Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:0808.0334 · Physical Review Letters

Employing Trapped Cold Ions to Verify the Quantum Jarzynski Equality

Gerhard Huber, Ferdinand Schmidt‐Kaler, Sebastian Deffner, Eric Lutz

Published Aug 14, 2008• 160 citations
arXivHTMLPDF

Abstract

We propose a scheme to investigate the nonequilibrium work distribution of a quantum particle under well controlled transformations of the external potential, exploiting the versatility of a single ion in a segmented linear Paul trap. We describe in detail how the motional quantum state of a single ion can be prepared, manipulated, and finally readout to fully determine the free energy difference in both harmonic and anharmonic potentials. Uniquely to our system, we show how an ion may be immersed in an engineered laser-field reservoir. Trapped ions therefore represent an ideal tool for investigating the Jarzynski equality in open and closed quantum systems.

DOI
10.1103/physrevlett.101.070403

Related papers

Experimental Verification of a Jarzynski-Related Information-Theoretic Equality by a Single Trapped Ion

Tian‐Jian Xiong, L.-L. Yan, Fei Zhou +7 more

Most nonequilibrium processes in thermodynamics are quantified only by inequalities; however, the Jarzynski relation presents a remarkably simple and general equality relating nonequilibrium quantities with the equilibrium free energy, and this equality holds in both the classical and quantum regimes. We report a single-spin test and confirmation of the Jarzynski relation in the quantum regime using a single ultracold ^{40}Ca^{+} ion trapped in a harmonic potential, based on a general information-theoretic equality for a temporal evolution of the system sandwiched between two projective measurements. By considering both initially pure and mixed states, respectively, we verify, in an exact and fundamental fashion, the nonequilibrium quantum thermodynamics relevant to the mutual information and Jarzynski equality.

arXiv:1803.10423•Physical Review Letters•Jan 5, 2018•54 citations

Quantum dynamics of single trapped ions

Dietrich G. Leibfried, R. Blatt, Christopher R. Monroe +1 more

Single trapped ions represent elementary quantum systems that are well isolated from the environment. They can be brought nearly to rest by laser cooling, and both their internal electronic states and external motion can be coupled to and manipulated by light fields. This makes them ideally suited for quantum-optical and quantum-dynamical studies under well-controlled conditions. Theoretical and experimental work on these topics is reviewed in the paper, with a focus on ions trapped in radio-frequency (Paul) traps.

Reviews of Modern Physics•Mar 10, 2003•2,736 citations

Control and Measurement of a Single-Ion Quantum Harmonic Oscillator

Katherine C. McCormick

A trapped-ion harmonic oscillator represents a rich and well-controlled platform for tests of quantum physics, with applications to quantum simulations, quantum sensing, and quantum information processing. Owing to its net charge, the ion's motion is affected by changes in the electric potential. Consequently, electric field and potential curvature noise will limit the coherence of the ion's harmonic oscillation. While in some respects, this serves as a limitation in the performance of the trapped ion system (for example, in the fidelity of two-qubit gates or quantum simulations with motional quanta), it also opens an opportunity to use the ion as a precise field sensor and to use engineered quantum states of motion to enhance the sensitivity to these fields beyond the standard quantum limit (SQL). This thesis describes the implementation of such applications on a single beryllium ion confined in a Paul trap. In the thesis, I present the theory of an ideal harmonic oscillator and the implementation of this system using the motion of a single trapped ion, including producing special quantum states of motion; these states include the energy eigenstates of the harmonic oscillator, called number states, up to n=100, superpositions of number states of the form (1/√2)(|0> + |n>), with n up to 18, and coherently displaced number states with an average occupation up to approximately 300. I describe how we use these quantum states of motion for precise sensing of fluctuations of the harmonic oscillator frequency. The sensitivity of the (1/√2)(|0> + |n>) state ideally follows the 1/n Heisenberg scaling for frequency sensitivity. Additionally, I describe investigations of the spectrum of motional frequency noise using a series of coherent displacements of the motion of the ion, with features similar to Ramsey and dynamical decoupling sequences for two-level systems. While these displaced states don't improve sensitivity over the SQL, they can be simply and rapidly implemented with trapped ions. I discuss extensions to all of these experiments, including to multiple ions in a new trap designed to confine 3 or 4 ions in individually tunable potential wells.

