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arXiv:0806.1743 · Physical Review B

Z2 spin-orbital liquid state in the square lattice Kugel-Khomskii model

Fa Wang, Ashvin Vishwanath

Published Aug 19, 2009• 73 citations
arXivHTMLPDF

Abstract

We argue for the existence of a liquid ground state in a class of square lattice models of orbitally degenerate insulators. Starting with the SU(4)-symmetric Kugel-Khomskii model, we utilize a Majorana Fermion representation of spin-orbital operators to access unusual phases. Variational wave functions of candidate liquid phases are thus obtained, whose properties are evaluated using variational Monte Carlo. These states are disordered and are found to have excellent energetics and ground state overlap $(>40%)$ when compared with exact diagonalization on 16-site clusters. We conclude that these are spin-orbital liquid ground states with emergent nodal fermions and ${\text{Z}}_{2}$ gauge fields. Connections to spin-3/2 cold-atom systems and properties in the absence of SU(4) symmetry are briefly discussed.

DOI
10.1103/physrevb.80.064413

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We argue for the existence of a liquid ground state in a class of square lattice models of orbitally degenerate insulators. Starting with the SU(4)-symmetric Kugel-Khomskii model, we utilize a Majorana Fermion representation of spin-orbital operators to access unusual phases. Variational wave functions of candidate liquid phases are thus obtained, whose properties are evaluated using variational Monte Carlo. These states are disordered and are found to have excellent energetics and ground state overlap (>40(>40%)(>40 when compared with exact diagonalization on 16-site clusters. We conclude that these are spin-orbital liquid ground states with emergent nodal fermions and Z2{\text{Z}}_{2}Z2​ gauge fields. Connections to spin-3/2 cold-atom systems and properties in the absence of SU(4) symmetry are briefly discussed.
Previous investigations have suggested that the simplest spin-orbital model on the simplest frustrated lattice can host a nematic quantum spin-orbital liquid state. Namely, the orbital degeneracy of the SU(4) Kugel-Khomskii model tends to enhance quantum fluctuations and stabilize a quantum spin-orbital liquid exhibiting stripy features on the triangular lattice, as revealed by the state-of-the-art method of the density matrix renormalization group boosted by Gutzwiller projected wave functions. In this work, using the variational quantum Monte Carlo method, we study several spin-orbital liquid states, including a uniform $\ensuremath{\pi}$-flux state, three stripy states, and a plaquette state, on the $L\ifmmode\times\else\texttimes\fi{}L$ torus up to L=24L=24L=24. It turns out that one of these stripy states, called the ``stripe-II'' state, is energetically favored. This ground state breaks the C6{C}_{6}C6​ symmetry of the lattice, resulting in a reduced C2{C}_{2}C2​ symmetry and doubled unit cells while preserving the SU(4) spin-orbital rotation symmetry. Such a nematic quantum spin-orbital liquid state can be characterized by a parton Fermi surface (FS) consisting of open orbits in the Brillouin zone, in contrast to the circular FS of the uniform $\ensuremath{\pi}$-flux state.
Previous investigations have suggested that the simplest spin-orbital model on the simplest frustrated lattice can host a nematic quantum spin-orbital liquid state. Namely, the orbital degeneracy of the SU(4) Kugel-Khomskii (KK) model tends to enhance quantum fluctuations and stabilize a quantum spin-orbital liquid exhibiting stripy features on the triangular lattice, as revealed by the state-of-the-art method of the density matrix renormalization group boosted by Gutzwiller projected wave functions. In this work, using the variational quantum Monte Carlo method, we have studied several spin-orbital liquid states, including a uniform πππ flux state, three stripy states, and a plaquette state, on the L×LL\times{}LL×L torus up to L=24L=24L=24. It turns out that one of these stripy states, called the "stripe-II" state, is energetically favored. This ground state breaks the C6C_6C6​ symmetry of the lattice, resulting in a reduced C2C_2C2​ symmetry and doubled unit cells, while preserving the SU(4) spin-orbital rotation symmetry. Such a nematic quantum spin-orbital liquid state can be characterized by a parton Fermi surface (FS) consisting of open orbits in the Brillouin zone, in contrast to the circular FS of the uniform πππ-flux state.
Theory of Dirac Spin-Orbital Liquids: monopoles, anomalies, and applications to SU(4)SU(4)SU(4) honeycomb models
