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arXiv:quant-ph/0505123 · Physical Review A

Mapping the Schrödinger picture of open quantum dynamics

Thomas F. Jordan, Anil Shaji, E. C. G. Sudarshan

Published Jan 18, 2006• 20 citations
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Abstract

For systems described by finite matrices, an affine form is developed for the maps that describe evolution of density matrices for a quantum system that interacts with another. This is established directly from the Heisenberg picture. It separates elements that depend only on the dynamics from those that depend on the state of the two systems. While the equivalent linear map is generally not completely positive, the homogeneous part of the affine maps is, and is shown to be composed of multiplication operations that come simply from the Hamiltonian for the larger system. The inhomogeneous part is shown to be zero if and only if the map does not increase the trace of the square of any density matrix. Properties are worked out in detail for two-qubit examples.

DOI
10.1103/physreva.73.012106

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For systems described by finite matrices, an affine form is developed for the maps that describe evolution of density matrices for a quantum system that interacts with another. This is established directly from the Heisenberg picture. It separates elements that depend only on the dynamics from those that depend on the state of the two systems. While the equivalent linear map is generally not completely positive, the homogeneous part of the affine maps is, and is shown to be composed of multiplication operations that come simply from the Hamiltonian for the larger system. The inhomogeneous part is shown to be zero if and only if the map does not increase the trace of the square of any density matrix. Properties are worked out in detail for two-qubit examples.
For quantum systems described by finite matrices, linear and affine maps of matrices are shown to provide equivalent descriptions of evolution of density matrices for a subsystem caused by unitary Hamiltonian evolution in a larger system; an affine map can be replaced by a linear map, and a linear map can be replaced by an affine map. There may be significant advantage in using an affine map. The linear map is generally not completely positive, but the linear part of an equivalent affine map can be chosen to be completely positive and related in the simplest possible way to the unitary Hamiltonian evolution in the larger system.
Linear maps of matrices describing the evolution of density matrices for a quantum system initially entangled with another are identified and found to be not always completely positive. They can even map a positive matrix to a matrix that is not positive, unless we restrict the domain on which the map acts. Nevertheless, their form is similar to that of completely positive maps. Only some minus signs are inserted in the operator-sum representation. Each map is the difference of two completely positive maps. The maps are first obtained as maps of mean values and then as maps of basis matrices. These forms also prove to be useful. An example for two entangled qubits is worked out in detail. The relation to earlier work is discussed.
We study the influence of the preparation of an open quantum system on its reduced time evolution. In contrast to the frequently considered case of an initial preparation where the total density matrix factorizes into a product of a system density matrix and a bath density matrix the time evolution generally is no longer governed by a linear map nor is this map affine. Put differently, the evolution is truly nonlinear and cannot be cast into the form of a linear map plus a term that is independent of the initial density matrix of the open quantum system. As a consequence, the inhomogeneity that emerges in formally exact generalized master equations is in fact a nonlinear term that vanishes for a factorizing initial state. The general results are elucidated with the example of two interacting spins prepared at thermal equilibrium with one spin subjected to an external field. The second spin represents the environment. The field allows the preparation of mixed density matrices of the first spin that can be represented as a convex combination of two limiting pure states, i.e., the preparable reduced density matrices make up a convex set. Moreover, the map from these reduced density matrices onto the corresponding density matrices of the total system is affine only for vanishing coupling between the spins. In general, the set of the accessible total density matrices is nonconvex.
The most general evolution of the density matrix of a quantum system with a finite-dimensional state space is by stochastic maps which take a density matrix linearly into the set of density matrices. These dynamical stochastic maps form a linear convex set that may be viewed as supermatrices. The property of Hermiticity of density matrices renders an associated supermatrix Hermitian and hence diagonalizable. The positivity of the density matrix does not make the associated supermatrix positive though. If the map itself is positive, it is called completely positive and it has a simple parametrization. This is extended to all positive (not completely positive) maps. A general dynamical map that does not preserve the norm of the density matrices it acts on can be thought of as the contraction of a norm-preserving map of an extended system. The reconstruction of such extended dynamics is also given.
A basic linearity of quantum dynamics, that density matrices are mapped linearly to density matrices, is proven very simply for a system that does not interact with anything else. It is assumed that at each time the physical quantities and states are described by the usual linear structures of quantum mechanics. Beyond that, the proof assumes only that the dynamics does not depend on anything outside the system but must allow the system to be described as part of a larger system. The basic linearity is linked with previously established results to complete a simple derivation of the linear Schr\"odinger equation. For this it is assumed that density matrices are mapped one-to-one onto density matrices. An alternative is to assume that pure states are mapped one-to-one onto pure states and that entropy does not decrease.
The operator-sum decomposition of a map from one density matrix to another has many applications in quantum information science. To this mapping there corresponds an affine map which provides a geometric description of the map of the density matrix in terms of the polarization vector representation. This has been thoroughly explored for qubits since the components of the polarization vector are measurable quantities (corresponding to expectation values of Hermitian operators) and also because it enables the description of map domains geometrically. Here we extend the operator-sum--affine-map correspondence to qudits, briefly discuss general properties of the map and the form for some particular cases, and provide several explicit results for qutrit maps. We use the affine map and a singular-value-like decomposition to find positivity constraints that provide a symmetry for small polarization vector magnitudes (states which are closer to the maximally mixed state), which is broken as the polarization vector increases in magnitude (a state becomes more pure). The dependence of this symmetry on the magnitude of the polarization vector implies the polar decomposition of the map cannot be used as it can for the qubit case. However, it still leads us to a connection between positivity and purity for general ddd-state systems.