Uttam Singh, Nicolas J. Cerf (Apr 13 2026).
Abstract: Thermal behavior in subsystems of closed quantum systems is commonly attributed to dynamical chaos, quantum ergodicity, canonical typicality, or the eigenstate thermalization hypothesis, suggesting a fundamentally statistical origin of thermalization. Here, we propose a potential alternative mechanism in which thermal structures emerge deterministically from symmetry considerations alone, without recourse to statistical arguments. We prove a finite de Finetti-type theorem for quantum states invariant under energy-preserving unitaries, establishing that the reduced marginals of any such invariant
N-qudit state are close (both in trace distance and relative entropy) to convex mixtures of thermal product states, with explicit error bounds vanishing as
N→∞. We further present an example of energy-conserving Lindblad dynamics whose long-time limit is invariant under energy-preserving unitaries, providing a dynamical realization of the desired symmetry class. These results imply that invariance under energy-preserving unitaries suffices as a sole fundamental, deterministic principle to enforce thermal structures.