We propose a novel approach to intrinsic decoherence without adding new assumptions to standard quantum mechanics. We generalize the Liouville equation just by requiring the dynamical semigroup property of time evolution and dropping the unitarity requirement. With no approximations and statistical assumptions we find a generalized Liouville equation which depends on two characteristic time t1 and t2 and reduces to the usual equation in the limit t1 = t2 -> 0. However, for t1 and t2 arbitrarily small but finite, our equation can be written as a finite difference equation which predicts state reduction to the diagonal form in the energy representation. The rate of decoherence becomes faster at the macroscopic limit as the energy scale of the system increases. In our approach the evolution time appears, a posteriori, as a statistical variable with a Poisson-gamma function probability distribution as if time evolution would take place randomly at average intervals t2 each evolution having a time width t1. This view point is supported by the derivation of a generalized Tam Mandelstam inequality. The relation with previous work by Milburn, with laser and micromaser theory and many experimental testable examples are described.
We propose a novel approach to intrinsic decoherence without adding new assumptions to standard quantum mechanics. We generalize the Liouville equation just by requiring the dynamical semigroup property of time evolution and dropping the unitarity requirement. With no approximations and statistical assumptions we find a generalized Liouville equation which depends on two characteristic time t1 and t2 and reduces to the usual equation in the limit t1 = t2 -> 0. However, for t1 and t2 arbitrarily small but finite, our equation can be written as a finite difference equation which predicts state reduction to the diagonal form in the energy representation. The rate of decoherence becomes faster at the macroscopic limit as the energy scale of the system increases. In our approach the evolution time appears, a posteriori, as a statistical variable with a Poisson-gamma function probability distribution as if time evolution would take place randomly at average intervals t2 each evolution having a time width t1. This view point is supported by the derivation of a generalized Tam Mandelstam inequality. The relation with previous work by Milburn, with laser and micromaser theory and many experimental testable examples are described.
We propose a novel approach to intrinsic decoherence without adding new assumptions to standard Quantum Mechanics. We generalize the Liouville equation just by requiring the dynamical semigroup property of time evolution and dropping the unitarity requirement. With no approximations and specific statistical assumptions we find a generalized Liouville equation which depends on two characteristic time t1 and t2 and reduces to the usual equation in the limit t1 = t2 --> 0. However, for t1 and t2 arbitrarily small but finite, our equation can be written as a finite difference equation which predicts state reduction to the diagonal form in the energy representation. The rate of decoherence becomes faster at the macroscopic limit as the energy scale of the system increases. In our approach the evolution time appears, a posteriori, as a statistical variable as if time evolution would take place randomly at average intervals t2, each evolution having a time width t1. A generalized Tam Mandelstam inequality is derived. The relation with previous work by Milburn is discussed. The agreement with recent experiments on damped Rabi oscillations is described.
A model for intrinsic decoherence in quantum mechanics is proposed, based on a simple modification of unitary Schr\"odinger evolution. On sufficiently small time scales the system evolves by a random sequence of unitary phase changes generated by the Hamiltonian. The Schr\"odinger equation is obtained to zeroth order in the expansion parameter. Higher-order corrections lead to a loss of coherence in the energy basis. The rate of coherence loss becomes very large as the energy scale of the system is increased. The expansion parameter determines an uncertainty in the time step on very short times scales. A number of testable consequences are derived including anomalous dispersion of a free particle, decay of oscillatory systems, destruction of interference-fringe visibility, and a phase shift of interference fringes.
The chrono-topology, as introduced axiomatically in a different context, is also supported by Liouville's theorem of statistical mechanics. It is shown that, if time is quantized, the distribution function (d.f.) becomes real. An elementary solution, g, of the classical Liouville equation has been found in phase-space and time, which can be used to construct any differentiable d.f, F(g), satisfying the same Liouville equation. The conditions imposed on F(g) are reality and additivity. The reality requirement, {Im F(g)=0) quantizes: (i) F(g) and makes it time-independent, (ii). The time variable, (iii) The energy. As a verification of chronotopology, the Planck constant h has been calculated on the basis of the time quantization. The d.f. F(g) becomes, after the time quantization, a real generalized Maxwell-Boltzmann d.f, F(g) = exp[g(p, g; l1,l2,..,lN)], depending on Ν quantum numbers. These facts are significant for quantum theory, because they uncover an intrinsic relationship between Liouville's theorem and quantum mechanics.
We explore whether quantum field theory can be understood as the statistical mechanics of a time-reversal-invariant stochastic generalization of Hamiltonian dynamics. The motivation for this project, started with this paper, is to assign sharp values to all observables and thereby avoid the quantum measurement problem. In classical mechanics, motion is deterministic and corresponds to an evolution of the phase space probability density according to Liouville's equation that is governed by first derivatives of the Hamiltonian in phase space. We derive a generalization of the Liouville equation with natural constraints -- namely, reduction to classical Hamiltonian dynamics as the stochasticity parameter ℏ↦0, Fokker-Planck form for the probability density evolution, local Hamiltonian dependence, time-reversal invariance, energy conservation, and minimality -- which turns out to be a Fokker-Planck equation with a generalized diffusion matrix that is symmetric, traceless, and constructed from the Hessian of the Hamiltonian. We then show that the Schrödinger equation in the coherent-state phase-space formulation of certain bosonic QFTs has precisely this form, with the Husimi function playing the role of the phase space probability density. The question to what extent this equation can be interpreted in terms of objective stochastic field theories is discussed in a companion paper.
In many problems of molecular physics of condensed matter the coupling V of the system of interest with its environment is strong. During a time interval of the order of the characteristic relaxation time ΓTy due to V, both the energy spectrum and the time evolution of the system cannot be determined exactly. A new representation is introduced in which the coupling V does not affect the energy spectrum, but it determines the time evolution. This causes the appearance of a new quantity ΓT, called “intrinsic time.” Some results of this procedure are (a) invariance of the basic physical equations under the new trnsformation, (b) noncommutation of ΓT with the Liouvillian, and (c) existence of a nonvanishing “entropy production” with respect to the intrinsic time.
Abstract This chapter introduces the density operator and the Liouville equation and outlines how reduced dynamical description of open quantum systems naturally leads to the appearance of relaxation processes. (1) The density operator and the quantum Liouville equation (the density matrix for a pure system, statistical mixtures, representations, coherences, thermodynamic equilibrium). (2) An example: The time evolution of a two-level system in the density matrix formalism. (3) Reduced descriptions. (4) Time evolution equations for reduced density operators: The quantum master equation (projection operators, The Nakajima–Zwanzig equation, Derivation of the quantum master equation using the thermal projector, The quantum master equation in the interaction representation, The Markovian limit—the Redfield equation, The secular approximation and the Lindblad equation). (5) The Lindblad equation in the ‘Heisenberg representation’. (6) Relaxation of a two-level system and a harmonic oscillator revisited. (7) The optically driven two-level system in a thermal environment—the Bloch equations. (8) The oscillating dipole model of a two-level molecule. (9) Analogy of a coupled two-level system to a spin ½ system in a magnetic field.