Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:0805.3770 · Physical Review Letters

Quantum Work Relations and Response Theory

David Andrieux, Pierre Gaspard

Published Jun 13, 2008• 97 citations
arXivHTMLPDF

Abstract

A universal quantum work relation is proved for isolated time-dependent Hamiltonian systems in a magnetic field as the consequence of microreversibility. This relation involves a functional of an arbitrary observable. The quantum Jarzynski equality is recovered in the case this observable vanishes. The Green-Kubo formula and the Casimir-Onsager reciprocity relations are deduced thereof in the linear response regime.

DOI
10.1103/physrevlett.100.230404

Related papers

Quantum work relations and response theory in parity-time-symmetric quantum systems

Bo-Bo Wei

In this work, we show that a universal quantum work relation for a quantum system driven arbitrarily far from equilibrium extends to a parity-time- (PT-) symmetric quantum system with unbroken PT symmetry, which is a consequence of microscopic reversibility. The quantum Jarzynski equality, linear response theory, and Onsager reciprocal relations for the PT-symmetric quantum system are recovered as special cases of the universal quantum work relation in a PT-symmetric quantum system. In the regime of broken PT symmetry, the universal quantum work relation does not hold because the norm is not preserved during the dynamics.

arXiv:1711.00586•Physical review. E•Jan 11, 2018•12 citations

The principle of microreversibility and the fluctuation relations for quantum systems driven out of equilibrium

Hiroshi Matsuoka

For classical systems driven out of equilibrium, Crooks derived a relation (the Crooks-Jarzynski relation), whose special cases include a relation (the Crooks relation) equivalent to the Kawasaki non-linear response relation. We derive a quantum extension of the Crooks-Jarzynski relation without explicitly using the principle of microreversibility. Its special cases lead to the Jarzynski equality and the standard linear response theory with a Green-Kubo formula with a canonical correlation function. We also derive a quantum extension of the Crooks relation using the principle of microreversibility. Its special cases lead to the Jarzynski equality, the Crooks transient fluctuation theorem, and the fluctuation theorem for current or shear stress, which leads to a Green-Kubo formula with a symmetrized correlation function. For each quantum Crooks relation, there exists a corresponding quantum Crooks-Jarzynski relation. Using either relation, we can derive the Jarzynski equality, the fluctuation theorems mentioned above, and the standard linear response theory.

arXiv:1210.8085•Oct 30, 2012•0 citations

Response theory for quantum fields in isolation

Stefan Floerchinger

Response theory describes the reaction of observales to perturbations in external fields. We review this formalism for quantum fiels in isolation that have unitary time evolution. An emphasis is put on consequences of causality and the resulting spectral representations for linear and nonlinear response functions, on functional techniques and generating functionals, including the description of the initial state, the evolution, and measurements. We review consequences of time reversal symmetry and relations for the statistics of work, and discuss a large class of quantum correlation functions, and their relation to response functions through fluctuation-dissipation relations. Consequences of conservation laws and gauge symmetries are mentioned briefly.

quant-pharXiv:2604.13637•Apr 16, 2026•0 citations

The fluctuation theorem for currents in open quantum systems

David Andrieux, Pierre Gaspard, Takaaki Monnai +1 more

A quantum-mechanical framework is set up to describe the full counting statistics of particles flowing between reservoirs in an open system under time-dependent driving. A symmetry relation is obtained, which is the consequence of microreversibility for the probability of the nonequilibrium work and the transfer of particles and energy between the reservoirs. In some appropriate long-time limit, the symmetry relation leads to a steady-state quantum fluctuation theorem for the currents between the reservoirs. On this basis, relationships are deduced which extend the Onsager–Casimir reciprocity relations to the nonlinear response coefficients.

arXiv:0811.3687•New Journal of Physics•Apr 7, 2009•210 citations

Quantum response theory for nonequilibrium steady states

Michael Konopik, Eric Lutz

Quantum response theory is a cornerstone of statistical physics.However, the standard Kubo formalism is restricted to isolated equilibrium systems.We here generalize Kubo's results to open quantum systems in nonequilibrium steady states.We derive three different, but equivalent, forms of the quantum response function.We discuss for each of them the role of the noncommutativity of quantum operators and introduce a steady-state extension of the Kubo transformation.We show in particular that the equilibrium response vanishes for perturbations that commute with the unperturbed Hamiltonian, while the steady-state response does not, highlighting the profound difference between the two linear response theories.

arXiv:1811.12277•Physical Review Research•Dec 6, 2019•17 citations

Linear response theory

Helmut Hofmann

Abstract This chapter presents a universal definition of linear response, which at first is studied for the example of the damped oscillator. From the quantal time evolution operator lowest order transition rates are deduced, together with microscopic response functions. Their fundamental properties are studied, in particular, the meaning of their reactive and dissipative parts for energy transfer. Correlation functions are introduced and related to response functions by way of the fluctuation dissipation theorem. For a random matrix model, the latter is shown to also hold true for microcanonical ensembles. Connections to thermal Green functions are established and an extension of response theory to unstable modes is discussed. With the help of the Mori product, relations among the static response, the adiabatic and the isothermal susceptibilities are given. Time dependent irreversible processes are studied by introducing relaxation functions and by following the variation of the density operator and of entropy. Onsager relations are presented and Kubo's expressions for transport coefficients are given.

