Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:0710.4356

Schemes for robust quantum computation with polar molecules: analysis of experimental feasibility

Elena Kuznetsova, Robin Côté, K. Kirby, Susanne F. Yelin

Published Oct 23, 2007• 0 citations
arXivHTMLPDF

Abstract

We analyse recently proposed physical implementations of a quantum computer based on polar molecules. A set of general requirements for a molecular system is presented, which would provide an optimal combination of quantum gate times, coherence times, number of operations, high gate accuracy and experimental feasibility. We proceed with a detailed analysis of a scheme utilizing switchable dipole-dipole interactions between polar molecules. Switchable dipole-dipole interaction is an efficient tool for realization of two-qubit quantum gates, necessary to construct a universal set of gates. We consider three possible realizations of a phase gate using specific molecules, such as CO, NF, alkali dimers and alkaline-earth monohalides. We suggest suitable electronic states and ransitions and investigate requirements for the pulses driving them. Finally, we analyse possible sources of decoherence.

DOI
10.48550/arxiv.0710.4356

Related papers

Analysis of experimental feasibility of polar-molecule-based phase gates

Elena Kuznetsova, Robin Côté, K. Kirby +1 more

We analyze a recently proposed physical implementation of a quantum computer based on polar molecules with ``switchable'' dipoles, i.e., dipole moments that can be switched ``on'' and ``off''. Conditional dipole-dipole interaction is an efficient tool for realizing two-qubit quantum gates necessary to construct universal gates. A set of general requirements for a molecular system is presented, which would provide an optimal combination of quantum gate times, coherence times, number of operations, high gate accuracy, and experimental feasibility. We proceed with an analysis of a two-qubit phase gate realization based on switchable dipole-dipole interactions between polar molecules in an optical lattice architecture. We consider one of the schemes proposed in our previous work [Phys. Rev. A 74, 050301(R) (2006)], using specific molecules, such as CO and NF. We suggest suitable electronic states and transitions, and investigate requirements for the laser pulses driving them. Finally, we analyze possible sources of decoherence and list practical difficulties of the scheme.

Physical Review A•Jul 9, 2008•50 citations

Polar molecules based phase gates

Elena Kuznetsova, Robin Côté, K. Kirby +1 more

"We analyze recently proposed physical implementations of a quantum computer based on polar molecules with switchable dipoles. Switch- able dipole-dipole interaction is an efficient tool for realization of two-qubit quantum gates, necessary to construct a universal set of gates. We specifically study a phase gate realization based on switchable dipole-dipole interactions between polar molecules in an optical lattice architecture. We consider one possible realization of the phase gate using a specific molecule, such as 13 CO."

Revista Mexicana de Física•Jan 1, 2010•0 citations

Implementation of three-qubit quantum computation with pendular states of polar molecules by optimal control

Zuo-Yuan Zhang, Jin‐Ming Liu, Zhengfeng Hu +1 more

Ultracold polar molecules have been considered as the possible candidates for quantum information processing due to their long coherence time and strong dipole-dipole interaction. In this paper, we consider three coupled polar molecules arranged in a linear chain and trapped in an electric field with gradient. By employing the pendular states of polar molecules as qubits, we successfully realize three-qubit quantum gates and quantum algorithms via the multi-target optimal control theory. Explicitly speaking, through the designs of the optimal laser pulses with multiple iterations, the triqubit Toffoli gate, the triqubit quantum adders, and the triqubit quantum Fourier transform can be achieved in only one operational step with high fidelities and large transition probabilities. Moreover, by combining the optimized Hadamard, oracle, and diffusion gate pulses, we simulate the Grover algorithm in the three-dipole system and show that the algorithm can perform well for search problems. In addition, the behaviors of the fidelity and the average transition probability with respect to iteration numbers are compared and analyzed for each gate pulse. Our findings could pave the way toward scalability for molecular quantum computing based on the pendular states and could be extended to implement multi-particle gate operation in the molecular system.

