noise.
We study the thermalization of a composite quantum system consisting of several subsystems, where only a small one of the subsystem contacts with a heat bath in equilibrium, while the rest of the composite system is contact free. We show that the whole composite system still can be thermalized after a relaxation time long enough, if the energy level structure of the composite system is connected, which means any two energy levels of the composite system can be connected by direct or indirect quantum transitions. With an example where an multi-level system interacts with a set of harmonic oscillators via non-demolition coupling, we find that the speed of relaxation to the global thermal state is suppressed by the multi-Franck-Condon factor due to the displacements of the Fock states when the degrees of freedom is large.