Dirac spin liquids represent a class of highly-entangled quantum phases in two dimensional Mott insulators, featuring exotic properties such as critical correlation functions and absence of well-defined low energy quasi-particles. Existing numerical works suggest that the spin-orbital SU(4)SU(4)SU(4) symmetric Kugel-Khomskii model of Mott insulators on the honeycomb lattice realizes a Dirac spin-orbital liquid, described at low energy by (2+1)d(2+1)d(2+1)d quantum electrodynamics (QED3_33​) with Nf=8N_f=8Nf​=8 Dirac fermions. We generalize methods previously developed for SU(2)SU(2)SU(2) spin systems to analyze the symmetry properties and stability of the Dirac spin-orbital liquid. We conclude that the standard Dirac state in the SU(4)SU(4)SU(4) honeycomb system, based on a simple parton mean-field ansatz, is intrinsically unstable at low energy due to the existence of a monopole perturbation that is allowed by physical symmetries and relevant under renormalization group flow. We propose two plausible alternative scenarios compatible with existing numerics. In the first scenario, we propose an alternative U(1)U(1)U(1) Dirac spin-orbital liquid, which is similar to the standard one except for its monopole symmetry quantum numbers. This alternative U(1)U(1)U(1) state represents a stable gapless phase. In the second scenario, we start from the standard U(1)U(1)U(1) Dirac liquid and Higgs the U(1)U(1)U(1) gauge symmetry down to Z4\mathbb{Z}_4Z4​. The resulting Z4\mathbb{Z}_4Z4​ Dirac spin-orbital liquid is stable. We also discuss the continuous quantum phase transitions from the Z4\mathbb{Z}_4Z4​ Dirac liquids to conventional symmetry-breaking orders, described by the QED3_33​ theory with Nf=8N_f=8Nf​=8 supplemented with a critical charge-444 Higgs field. We discuss possible ways to distinguish these scenarios in numerics. We also extend previous calculations of the quantum anomalies of QED3_33​ and match with generalized lattice Lieb-Schultz-Mattis constraints.
We consider the phase diagram of the most general SU(4)-symmetric two-site Hamiltonian for a system of two fermions per site (i.e., self-conjugate 6\mathbf{6}6 representation) on the square lattice. It is known that this model hosts magnetic phases breaking SU(4) symmetry and quantum disordered dimerlike phases breaking lattice translation symmetry. Motivated by a previous work [O. Gauth\'e, S. Capponi, and D. Poilblanc, Phys. Rev. B 99, 241112(R) (2019)], we investigate the possibility of the existence of SU(4) quantum spin liquid phases in this model, using SU(4)-symmetric projected entangled pair states (PEPS) of small bond dimensions, which can be classified according to point group and charge (C) symmetries. Among several (disconnected) families of SU(4)-symmetric PEPS, breaking or not C-symmetry, we identify critical or topological spin liquids which may be stable in some regions of the phase diagram. These results are confronted to exact diagonalization (ED) and density matrix renormalization group (DMRG) calculations.
Emergent gauge theories take a prominent role in the description of quantum matter, supporting deconfined phases with topological order and fractionalized excitations. A common construction of \mathbb{Z}_2 ℤ 2 lattice gauge theories, first introduced by Wegner, involves Ising gauge spins placed on links and subject to a discrete \mathbb{Z}_2 ℤ 2 Gauss law constraint. As shown by Kitaev, \mathbb{Z}_2 ℤ 2 lattice gauge theories also emerge in the exact solution of certain spin systems with bond-dependent interactions. In this context, the \mathbb{Z}_2 ℤ 2 gauge field is constructed from Majorana fermions, with gauge constraints given by the parity of Majorana fermions on each site. In this work, we provide an explicit Jordan-Wigner transformation that maps between these two formulations on the square lattice, where the Kitaev-type gauge theory emerges as the exact solution of a spin-orbital (Kugel-Khomskii) Hamiltonian. We then apply our mapping to study local perturbations to the spin-orbital Hamiltonian, which correspond to anisotropic interactions between electric-field variables in the \mathbb{Z}_2 ℤ 2 gauge theory. These are shown to induce anisotropic confinement that is characterized by emergence of weakly-coupled one-dimensional spin chains. We study the nature of these phases and corresponding confinement transitions in both absence and presence of itinerant fermionic matter degrees of freedom. Finally, we discuss how our mapping can be applied to the Kitaev spin-1/2 model on the honeycomb lattice.
We study possible spin liquids on square lattice that respect all lattice symmetries and time-reversal symmetry within the framework of Schwinger boson (mean-field) theory. Such spin liquids have spin gap and emergent Z2{Z}_{2}Z2​ gauge field excitations. We classify them by the projective symmetry group method, and find six spin-liquid states that are potentially relevant to the ${J}_{1}\text{\ensuremath{-}}{J}_{2}$ Heisenberg model. The properties of these states are studied under mean-field approximation. Interestingly we find a spin-liquid state that can go through continuous phase transitions to either the N\'eel magnetic order or magnetic orders of the wave vector at the Brillouin zone edge center. We also discuss the connection between our results and the Abrikosov fermion spin liquids.