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arXiv:0805.4488

On the von Neumann equation with time-dependent Hamiltonian. Part II: Applications

Maciej Kuna, Jan Naudts

Published May 29, 2008• 1 citation
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Abstract

This second part deals with applications of a general method to describe the quantum time evolution determined by a Schroedinger equation with time-dependent Hamiltonian. A new aspect of our approach is that we find all solutions starting from one special solution. The two main applications are reviewed, namely the Bloch equations and the harmonic oscillator with time-dependent frequency. Even in these well-known examples some new results are obtained.

DOI
10.48550/arxiv.0805.4488

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This second part deals with applications of a general method to describe the quantum time evolution determined by a Schroedinger equation with time-dependent Hamiltonian. A new aspect of our approach is that we find all solutions starting from one special solution. The two main applications are reviewed, namely the Bloch equations and the harmonic oscillator with time-dependent frequency. Even in these well-known examples some new results are obtained.
It is shown that the eigenvalue problem for the Hamiltonians of the standard form, H=p2/(2m)+V(x)H=p^2/(2m)+V(x)H=p2/(2m)+V(x), is equivalent to the classical dynamical equation for certain harmonic oscillators with time-dependent frequency. This is another indication of the central role played by time-dependent harmonic oscillators in quantum mechanics. The utility of the known results for eigenvalue problem in the solution of the dynamical equations of a class of time-dependent harmonic oscillators is also pointed out.
The unitary operators U(t), describing the quantum time evolution of systems with a time-dependent Hamiltonian, can be constructed in an explicit manner using the method of time-dependent invariants. We clarify the role of Lie-algebraic techniques in this context and elaborate the theory for SU(2) and SU(1,1). We show that the constructions known as Magnus expansion and Wei-Norman expansion correspond with different representations of the rotation group. A simpler construction is obtained when representing rotations in terms of Euler angles. The many applications are postponed to Part II of the paper.
Chapter 9 is devoted to a detailed study of the harmonic oscillator in one dimension. The time-dependent Schrödinger equation is used to construct the coherent oscillator packet with minimal dispersion, which provides an opportunity to appreciate the similarities and differences between the dynamics of the classical and quantum oscillators. In a second step, we study the stationary solutions of the oscillator, which represent one of the most important orthogonal sets of quantum eigenfunctions because of its many applications, properties, and relative simplicity. Further, the use of raising and lowering (or creation and annihilation) operators is shown to be a powerful way of dealing with both material and field oscillators in general. Finally, the problem of two coupled oscillators is used to generalize the Schrödinger equation to the case of more than one particle.
The derivation of the time dependent Schrödinger equation with transversal and longitudinal relaxation, as the quantum mechanical analog of the classical Landau-Lifshitz-Bloch equation, has been described. Starting from the classical Landau-Lifshitz-Bloch equation the transition to quantum mechanics has been performed and the corresponding von-Neumann equation deduced. In a second step the time Schrödinger equation has been derived. Analytical proofs and computer simulations show the correctness and applicability of the derived Schrödinger equation.
Solutions of the Schrödinger equation with an exact time dependence are derived as eigenfunctions of dynamical invariants which are constructed from time-independent operators using time-dependent unitary transformations. Exact solutions and a closed form expression for the corresponding time evolution operator are found for a wide range of time-dependent Hamiltonians in d dimensions, including non-Hermitean -symmetric Hamiltonians. Hamiltonians are constructed using time-dependent unitary spatial transformations comprising dilatations, translations and rotations and solutions are found in several forms: as eigenfunctions of a quadratic invariant, as coherent state eigenfunctions of boson operators, as plane wave solutions from which the general solution is obtained as an integral transform by means of the Fourier transform, and as distributional solutions for which the initial wavefunction is the Dirac δ-function. For the isotropic harmonic oscillator in d dimensions radial solutions are found which extend known results for d = 1, including Barut–Girardello and Perelomov coherent states (i.e., vector coherent states), which are shown to be related to eigenfunctions of the quadratic invariant by the ζ-transformation. This transformation, which leaves the Ermakov equation invariant, implements SU(1, 1) transformations on linear dynamical invariants. coherent states are derived also for the time-dependent linear potential. Exact solutions are found for Hamiltonians with electromagnetic interactions in which the time-dependent magnetic and electric fields are not necessarily spatially uniform. As an example, it is shown how to find exact solutions of the time-dependent Schrödinger equation for the Dirac magnetic monopole in the presence of time-dependent magnetic and electric fields of a specified form.