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arXiv:0811.3351

Generalized grand-canonical ensemble theory for interacting Bose-Einstein systems

Alexander Jurisch, Jan Michael Rost

Published Nov 20, 2008• 0 citations
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Abstract

We use the maximum information principle to include particle-interaction into the grand-canonical theory of BECs. The inclusion of the particle-interaction elucidates why thermodynamic calculations for BECs by the grand-canonical ensemble for the non-interacting case are in coincidence with up to date experimental results. However, in our generalized theory we can show that a BEC experiences a real and abrupt phase-transition in contrast to the smooth phase-transition predicted by the non-interacting grand-canonical ensemble. In addition, we discuss possible effects due to a thermal environment and the experimental probing from a general point of view.

DOI
10.48550/arxiv.0811.3351

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We use the maximum information principle to include particle-interaction into the grand-canonical theory of BECs. The inclusion of the particle-interaction elucidates why thermodynamic calculations for BECs by the grand-canonical ensemble for the non-interacting case are in coincidence with up to date experimental results. However, in our generalized theory we can show that a BEC experiences a real and abrupt phase-transition in contrast to the smooth phase-transition predicted by the non-interacting grand-canonical ensemble. In addition, we discuss possible effects due to a thermal environment and the experimental probing from a general point of view.
We analyze the general relation between canonical and grand canonical ensembles in the thermodynamic limit. We begin our discussion by deriving, with an alternative approach, some standard results first obtained by Kac and coworkers in the late 1970s. Then, motivated by the Bose-Einstein condensation (BEC) of trapped gases with a fixed number of atoms, which is well described by the canonical ensemble and by the recent groundbreaking experimental realization of BEC with photons in a dye-filled optical microcavity under genuine grand canonical conditions, we apply our formalism to a system of non-interacting Bose particles confined in a two-dimensional harmonic trap. We discuss in detail the mathematical origin of the inequivalence of ensembles observed in the condensed phase, giving place to the so-called grand canonical catastrophe of density fluctuations. We also provide explicit analytical expressions for the internal energy and specific heat and compare them with available experimental data. For these quantities, we show the equivalence of ensembles in the thermodynamic limit.
Abstract Particle fluctuations in systems, exhibiting Bose–Einstein condensation, are reviewed in order to clarify the basic points that attract high interest and often confront misunderstanding. It is explained that the so-called ‘grand canonical catastrophe’, claiming the occurrence of catastrophic particle fluctuations in the condensed phase, treated by grand canonical ensemble, does not exist. What exists is the incorrect use of the grand canonical ensemble, where gauge symmetry is not broken, while the correct description of the condensed phase necessarily requires gauge symmetry breaking. The ideal Bose gas has no catastrophic condensate fluctuations, and moreover there are no condensate fluctuations at all, as soon as gauge symmetry is broken. However it does have anomalous fluctuations of uncondensed particles, which implies its instability. For interacting particles, there are no condensate fluctuations, as soon as gauge symmetry is broken, and anomalous fluctuations of uncondensed particles, when correctly calculated, do not appear. Particle fluctuations in the systems of trapped atoms are discussed. Canonical ensemble and grand canonical ensemble with broken gauge symmetry are equivalent with respect to the number of particle scaling.
We study the Bose-Einstein condensation phase transition in a weakly interacting gas through a perturbative analysis of finite systems. In both the grand canonical and the canonical ensembles, perturbation theory suffers from infrared divergences and cannot directly determine the transition temperature in the thermodynamic limit. However, in conjunction with finite-size scaling, perturbation theory provides a powerful calculation tool. Here we use this combination of perturbation theory and scaling to estimate a shift in the transition temperature in the canonical ensemble consistent with grand canonical calculations.
Based on grand canonical assembles statistics,the Bose Einstein Condensation (BEC) in non interacting bound atomic system is studied.Some basic concepts of BEC in conventional infinite Bose system are extended.The condition of chemical potential μ ≤0 will not be guarantted for the present finite bound system,and the vapour with μ 0,the state without condensation at any eigenstate,might be possible in principle even below a critical temperature T C .Gibbs functions for both the gas and the BEC state at temperature TT C have been calculated.The condition for BEC to appear is presented.The relation of BEC temperature T C with the density of particles is estimated and the result is qualitatively in good agreement with the experimental results.
In this paper, we present a general method of superstabilization corresponding to add the 'forward scattering' interaction to some non-superstable model. Then, we evaluate the free-energy density, the grand-canonical pressure and particle density for the new (superstable) Bose gas using those for the (non-superstable) model. To sum up, this first part should give us the thermodynamic basis necessary to explain, in a subsequent paper, the main interest of this method: the restoration of the strong equivalence of ensembles (canonical/grand-canonical) without destroying the 'fundamental' thermodynamic properties (such as Bose condensation phenomenona) issued from the first non-superstable system.
Grand-canonical fluctuations of Bose-Einstein condensates of light are accessible to state-of-the-art experiments [J. Schmitt et al., Phys. Rev. Lett. 112, 030401 (2014).PRLTAO0031-900710.1103/PhysRevLett.112.030401]. We phenomenologically describe these fluctuations by using the grand-canonical ensemble for a weakly interacting Bose gas at thermal equilibrium. For a two-dimensional harmonic trap, we use two models for which the canonical partition functions of the weakly interacting Bose gas are given by exact recurrence relations. We find that the grand-canonical condensate fluctuations for weakly interacting Bose gases vanish at zero temperature, thus behaving qualitatively similarly to an ideal gas in the canonical ensemble (or microcanonical ensemble) rather than the grand-canonical ensemble. For low but finite temperatures, the fluctuations remain considerably higher than for the canonical ensemble, as predicted by the ideal gas in the grand-canonical ensemble, thus clearly showing that we are not in a regime in which the ensembles are equivalent.