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arXiv:quant-ph/0702260

Nodes of Wavefunctions

Marco Moriconi

Published Feb 27, 2007• 0 citations
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Abstract

We give a simple argument to show that the $n$th wavefunction for the one-dimensional Schrödinger equation has $n-1$ nodes. We also show that if $n_1 < n_2$, then between two consecutive zeros of $ψ_{n_1}$, there is a zero of $ψ_{n_2}$.

DOI
10.48550/arxiv.quant-ph/0702260

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We give a simple argument to show that the nnnth wavefunction for the one-dimensional Schrödinger equation has n−1n-1n−1 nodes. We also show that if n1<n2n_1 < n_2n1​<n2​, then between two consecutive zeros of ψn1ψ_{n_1}ψn1​​, there is a zero of ψn2ψ_{n_2}ψn2​​.
Conventional one-dimensional oscillation theorem is found to be violated for multi-component Schrödinger equations in a general case while for two-component eigenstates coupled by the sign-constant potential operator the following statements are valid: (1) the ground state (v=0v = 0v=0) is not degenerate; and (2) the arithmetic mean of nodes n1n_1n1​, n2n_2n2​ for the two-component wavefunction never exceeds the ordering number vvv of eigenstate: (n1+n2)/2≤v(n_1 + n_2)/2\leq v(n1​+n2​)/2≤v.
We analyze two simple models derived from a quantum-mechanical particle on an elliptical path. The first Hamiltonian operator is non-Hermitian but equivalent to an Hermitian operator. It exhibits the same two-fold degeneracy as the particle on a circular path. More precisely, the spectrum is $E_{n}=n^{2}E_{1},\ n=0,\pm 1,\pm 2,\ldots $, E1>0E_{1}>0E1​>0. The second Hamiltonian operator is Hermitian and does not exhibit such degeneracy. In this case the nth excited energy level splits at the nth order of perturbation theory. Both models can be described in terms of symmetry point groups with one-dimensional irreducible representations but the non-Hermitian example exhibits an additional symmetry that explains the two-fold degeneracy. The Schrödinger equation for the first example is exactly solvable.