The Journal of Chemical Physics•Jan 22, 2020•13 citations

Schemes for robust quantum computation with polar molecules

Susanne F. Yelin, K. Kirby, Robin Côté

We show how ultracold polar molecules, suggested as a new platform for quantum computation, can be manipulated to switch ``on'' and ``off'' their strong dipole-dipole interactions. This can be accomplished through selective excitation of states with considerably different dipole moments. We discuss different schemes for quantum gates using real molecules: CO, LiH, and CaF, as examples of polar molecules which are being experimentally studied at ultracold temperatures. These schemes can be realized in several recently proposed architectures.

arXiv:quant-ph/0602030•Physical Review A•Nov 9, 2006•301 citations

Quantum Computation in a Hybrid Array of Molecules and Rydberg Atoms

Chi Zhang, Michael R. Tarbutt

We show that an array of polar molecules interacting with Rydberg atoms is a promising hybrid system for scalable quantum computation.Quantum information is stored in long-lived hyperfine or rotational states of molecules, which interact indirectly through resonant dipole-dipole interactions with Rydberg atoms.A two-qubit gate based on this interaction has a duration of 1 μs and an achievable fidelity of 99.9%.The gate has little sensitivity to the motional states of the particles-the molecules can be in thermal states, the atoms do not need to be trapped during Rydberg excitation, the gate does not heat the molecules, and heating of the atoms has a negligible effect.Within a large, static array, the gate can be applied to arbitrary pairs of molecules separated by tens of micrometres, making the scheme highly scalable.The molecule-atom interaction can also be used for rapid qubit initialization and efficient, nondestructive qubit readout, without driving any molecular transitions.Single-qubit gates are driven using microwave pulses alone, exploiting the strong electric dipole transitions between rotational states.Thus, all operations required for large-scale quantum computation can be done without moving the molecules or exciting them out of their ground electronic states.

arXiv:2204.04276•PRX Quantum•Sep 16, 2022•42 citations

Asymmetric quantum Rabi model, trap-dipole resonance, and quantum gates with optically trapped ultracold polar molecules

Yan Lu, Xiao-Feng Shi

Optically trapped ultracold polar molecules can have multiple long-lived states for coding quantum information, and can exhibit electric dipole-dipole interactions~(DDI) which enables entanglement generation. The general understanding on the quantized motion~(QM) of molecules in the traps is that it causes fluctuation of DDI. Here, we find that the molecular QM can realize an asymmetric quantum Rabi model, which is of specific importance in the study of fundamental physics. The molecular QM can also lead to an exotic trap-dipole resonance, resulting in excess population loss to uncoupled motional states, and, hence, should be avoided in a general quantum control over polar molecules. To examine the impact of QM on quantum computing based on polar molecules, we introduce two gate protocols, a fast iSWAP gate which can be realized by a global microwave pulse of pulse area smaller than $2π$, and a controlled-phase gate with an arbitrary controlled phase, and find that both gates can attain a high fidelity.