•Jan 1, 2019•1 citation

Computational study of vibrational qubits in anharmonic linear ion traps

Lei Wang

A string of cold ions confined in a linear trap represents a man-made quantum object with a broad range of applications in atomic and molecular spectroscopy, such as high-precision measurement of atomic properties. An efficient isolation from the environment guarantees excellent coherent properties of such systems and makes them suitable for practical realization of the quantum information processing. The pioneering theoretical [Cirac and Zoller] and experimental [Wineland and Monroe] work in 1990s resulted in the explosive expansion of this field during the last decade. In this dissertation an alternative new method for controlling the quantized motional/vibrational states of ions in a trap is explored theoretically. It is proposed to create small anharmonicity in the trapping potential which would modify the spectrum of states and allow addressing the state-to-state transitions selectively. In this approach all ions remain in the ground electronic state and their motion is controlled adiabatically and coherently by applying the optimally shaped electric fields (RF). The optimal control theory, accurate numerical calculation of the energies and wavefunctions, and numerical propagation of wave packets are employed. Two sources of vibrational anharmonicity are studied: the intrinsic Coulomb anharmonicity due to the ion-ion interactions and the external anharmonicity of the trapping potential. It is shown that the magnitude of Coulomb anharmonicity is insufficient for the control. In contrast, anharmonicity of the trapping potential allows controlling the motion of ions very accurately. It is demonstrated that one ion in a slightly anharmonic trap can be easily controlled and used to represent one qubit. A multi-qubit system can be created by employing a long progression of states of a single ion, or by trapping multiple ions and controlling several normal vibration modes of the ion string. Up to four qubits are modeled in this work and accurate pulses are optimized for a set of universal quantum gates: NOT, conditional NOT (CNOT) and Hadamard transformation. The control field for Shor's algorithm (quantum algorithm for factorization onto prime numbers) is also obtained. It is demonstrated that a careful choice of system properties allows achieving very high accuracy of qubit transformations, up to 0.999.

•Jan 1, 2012•0 citations

Quantum State Manipulation and Dynamics in Micro Ion Traps

Frank Ziesel

The outstanding degree of control over trapped ions in Paul traps gives rise to the development of novel quantum manipulation techniques. Optical transitions can be used for precise manipulation of internal and external states. This way, non-classical states can be created which are a key component of quantum algorithms based on quantum logic operations. This powerful optical toolbox enabled the trapped ion system to assume leadership in the field of quantum computation. This thesis addresses two major challenges in the field of micro ion trap quantum optics. The temperature dependence of the heating rate from the ion trap surface is analysed in a novel cryogenic micro ion trap. Furthermore segmented traps allow state manipulations by time dependent electrical potentials, generated by the control voltages. These electrical fields provide a fast and reliable control handle to the ions external degrees of freedom. Quantum computation in Paul trap arrays is based on a combination of ion crystal transport, splitting and merging operations, while laser driven quantum state manipulations are mainly carried out on small ion crystals. Within this thesis a basic building block was realised by performing transport operations with a single ground-state cooled ion. As a highlight of experimental achievements, shuttling in the non-adiabatic regime, on the timescale of the motional period was demonstrated with low residual energy transfer. For his endeavour a specialised low noise arbitrary function generator was designed and manufactured during this thesis. Arbitrary voltage ramps at a sampling rate of up to 2.5 MS/s on up to 12 channels allow the study of a novel excitation method by directly manipulating the ion using electrical forces. Accurate numerical simulations in combination with the fast high resolution voltage supply allow deterministic quantum manipulations via momentum kicks. I report the first experimental demonstration of displaced number states with trapped ions.

