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arXiv:0805.4024 · Symmetry Integrability and Geometry Methods and Applications

Hamiltonian Systems Inspired by the Schrödinger Equation

Vasyl Kovalchuk

Published May 27, 2008• 4 citations
arXivHTMLPDF

Abstract

Described is n-level quantum system realized in the n-dimensional "Hilbert" space H with the scalar product G taken as a dynamical variable.The most general Lagrangian for the wave function and G is considered.Equations of motion and conservation laws are obtained.Special cases for the free evolution of the wave function with fixed G and the pure dynamics of G are calculated.The usual, first-and second-order modified Schrödinger equations are obtained.

DOI
10.3842/sigma.2008.046

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Described is n-level quantum system realized in the n-dimensional "Hilbert" space H with the scalar product G taken as a dynamical variable.The most general Lagrangian for the wave function and G is considered.Equations of motion and conservation laws are obtained.Special cases for the free evolution of the wave function with fixed G and the pure dynamics of G are calculated.The usual, first-and second-order modified Schrödinger equations are obtained.
In the one-dimensional stationary case, we construct a mechanical Lagrangian describing the quantum motion of a nonrelativistic spinless system. This Lagrangian is written as a difference between a function T, which represents the quantum generalization of the kinetic energy and which depends on the coordinate x and the temporal derivatives of x up the third order, and the classical potential V(x). The Hamiltonian is then constructed and the corresponding canonical equations are deduced. The function T is first assumed to be arbitrary. The development of T in a power series together with the dimensional analysis allow us to fix univocally the series coefficients by requiring that the well-known quantum stationary Hamilton–Jacobi equation be reproduced. As a consequence of this approach, we formulate the law of the quantum motion representing a new version of the quantum Newton law. We also analytically establish the famous Bohm relation [Formula: see text] outside the framework of the hydrodynamical approach and show that the well-known quantum potential, although it is a part of the kinetic term, plays really the role of an additional potential as assumed by Bohm.
We develop a general `classicalization' procedure that links Hilbert-space and phase-space operators, using Weyl's operator. Then we transform the time-dependent Schrödinger equation into a phase-space picture using free parameters. They include position Q and momentum P . We expand the phase-space Hamiltonian in an ℏ-Taylor series and fix parameters with the condition that coefficients of ℏ 0 , -iℏ 1 ∂/∂ Q and iℏ 1 ∂/∂ P vanish. This condition results in generalized Hamilton equations and a natural link between classical and quantum dynamics, while the quantum motion-equation remains exact . In this picture, the Schrödinger equation reduces in the classical limit to a generalized Liouville equation for the quantum-mechanical system state. We modify Glauber's coherent states with a suitable phase factor S ( Q , P , t ) and use them to obtain phase-space representations of quantum dynamics and quantum-mechanical quantities.
The similarity in form between the two real equations implied by the single-body spin-0 Schrödinger equation in the position representation (wave mechanics) and the equations of fluid mechanics with potential flow in its Eulerian formulation was first pointed out by Madelung in 1926 [1]. In this analogy, the probability density is proportional to the fluid density, and the phase of the wave function is a velocity potential. A novel feature of the quantum fluid is the appearance of quantum stresses, which are usually represented through the quantum potential. To achieve mathematical equivalence of the models, the hydrodynamic variables have to satisfy 4.1 Introduction .................................................................................................... 55 4.2 Deduction of Schrödinger’s Equation from the Lagrangian Picture Trajectory Theory ........................................................................................... 57 4.2.1 Lagrangian Picture ............................................................................. 57 4.2.2 Eulerian Picture .................................................................................. 62 4.2.3 Equivalence of First-Order and Second-Order Trajectory Laws ........64
This chapter focuses on the time-dependent Schrödinger equation and its solutions for several prototype systems. It provides the basis for discussing and understanding quantum dynamics in condensed phases, however, a full picture can be obtained only by including also dynamical processes that destroy the quantum mechanical phase. Such a full description of quantum dynamics cannot be handled by the Schrödinger equation alone; a more general approach based on the quantum Liouville equation is needed. This important part of the theory of quantum dynamics is discussed in Chapter 10. Given a system characterized by a Hamiltonian Ĥ , the time-dependent Schrödinger equation is For a closed, isolated system Ĥ is time independent; time dependence in the Hamiltonian enters via effect of time-dependent external forces. Here we focus on the earlier case. Equation (1) is a first-order linear differential equation that can be solved as an initial value problem.
The quantum mechanical, time-dependent wave equation in generalized coordinates is obtained by a slight modification of Schrödinger's original derivation. If the classical Hamiltonian for a system is known, the variational technique may be applied to the Hamilton-Jacobi equation to yield an Euler-Lagrange equation. This latter is then the wave equation for the system. The method, which is generally easy to apply, is illustrated by applications to a single particle in curvilinear coordinates and to a symmetric top molecule.