quant-pharXiv:2605.22276•Quantum Science and Technology•May 22, 2026•0 citations
We analyse recently proposed physical implementations of a quantum computer based on polar molecules. A set of general requirements for a molecular system is presented, which would provide an optimal combination of quantum gate times, coherence times, number of operations, high gate accuracy and experimental feasibility. We proceed with a detailed analysis of a scheme utilizing switchable dipole-dipole interactions between polar molecules. Switchable dipole-dipole interaction is an efficient tool for realization of two-qubit quantum gates, necessary to construct a universal set of gates. We consider three possible realizations of a phase gate using specific molecules, such as CO, NF, alkali dimers and alkaline-earth monohalides. We suggest suitable electronic states and ransitions and investigate requirements for the pulses driving them. Finally, we analyse possible sources of decoherence.
We analyze a recently proposed physical implementation of a quantum computer based on polar molecules with ``switchable'' dipoles, i.e., dipole moments that can be switched ``on'' and ``off''. Conditional dipole-dipole interaction is an efficient tool for realizing two-qubit quantum gates necessary to construct universal gates. A set of general requirements for a molecular system is presented, which would provide an optimal combination of quantum gate times, coherence times, number of operations, high gate accuracy, and experimental feasibility. We proceed with an analysis of a two-qubit phase gate realization based on switchable dipole-dipole interactions between polar molecules in an optical lattice architecture. We consider one of the schemes proposed in our previous work [Phys. Rev. A 74, 050301(R) (2006)], using specific molecules, such as CO and NF. We suggest suitable electronic states and transitions, and investigate requirements for the laser pulses driving them. Finally, we analyze possible sources of decoherence and list practical difficulties of the scheme.
"We analyze recently proposed physical implementations of a quantum computer based on polar molecules with switchable dipoles. Switch- able dipole-dipole interaction is an efficient tool for realization of two-qubit quantum gates, necessary to construct a universal set of gates. We specifically study a phase gate realization based on switchable dipole-dipole interactions between polar molecules in an optical lattice architecture. We consider one possible realization of the phase gate using a specific molecule, such as 13 CO."
Ultracold polar molecules have been considered as the possible candidates for quantum information processing due to their long coherence time and strong dipole-dipole interaction. In this paper, we consider three coupled polar molecules arranged in a linear chain and trapped in an electric field with gradient. By employing the pendular states of polar molecules as qubits, we successfully realize three-qubit quantum gates and quantum algorithms via the multi-target optimal control theory. Explicitly speaking, through the designs of the optimal laser pulses with multiple iterations, the triqubit Toffoli gate, the triqubit quantum adders, and the triqubit quantum Fourier transform can be achieved in only one operational step with high fidelities and large transition probabilities. Moreover, by combining the optimized Hadamard, oracle, and diffusion gate pulses, we simulate the Grover algorithm in the three-dipole system and show that the algorithm can perform well for search problems. In addition, the behaviors of the fidelity and the average transition probability with respect to iteration numbers are compared and analyzed for each gate pulse. Our findings could pave the way toward scalability for molecular quantum computing based on the pendular states and could be extended to implement multi-particle gate operation in the molecular system.
We show how ultracold polar molecules, suggested as a new platform for quantum computation, can be manipulated to switch ``on'' and ``off'' their strong dipole-dipole interactions. This can be accomplished through selective excitation of states with considerably different dipole moments. We discuss different schemes for quantum gates using real molecules: CO, LiH, and CaF, as examples of polar molecules which are being experimentally studied at ultracold temperatures. These schemes can be realized in several recently proposed architectures.
We show that an array of polar molecules interacting with Rydberg atoms is a promising hybrid system for scalable quantum computation.Quantum information is stored in long-lived hyperfine or rotational states of molecules, which interact indirectly through resonant dipole-dipole interactions with Rydberg atoms.A two-qubit gate based on this interaction has a duration of 1 μs and an achievable fidelity of 99.9%.The gate has little sensitivity to the motional states of the particles-the molecules can be in thermal states, the atoms do not need to be trapped during Rydberg excitation, the gate does not heat the molecules, and heating of the atoms has a negligible effect.Within a large, static array, the gate can be applied to arbitrary pairs of molecules separated by tens of micrometres, making the scheme highly scalable.The molecule-atom interaction can also be used for rapid qubit initialization and efficient, nondestructive qubit readout, without driving any molecular transitions.Single-qubit gates are driven using microwave pulses alone, exploiting the strong electric dipole transitions between rotational states.Thus, all operations required for large-scale quantum computation can be done without moving the molecules or exciting them out of their ground electronic states.
Optically trapped ultracold polar molecules can have multiple long-lived states for coding quantum information, and can exhibit electric dipole-dipole interactions~(DDI) which enables entanglement generation. The general understanding on the quantized motion~(QM) of molecules in the traps is that it causes fluctuation of DDI. Here, we find that the molecular QM can realize an asymmetric quantum Rabi model, which is of specific importance in the study of fundamental physics. The molecular QM can also lead to an exotic trap-dipole resonance, resulting in excess population loss to uncoupled motional states, and, hence, should be avoided in a general quantum control over polar molecules. To examine the impact of QM on quantum computing based on polar molecules, we introduce two gate protocols, a fast iSWAP gate which can be realized by a global microwave pulse of pulse area smaller than 2π2π2π, and a controlled-phase gate with an arbitrary controlled phase, and find that both gates can attain a high fidelity.