We study the influence of thermal Casimir-Polder forces on the near-surface trapping of cold polar molecules, with emphasis on LiH and YbF near a Au surface at room temperature. We show that even for a molecule initially prepared in its electronic and rovibrational ground state, the Casimir-Polder force oscillates with the molecule-wall separation. The nonresonant force and the evanescent part of the resonant force almost exactly cancel at high temperature which results in a saturation of the (attractive) force in this limit. This implies that the Casimir-Polder force on a fully thermalized molecule can differ dramatically from that obtained using a naive perturbative expansion of the Lifshitz formula based on the molecular ground-state polarizability. A dynamical calculation reveals how the spatial oscillations die out on a typical time scale of several seconds as thermalization of the molecule with its environment sets in.
We study the influence of thermal Casimir-Polder forces on the near-surface trapping of cold polar molecules, with emphasis on LiH and YbF near a Au surface at room temperature. We show that even for a molecule initially prepared in its electronic and rovibrational ground state, the Casimir-Polder force oscillates with the molecule-wall separation. The nonresonant force and the evanescent part of the resonant force almost exactly cancel at high temperature which results in a saturation of the (attractive) force in this limit. This implies that the Casimir-Polder force on a fully thermalized molecule can differ dramatically from that obtained using a naive perturbative expansion of the Lifshitz formula based on the molecular ground-state polarizability. A dynamical calculation reveals how the spatial oscillations die out on a typical time scale of several seconds as thermalization of the molecule with its environment sets in.
We report on the first measurement of a temperature dependence of the Casimir-Polder force. This measurement was obtained by positioning a nearly pure 87Rb Bose-Einstein condensate a few microns from a dielectric substrate and exciting its dipole oscillation. Changes in the collective oscillation frequency of the magnetically trapped atoms result from spatial variations in the surface-atom force. In our experiment, the dielectric substrate is heated up to 605 K, while the surrounding environment is kept near room temperature (310 K). The effect of the Casimir-Polder force is measured to be nearly 3 times larger for a 605 K substrate than for a room-temperature substrate, showing a clear temperature dependence in agreement with theory.
We analyze the thermal Casimir-Polder potential experienced by a ground-state molecule in a planar cavity and investigate the prospects for using such a setup for molecular guiding. The resonant atom-field interaction associated with this nonequilibrium situation manifests itself in oscillating standing-wave components of the potential. While the respective potential wells are normally too shallow to be useful, they may be amplified by a highly reflecting cavity whose width equals a half-integer multiple of a particular molecular transition frequency. We find that with an ideal choice of molecule and the use of a cavity bounded by Bragg mirrors of ultrahigh reflectivity, it may be possible to boost the potential by up to two orders of magnitude. We analytically derive the scaling of the potential depth as a function of reflectivity and analyze how it varies with temperature and molecular properties. It is also shown how the potential depth decreases for standing waves with a larger number of nodes. Finally, we investigate the lifetime of the molecular ground state in a thermal environment and find that it is not greatly influenced by the cavity and remains in the order of several seconds.
We consider the dynamical atom-surface Casimir-Polder force in the nonequilibrium configuration of an atom near a perfectly conducting wall, initially prepared in an excited state with the field in its vacuum state. We evaluate the time-dependent Casimir-Polder force on the atom and find that it shows an oscillatory behavior from attractive to repulsive both in time and in space. We also investigate the asymptotic behavior in time of the dynamical force and of related local field quantities, showing that the static value of the force, as obtained by a time-independent approach, is recovered for times much longer than the time scale of the atomic self-dressing but shorter than the atomic decay time. We then discuss the evolution of global quantities such as atomic and field energies and their asymptotic behavior. We also compare our results for the dynamical force on the excited atom with analogous results recently obtained for an initially bare ground-state atom. We show that new relevant features are obtained in the case of an initially excited atom, for example, much larger values of the dynamical force with respect to the static one, allowing for an easier way to single out and observe the dynamical Casimir-Polder effect.
We have investigated, by separating the contributions from thermal fluctuations (tf) and the radiation reaction (rr), the gravitational Casimir-Polder interaction between a gravitationally polarizable two-level object and an infinite gravitational Dirichlet boundary in a thermal bath at a temperature T. The results indicate that the rr-contribution to the interaction potential is independent of the temperature, whereas the tf-contribution is generally governed by a nontrivial interplay between the thermal corrections and the polarization effect. Here, the object-to-boundary distance, the characteristic transition wavelength of the object and the thermal wavelength of gravitons are denoted by L, λ and β, respectively. In contrast to the vacuum case, where the interaction potential scales as L−5 for L≪λ and L−6 for L≫λ, corresponding to an always repulsive force, qualitatively new behaviors emerge at high temperatures. Particularly, when 4βλ3≪L≪λ and the object is polarizable within the plane perpendicular to the boundary, a novel scaling of TL−1 arises; when βλ≪L≪λ and the object is polarizable along the vertical-to-boundary axis, the interaction force becomes surprisingly attractive. At extremely high temperatures and large distances, i.e. when β≪λ≪L, the potential oscillates with the distance L and thus an attractive or repulsive and even vanishing force can be resulted, depending on the exact values of L. Our work demonstrates that thermal gravitons can act as an active control mechanism for quantum gravitational interactions, and temperature, polarization configuration, and object-to-boundary distance jointly determine the magnitude, scaling law, and even the attractive or repulsive nature of the interaction force.
Within the frame of macroscopic QED in linear, causal media, we study the radiation force of Casimir-Polder type acting on an atom which is positioned near dispersing and absorbing magnetodielectric bodies and initially prepared in an arbitrary electronic state. It is shown that minimal and multipolar coupling lead to essentially the same lowest-order perturbative result for the force acting on an atom in an energy eigenstate. To go beyond perturbation theory, the calculations are based on the exact center-of-mass equation of motion. For a nondriven atom in the weak-coupling regime, the force as a function of time is a superposition of force components that are related to the electronic density matrix elements at a chosen time. Even the force component associated with the ground state is not derivable from a potential in the ususal way, because of the position dependence of the atomic polarizability. Further, when the atom is initially prepared in a coherent superposition of energy eigenstates, then temporally oscillating force components are observed, which are due to the interaction of the atom with both electric and magnetic fields.
The surface–atom Casimir–Polder–Lifshitz force out of thermal equilibrium is investigated in the framework of macroscopic electrodynamics. Particular attention is devoted to its large distance limit that shows a new, stronger behaviour with respect to the equilibrium case. The frequency shift produced by the surface–atom force on the centre-of-mass oscillations of a harmonically trapped Bose–Einstein condensate and on the Bloch oscillations of an ultra-cold fermionic gas in an optical lattice are discussed for configurations out of thermal equilibrium.