•Jan 1, 2012•0 citations

Adiabatic coherent control in the anharmonic ion trap: Numerical analysis of vibrational anharmonicities

Lei Wang, Dmitri Babikov

Anharmonicity of the quantized motional states of ions in a Paul trap can be utilized to address the state-to-state transitions selectively and control the motional modes of trapped ions coherently and adiabatically [Zhao and Babikov, Phys. Rev. A 77, 012338 (2008)]. In this paper we study two sources of the vibrational anharmonicity in the ion traps: the intrinsic Coulomb anharmonicity due to ion-ion interactions and the external anharmonicity of the trapping potential. An accurate numerical approach is used to compute energies and wave functions of vibrational eigenstates. The magnitude of the Coulomb anharmonicity is determined and shown to be insufficient for successful control. In contrast, anharmonicity of the trapping potential allows one to control the motion of ions very efficiently using the time-varying electric fields. Optimal control theory is used to derive the control pulses. One ion in a slightly anharmonic trap can be easily controlled. In the two- and three-ion systems the symmetric stretching mode is dark and cannot be controlled at all. The other two normal modes of the three-ion system can be controlled and used, for example, to encode a two-qubit system into the motional states of ions. A trap architecture that allows the necessary amount of vibrational anharmonicity to be achieved is proposed.