•Apr 17, 2008•1 citation
A universal quantum work relation is proved for isolated time-dependent Hamiltonian systems in a magnetic field as the consequence of microreversibility. This relation involves a functional of an arbitrary observable. The quantum Jarzynski equality is recovered in the case this observable vanishes. The Green-Kubo formula and the Casimir-Onsager reciprocity relations are deduced thereof in the linear response regime.
In this work, we show that a universal quantum work relation for a quantum system driven arbitrarily far from equilibrium extends to a parity-time- (PT-) symmetric quantum system with unbroken PT symmetry, which is a consequence of microscopic reversibility. The quantum Jarzynski equality, linear response theory, and Onsager reciprocal relations for the PT-symmetric quantum system are recovered as special cases of the universal quantum work relation in a PT-symmetric quantum system. In the regime of broken PT symmetry, the universal quantum work relation does not hold because the norm is not preserved during the dynamics.
For classical systems driven out of equilibrium, Crooks derived a relation (the Crooks-Jarzynski relation), whose special cases include a relation (the Crooks relation) equivalent to the Kawasaki non-linear response relation. We derive a quantum extension of the Crooks-Jarzynski relation without explicitly using the principle of microreversibility. Its special cases lead to the Jarzynski equality and the standard linear response theory with a Green-Kubo formula with a canonical correlation function. We also derive a quantum extension of the Crooks relation using the principle of microreversibility. Its special cases lead to the Jarzynski equality, the Crooks transient fluctuation theorem, and the fluctuation theorem for current or shear stress, which leads to a Green-Kubo formula with a symmetrized correlation function. For each quantum Crooks relation, there exists a corresponding quantum Crooks-Jarzynski relation. Using either relation, we can derive the Jarzynski equality, the fluctuation theorems mentioned above, and the standard linear response theory.
Response theory describes the reaction of observales to perturbations in external fields. We review this formalism for quantum fiels in isolation that have unitary time evolution. An emphasis is put on consequences of causality and the resulting spectral representations for linear and nonlinear response functions, on functional techniques and generating functionals, including the description of the initial state, the evolution, and measurements. We review consequences of time reversal symmetry and relations for the statistics of work, and discuss a large class of quantum correlation functions, and their relation to response functions through fluctuation-dissipation relations. Consequences of conservation laws and gauge symmetries are mentioned briefly.
A quantum-mechanical framework is set up to describe the full counting statistics of particles flowing between reservoirs in an open system under time-dependent driving. A symmetry relation is obtained, which is the consequence of microreversibility for the probability of the nonequilibrium work and the transfer of particles and energy between the reservoirs. In some appropriate long-time limit, the symmetry relation leads to a steady-state quantum fluctuation theorem for the currents between the reservoirs. On this basis, relationships are deduced which extend the Onsager–Casimir reciprocity relations to the nonlinear response coefficients.
Quantum response theory is a cornerstone of statistical physics.However, the standard Kubo formalism is restricted to isolated equilibrium systems.We here generalize Kubo's results to open quantum systems in nonequilibrium steady states.We derive three different, but equivalent, forms of the quantum response function.We discuss for each of them the role of the noncommutativity of quantum operators and introduce a steady-state extension of the Kubo transformation.We show in particular that the equilibrium response vanishes for perturbations that commute with the unperturbed Hamiltonian, while the steady-state response does not, highlighting the profound difference between the two linear response theories.
Abstract This chapter presents a universal definition of linear response, which at first is studied for the example of the damped oscillator. From the quantal time evolution operator lowest order transition rates are deduced, together with microscopic response functions. Their fundamental properties are studied, in particular, the meaning of their reactive and dissipative parts for energy transfer. Correlation functions are introduced and related to response functions by way of the fluctuation dissipation theorem. For a random matrix model, the latter is shown to also hold true for microcanonical ensembles. Connections to thermal Green functions are established and an extension of response theory to unstable modes is discussed. With the help of the Mori product, relations among the static response, the adiabatic and the isothermal susceptibilities are given. Time dependent irreversible processes are studied by introducing relaxation functions and by following the variation of the density operator and of entropy. Onsager relations are presented and Kubo's expressions for transport coefficients are given.