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arXiv:quant-ph/9907031

Alternative Forms of Generalized Vectors and Operators for Spin 1/2

Habatwa Vincent Mweene

Published Jul 8, 1999• 0 citations
arXivHTMLPDF

Abstract

The forms of the generalized quantities that we have recently introduced are dependent on the phase of the probability amplitudes for spin-projection measurements. In this paper, we show explicitly that changing the phase gives different forms for both the spin vectors and spin operators. Therefore, there are as many forms of these quantities as there are different choices of phase.

DOI
10.48550/arxiv.quant-ph/9907031

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The forms of the generalized quantities that we have recently introduced are dependent on the phase of the probability amplitudes for spin-projection measurements. In this paper, we show explicitly that changing the phase gives different forms for both the spin vectors and spin operators. Therefore, there are as many forms of these quantities as there are different choices of phase.
In a recent paper, we introduced a new way of treating systems of compounded angular momentum. We obtained the probability amplitudes for measurements on the systems and used these to derive the matrix treatment of compounded spin. However, the matrix forms are in 3- and 4- dimensional space and are therefore entirely different from the standard forms. This raises the question of the connection between these forms and the standard forms. In this paper, we answer this question. We not only derive the standard matrix treatment of spin addition - we discover a more generalized form of the theory. We apply the new generalized theory to the singlet and triplet states arising from the addition of the spins of two systems of spin 1/2 each. We obtain new generalized forms of the vectors and operators for these cases, and show that they reduce to the standard forms in the appropriate limit.
The interpretation of quantum mechanics due to Lande' is applied to the connection between wave mechanics and matrix mechanics. The connection between the differential eigenvalue equation and the matrix eigenvalue equation for an operator is elucidated. In particular, we show that the elements of a matrix vector state are probability amplitudes with a structure rather than being mere constants. We obtain the most general expressions for the probability amplitudes for the description of spin-1/2 measurements. As a result, we derive spin-1/2 operators and vectors from first principles. The procedure used is analogous to that by which orbital angular momentum wavefunctions and operators are transformed to matrix mechanics vectors and matrices. The most generalized forms of the spin operators and their eigenvectors for spin-1/2 are derived and shown to reduce to the Pauli spin matrices and vectors in an appropriate limit.
Solutions of the Dirac equation for an electron in the Coulomb potential are obtained using operator invariants of the equation, namely the Dirac, Johnson-Lippmann and recently found new invariant. It is demonstrated that these operators are the spin invariants. The generalized invariant is constructed and the exact general solution of the Dirac equation are found. In particular, the explicit expressions of the bispinors corresponding to the three complete sets of the invariants, their eigenvalues and quantum numbers are calculated. It is shown that the general solution of one center Coulomb Dirac equation contains free parameters. Changing one or more of these parameters, one can transform one solution of the Dirac equation into any other. It is shown for the first time that these invariants determine electron spatial probability amplitude and spin polarization in each quantum state. Electron probability densities and spin polarizations are explicitly calculated in the general form for several electron states in the hydrogen-like energy spectrum. Spatial distributions of these characteristics are shown to depend essentially on the invariant set, demonstrating, in spite of the accidental degeneracy of energy levels, physical difference of the states corresponding to different spin invariants.