Physical Review A•Feb 7, 2011•12 citations
We propose a scheme to investigate the nonequilibrium work distribution of a quantum particle under well controlled transformations of the external potential, exploiting the versatility of a single ion in a segmented linear Paul trap. We describe in detail how the motional quantum state of a single ion can be prepared, manipulated, and finally readout to fully determine the free energy difference in both harmonic and anharmonic potentials. Uniquely to our system, we show how an ion may be immersed in an engineered laser-field reservoir. Trapped ions therefore represent an ideal tool for investigating the Jarzynski equality in open and closed quantum systems.
Most nonequilibrium processes in thermodynamics are quantified only by inequalities; however, the Jarzynski relation presents a remarkably simple and general equality relating nonequilibrium quantities with the equilibrium free energy, and this equality holds in both the classical and quantum regimes. We report a single-spin test and confirmation of the Jarzynski relation in the quantum regime using a single ultracold ^{40}Ca^{+} ion trapped in a harmonic potential, based on a general information-theoretic equality for a temporal evolution of the system sandwiched between two projective measurements. By considering both initially pure and mixed states, respectively, we verify, in an exact and fundamental fashion, the nonequilibrium quantum thermodynamics relevant to the mutual information and Jarzynski equality.
Single trapped ions represent elementary quantum systems that are well isolated from the environment. They can be brought nearly to rest by laser cooling, and both their internal electronic states and external motion can be coupled to and manipulated by light fields. This makes them ideally suited for quantum-optical and quantum-dynamical studies under well-controlled conditions. Theoretical and experimental work on these topics is reviewed in the paper, with a focus on ions trapped in radio-frequency (Paul) traps.
A trapped-ion harmonic oscillator represents a rich and well-controlled platform for tests of quantum physics, with applications to quantum simulations, quantum sensing, and quantum information processing. Owing to its net charge, the ion's motion is affected by changes in the electric potential. Consequently, electric field and potential curvature noise will limit the coherence of the ion's harmonic oscillation. While in some respects, this serves as a limitation in the performance of the trapped ion system (for example, in the fidelity of two-qubit gates or quantum simulations with motional quanta), it also opens an opportunity to use the ion as a precise field sensor and to use engineered quantum states of motion to enhance the sensitivity to these fields beyond the standard quantum limit (SQL). This thesis describes the implementation of such applications on a single beryllium ion confined in a Paul trap. In the thesis, I present the theory of an ideal harmonic oscillator and the implementation of this system using the motion of a single trapped ion, including producing special quantum states of motion; these states include the energy eigenstates of the harmonic oscillator, called number states, up to n=100, superpositions of number states of the form (1/√2)(|0> + |n>), with n up to 18, and coherently displaced number states with an average occupation up to approximately 300. I describe how we use these quantum states of motion for precise sensing of fluctuations of the harmonic oscillator frequency. The sensitivity of the (1/√2)(|0> + |n>) state ideally follows the 1/n Heisenberg scaling for frequency sensitivity. Additionally, I describe investigations of the spectrum of motional frequency noise using a series of coherent displacements of the motion of the ion, with features similar to Ramsey and dynamical decoupling sequences for two-level systems. While these displaced states don't improve sensitivity over the SQL, they can be simply and rapidly implemented with trapped ions. I discuss extensions to all of these experiments, including to multiple ions in a new trap designed to confine 3 or 4 ions in individually tunable potential wells.
A string of cold ions confined in a linear trap represents a man-made quantum object with a broad range of applications in atomic and molecular spectroscopy, such as high-precision measurement of atomic properties. An efficient isolation from the environment guarantees excellent coherent properties of such systems and makes them suitable for practical realization of the quantum information processing. The pioneering theoretical [Cirac and Zoller] and experimental [Wineland and Monroe] work in 1990s resulted in the explosive expansion of this field during the last decade. In this dissertation an alternative new method for controlling the quantized motional/vibrational states of ions in a trap is explored theoretically. It is proposed to create small anharmonicity in the trapping potential which would modify the spectrum of states and allow addressing the state-to-state transitions selectively. In this approach all ions remain in the ground electronic state and their motion is controlled adiabatically and coherently by applying the optimally shaped electric fields (RF). The optimal control theory, accurate numerical calculation of the energies and wavefunctions, and numerical propagation of wave packets are employed. Two sources of vibrational anharmonicity are studied: the intrinsic Coulomb anharmonicity due to the ion-ion interactions and the external anharmonicity of the trapping potential. It is shown that the magnitude of Coulomb anharmonicity is insufficient for the control. In contrast, anharmonicity of the trapping potential allows controlling the motion of ions very accurately. It is demonstrated that one ion in a slightly anharmonic trap can be easily controlled and used to represent one qubit. A multi-qubit system can be created by employing a long progression of states of a single ion, or by trapping multiple ions and controlling several normal vibration modes of the ion string. Up to four qubits are modeled in this work and accurate pulses are optimized for a set of universal quantum gates: NOT, conditional NOT (CNOT) and Hadamard transformation. The control field for Shor's algorithm (quantum algorithm for factorization onto prime numbers) is also obtained. It is demonstrated that a careful choice of system properties allows achieving very high accuracy of qubit transformations, up to 0.999.
The outstanding degree of control over trapped ions in Paul traps gives rise to the development of novel quantum manipulation techniques. Optical transitions can be used for precise manipulation of internal and external states. This way, non-classical states can be created which are a key component of quantum algorithms based on quantum logic operations. This powerful optical toolbox enabled the trapped ion system to assume leadership in the field of quantum computation. This thesis addresses two major challenges in the field of micro ion trap quantum optics. The temperature dependence of the heating rate from the ion trap surface is analysed in a novel cryogenic micro ion trap. Furthermore segmented traps allow state manipulations by time dependent electrical potentials, generated by the control voltages. These electrical fields provide a fast and reliable control handle to the ions external degrees of freedom. Quantum computation in Paul trap arrays is based on a combination of ion crystal transport, splitting and merging operations, while laser driven quantum state manipulations are mainly carried out on small ion crystals. Within this thesis a basic building block was realised by performing transport operations with a single ground-state cooled ion. As a highlight of experimental achievements, shuttling in the non-adiabatic regime, on the timescale of the motional period was demonstrated with low residual energy transfer. For his endeavour a specialised low noise arbitrary function generator was designed and manufactured during this thesis. Arbitrary voltage ramps at a sampling rate of up to 2.5 MS/s on up to 12 channels allow the study of a novel excitation method by directly manipulating the ion using electrical forces. Accurate numerical simulations in combination with the fast high resolution voltage supply allow deterministic quantum manipulations via momentum kicks. I report the first experimental demonstration of displaced number states with trapped ions.
Anharmonicity of the quantized motional states of ions in a Paul trap can be utilized to address the state-to-state transitions selectively and control the motional modes of trapped ions coherently and adiabatically [Zhao and Babikov, Phys. Rev. A 77, 012338 (2008)]. In this paper we study two sources of the vibrational anharmonicity in the ion traps: the intrinsic Coulomb anharmonicity due to ion-ion interactions and the external anharmonicity of the trapping potential. An accurate numerical approach is used to compute energies and wave functions of vibrational eigenstates. The magnitude of the Coulomb anharmonicity is determined and shown to be insufficient for successful control. In contrast, anharmonicity of the trapping potential allows one to control the motion of ions very efficiently using the time-varying electric fields. Optimal control theory is used to derive the control pulses. One ion in a slightly anharmonic trap can be easily controlled. In the two- and three-ion systems the symmetric stretching mode is dark and cannot be controlled at all. The other two normal modes of the three-ion system can be controlled and used, for example, to encode a two-qubit system into the motional states of ions. A trap architecture that allows the necessary amount of vibrational anharmonicity to be achieved is proposed.