Macroscopic quantum tunnelling is described using the master equation for the reduced Wigner function of an open quantum system at zero temperature. Our model consists of a particle trapped in a cubic potential interacting with an environment characterized by dissipative and normal and anomalous diffusion coefficients. A representation based on the energy eigenfunctions of the isolated system, i.e. the system uncoupled to the environment, is used to write the reduced Wigner function, and the master equation becomes simpler in that representation. The energy eigenfunctions computed in a WKB approximation incorporate the tunnelling effect of the isolated system and the effect of the environment is described by an equation that is in many ways similar to a Fokker–Planck equation. Decoherence is easily identified from the master equation and we find that when the decoherence time is much shorter than the tunnelling time the master equation can be approximated by a Kramers-like equation describing thermal activation due to the zero point fluctuations of the quantum environment. The effect of anomalous diffusion can be dealt with perturbatively and its overall effect is to inhibit tunnelling.
Macroscopic quantum tunnelling is described using the master equation for the reduced Wigner function of an open quantum system at zero temperature. Our model consists of a particle trapped in a cubic potential interacting with an environment characterized by dissipative and normal and anomalous diffusion coefficients. A representation based on the energy eigenfunctions of the isolated system, i.e. the system uncoupled to the environment, is used to write the reduced Wigner function, and the master equation becomes simpler in that representation. The energy eigenfunctions computed in a WKB approximation incorporate the tunnelling effect of the isolated system and the effect of the environment is described by an equation that is in many ways similar to a Fokker–Planck equation. Decoherence is easily identified from the master equation and we find that when the decoherence time is much shorter than the tunnelling time the master equation can be approximated by a Kramers-like equation describing thermal activation due to the zero point fluctuations of the quantum environment. The effect of anomalous diffusion can be dealt with perturbatively and its overall effect is to inhibit tunnelling.
The tunneling probability for a system modelling macroscopic quantum tunneling is computed. We consider an open quantum system with one degree of freedom consisting of a particle trapped in a cubic potential interacting with an environment characterized by a dissipative and a diffusion parameter. A representation based on the energy eigenfunctions of the isolated system, i. e. the system uncoupled to the environment, is used to write the dynamical master equation for the reduced Wigner function of the open quantum system. This equation becomes very simple in that representation. The use of the WKB approximation for the eigenfunctions suggests an approximation which allows an analytic computation of the tunneling rate, in this real time formalism, when the system is initially trapped in the false ground state. We find that the decoherence produced by the environment suppresses tunneling in agreement with results in other macroscopic quantum systems with different potentials. We confront our analytical predictions with an experiment where the escape rate from the zero voltage state was measured for a current-biased Josephson junction shunted with a resistor.
Recent progress in our understanding of quantum effects on the Brownian motion in an external potential is reviewed. This problem is ubiquitous in physics and chemistry, particularly in the context of decay of metastable states, for example, the reversal of the magnetization of a single domain ferromagnetic particle, kinetics of a superconducting tunnelling junction, etc. Emphasis is laid on the establishment of master equations describing the diffusion process in phase space analogous to the classical Fokker-Planck equation. In particular, it is shown how Wigner's [E. P. Wigner, Phys. Rev., 1932, 40, 749] method of obtaining quantum corrections to the classical equilibrium Maxwell-Boltzmann distribution may be extended to the dissipative non-equilibrium dynamics governing the quantum Brownian motion in an external potential V(x), yielding a master equation for the Wigner distribution function W(x,p,t) in phase space (x,p). The explicit form of the master equation so obtained contains quantum correction terms up to o(h(4)) and in the classical limit, h --> 0, reduces to the classical Klein-Kramers equation. For a quantum oscillator, the method yields an evolution equation coinciding in all respects with that of Agarwal [G. S. Agarwal, Phys. Rev. A, 1971, 4, 739]. In the high dissipation limit, the master equation reduces to a semi-classical Smoluchowski equation describing non-inertial quantum diffusion in configuration space. The Wigner function formulation of quantum Brownian motion is further illustrated by finding quantum corrections to the Kramers escape rate, which, in appropriate limits, reduce to those yielded via quantum generalizations of reaction rate theory.
The master equation for a linear open quantum system in a general environment is derived using a stochastic approach. This is an alternative derivation to that of Hu, Paz and Zhang, which was based on the direct computation of path integrals, or to that of Halliwell and Yu, based on the evolution of the Wigner function for a linear closed quantum system. We first show by using the influence functinal formalism that the reduced Wigner function for the open system coincides with a distribution function resulting from averaging both over the initial conditions and the stochastic source of a formal Langevin equation. The master equation for the reduced Wigner function can then be deduced as a Fokker-Planck equation obtained from the formal Langevin equation.
An open quantum system is a quantum system that interacts with some environment whose degrees of freedom have been coarse grained away. This model describes non-equilibrium processes more general than scattering-matrix formulations. Furthermore, the microscopically-derived environment provides a model of noise, dissipation and decoherence far more general than Markovian (white noise) models. The latter are fully characterized by Lindblad equations and can be motivated phenomenologically. Non-Markovian processes consistently account for backreaction with the environment and can incorporate effects such as finite temperature and spatial correlations. We consider linear systems with bilinear coupling to the environment, or quantum Brownian motion, and nonlinear systems with weak coupling to the environment. For linear systems we provide exact solutions with analytical results for a variety of spectral densities. Furthermore, we point out an important mathematical subtlety which led to incorrect master-equation coefficients in earlier derivations, given nonlocal dissipation. For nonlinear systems we provide perturbative solutions by translating the formalism of canonical perturbation theory into the context of master equations. It is shown that unavoidable degeneracy causes an unfortunate reduction in accuracy between perturbative master equations and their solutions. We also extend the famous theorem of Lindblad, Gorini, Kossakowski and Sudarshan on completely positivity to non-Markovian master equations. Our application is primarily to model atoms interacting via a common electromagnetic field. The electromagnetic field contains correlations in both space and time, which are related to its relativistic (photon-mediated) nature. As such, atoms residing in the same field experience different environmental effects depending upon their relative position and orientation. Our more accurate solutions were necessary to assess sudden death of entanglement at zero temperature. In contrast to previous claims, we found that all initial states of two-level atoms undergo finite-time disentanglement. We were also able to access regimes which cannot be described by Lindblad equations and other simpler methods, such as near resonance. Finally we revisit the infamous Abraham-Lorentz force, wherein a single particle in motion experiences backreaction from the electromagnetic field. This leads to a number of well-known problems including pre-acceleration and runaway solutions. We found a more a more-suitable open-system treatment of the nonrelativistic particle to be perfectly causal and dissipative without any extraneous requirements for finite size of the particle, weak coupling to the field, etc..
In this review we discuss recent progress in the theory of open quantum systems based on non-MarkovianNon-Markovian quantum state diffusionQuantum state diffusion equation and master equationsMaster equation. In particular, we show that an exact master equation for an open quantum system consisting of a few qubits can be explicitly constructed by using the corresponding non-Markovian quantum state diffusion equation. The exact master equation arises naturally from the quantum decoherence dynamics of qubit systems collectively interacting with a colored noise. We illustrate our general theoretical formalism by the explicit construction of a three-qubit system coupled to a non-Markovian bosonic environment. This exact qubit master equation accurately characterizes the time evolution of the qubit system in various parameter domains, and paves the way for investigation of the memory effect of an open quantum system in a non-Markovian regime without any approximation.