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arXiv:0709.1376

Time-reversal properties in the coupling of quantum angular momenta

Gavriel Segre

Published Sep 10, 2007• 1 citation
arXivHTMLPDF

Abstract

After a synoptic panorama about some still unsolved foundational problems involving time-reversal, we show that the \emph{double time-reversal superselection rule} of Nonrelativistic Quantum Mechanics is redundant. We then analyze which, among the symmetries of the Clebsch-Gordan coefficients, may be inferred through time-reversal considerations. Finally, we show how Coupling Theory allows to improve our comprehension of the fact that, in presence of hidden symmetries, Wigner's Theorem concerning Kramers degeneration cannot be applied, by analyzing a set of Z uncoupled massive particles, both in the case in which they are bosons of spin zero and in the case in which they are fermions of spin 1/2, subjected to a Keplerian force's field and considering the coupling of the 2Z quantum angular momenta resulting by the hidden SO(4) symmetry owed to the fact that, apart from the rotational SO(3) symmetry responsible of the conservation of the angular momentum, the Laplace-Runge-Lenz vector is also conserved.

DOI
10.48550/arxiv.0709.1376

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After a synoptic panorama about some still unsolved foundational problems involving time-reversal, we show that the \emph{double time-reversal superselection rule} of Nonrelativistic Quantum Mechanics is redundant. We then analyze which, among the symmetries of the Clebsch-Gordan coefficients, may be inferred through time-reversal considerations. Finally, we show how Coupling Theory allows to improve our comprehension of the fact that, in presence of hidden symmetries, Wigner's Theorem concerning Kramers degeneration cannot be applied, by analyzing a set of Z uncoupled massive particles, both in the case in which they are bosons of spin zero and in the case in which they are fermions of spin 1/2, subjected to a Keplerian force's field and considering the coupling of the 2Z quantum angular momenta resulting by the hidden SO(4) symmetry owed to the fact that, apart from the rotational SO(3) symmetry responsible of the conservation of the angular momentum, the Laplace-Runge-Lenz vector is also conserved.
Quantization of spin and orbital angular momenta in standard quantum mechanics is rooted in the fundamental rotational symmetry of space in conjunction with the results of experiments on atomic and subatomic particles conducted with the Stern-Gerlach apparatus. We explain some of the most important features of spin and orbital angular momenta as inescapable consequences of elementary Stern-Gerlach experiments viewed in light of the rotational symmetry of space. The rotation operator is first derived for spin-½ particles, then extended to spin-1 particles by treating the case of a hydrogen atom in its ground state, where the spin of the proton combines with that of the electron to create a spin-1 triplet state. Along the way, we examine the evolution of a particle’s spin state under an applied magnetic field, where the interaction energy arises from the existence of a magnetic dipole moment for each particle in proportion to its spin angular momentum. Whereas a constant magnetic field B0 causes the particle’s magnetic moment to gyrate around the direction of B0, it will be seen that the presence of a small oscillating magnetic field perpendicular to B0 brings about the so-called Rabi oscillations, which involve periodic flippings of the particle’s spin orientation. In the case of a hydrogen atom in its ground state, the interaction between the magnetic dipole moments of the proton and the electron splits the ground state between a lower energy singlet having a net angular momentum of zero (spin-0 state), and a higher energy triplet having a total angular momentum of ħ (spin-1 state). This hyperfine splitting is the source of the well-known 21-cm line observed in the spectrum of the hydrogen atom, which arises from transitions between the atom’s singlet and triplet states. In the final section, we put forward an argument (originally made by Richard Feynman) that ties the rotational symmetry of space to the conservation of angular momentum in quantum mechanics. The argument is, in fact, quite general, enabling one to deduce other conservation laws from various inherent symmetries of quantum mechanical systems.
In this chapter we discuss the properties of the time-reversal operator (introduced into quantum mechanics by Wigner in 1932) for particles without spin, as well as taking into account the spin. There are given Wigner criteria ( a ), ( b ), and ( c ) concerning the absence or presence of an additional degeneracy of energy levels due to the symmetry with respect to time reversal, both in the case when the spin of particles that form the quantum system is taken into account and in the case it is not. Wigner corepresentations of symmetry groups associated with the presence of time-reversal symmetry are also discussed.
This thesis examines the quantum-mechanical geometric phase with a view toward time reversal symmetry considerations. The idea of time reversal in quantum mechanics is investigated, disagreements and inconsistencies in the literature are examined, and the action of the time reversal operator is extended to time-dependent Hamiltonians. With this background, and using a definition of time reversal symmetry based on the evolution operator, I demonstrate that the existence of a non-zero geometric phase can in all cases be attributed to a breakdown of time reversal symmetry in some form. This result holds for both adiabatic and nonadiabatic evolutions, and for arbitrary dimensional parameter spaces. I explore the role of the geometric phase in a two-level Kramers system described by a parameter-dependent Hamiltonian such that the two levels can become degenerate for some value of the parameters, and discuss, from a mathematical point of view, the monopole geometric potential that results. I then extend this analysis by considering a pair of Kramers doublets, each doublet degenerate due to time reversal symmetry, where the parameters can be chosen so that each of the pair of doublets becomes degenerate with the other. I find the explicit functional forms for the two resulting nonabelian geometric gauge potentials and show that they can be identified exactly with the only two gauge-inequivalent SU(2) monopole potentials of Yang. Furthermore, following a conformal transformation these potentials can be mapped to those of the SU(2) instanton/anti-instanton pair. Finally I examine the relevance of the geometric phase to the molecular physics of time-odd systems. Time-odd coupling in molecular physics is a much under-studied area, with many potentially interesting results. Specifically I study time-odd coupling in Jahn-Teller systems under the Born-Oppenheimer approximation, where the electronic position states are coupled to the lattice momentum rather than the usual time-even lattice position. As an example I solve the E ⊗ (b₁ ⊕ b₂ ⊕ a₂) Jahn-Teller system exactly, showing that once again monopole-like geometric potentials arise, and comment on how this affects the angular momentum of the lattice subsystem.
As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.
Transformations, conservation laws, and symmetries have played an important role in the development of modern quantum mechanics. This chapter includes translation in space and time, rotation in space and rotation operator, parity operations and space inversion, time reversal operator and its properties for both zero and non-zero spin particles, solved examples, and unsolved exercises. The chapter discusses in detail how the rotation in space leads to important relations between various components of orbital and total angular momenta, which play an important role in formulations of quantum mechanics. Parity conservation and the most striking properties of the parity operator, relevance of time reversal in classical and quantum mechanical descriptions, and the antiunitary and antilinear properties of the time reversal operator are also featured details in the chapter.