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arXiv:quant-ph/0408164

On the notion of a macroscopic quantum system

Andrei Yu. Khrennikov

Published Aug 26, 2004• 0 citations
arXivHTMLPDF

Abstract

It is proposed to define "quantumness" of a system (micro or macroscopic, physical, biological, social, political) by starting with understanding that quantum mechanics is a statistical theory. It says us only about probability distributions. The only possible criteria of quantum behaviour are statistical ones. Therefore I propose to consider any system which produces quantum statistics as quantum ("quantumlike"). A possible test is based on the interference of probabilities. I was mainly interested in using such an approach to "quantumness" to extend the domain of applications of quantum mathematical formalism and especially to apply it to cognitive sciences. There were done experiments on interference of probabilities for ensembles of students and a nontrivial interference was really found. One could say that the quantum statistical behaviour might be expected. But the problem was not so trivial. Yes, we might expect nonclassical statistics, but there was no reason to get the quantum one, i.e., cos-interference. But we got it!

DOI
10.48550/arxiv.quant-ph/0408164

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It is proposed to define "quantumness" of a system (micro or macroscopic, physical, biological, social, political) by starting with understanding that quantum mechanics is a statistical theory. It says us only about probability distributions. The only possible criteria of quantum behaviour are statistical ones. Therefore I propose to consider any system which produces quantum statistics as quantum ("quantumlike"). A possible test is based on the interference of probabilities. I was mainly interested in using such an approach to "quantumness" to extend the domain of applications of quantum mathematical formalism and especially to apply it to cognitive sciences. There were done experiments on interference of probabilities for ensembles of students and a nontrivial interference was really found. One could say that the quantum statistical behaviour might be expected. But the problem was not so trivial. Yes, we might expect nonclassical statistics, but there was no reason to get the quantum one, i.e., cos-interference. But we got it!
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We present a quantum-like (QL) model in that contexts (complexes of e.g. mental, social, biological, economic or even political conditions) are represented by complex probability amplitudes. This approach gives the possibility to apply the mathematical quantum formalism to probabilities induced in any domain of science. In our model quantum randomness appears not as irreducible randomness (as it is commonly accepted in conventional quantum mechanics, e.g., by von Neumann and Dirac), but as a consequence of obtaining incomplete information about a system. We pay main attention to the QL description of processing of incomplete information. Our QL model can be useful in cognitive, social and political sciences as well as economics and artificial intelligence. In this paper we consider in a more detail one special application -- QL modeling of brain's functioning. The brain is modeled as a QL-computer.
Recently, the possibility of investigating single molecule, or single spin observables, as well as the necessity of a better understanding of the mechanisms underlying quantum dynamics in order to obtain nanoscale devices and nanostructered materials suitable for quantum computing tasks, have revived the interest in foundational aspects of quantum statistical mechanics. This thesis aims to give a contribution to this field by re-considering the statistical characterization of a quantum system at the light of some paradigmatic changes in our understanding of quantum theory which have taken place in the last two decades. In particular the impressive development of quantum information theory has changed the perceptions of quantum entanglement: for a long time it has been considered a somewhat paradoxical property of the matter at the atomic scale, but now it is regarded as an essential and ubiquitous phenomenon whose consequences are affecting the very macroscopic world that we experience. Still the decoherence program has brought out the importance of considering a quantum system together with its environment in order to clarify some key aspects of quantum dynamics. Thus, we start from the idea that quantum correlations are ubiquitous and somewhat uncontrollable in systems with many degrees of freedom which are typically considered in statistical mechanics. As a consequence we assume the standpoint that quantum statistical mechanics has not to be based on the underlying idea of a collection of many, independent quantum systems but rather it has to emerge at the level of a global wavefunction (pure state) which describes the system as well as its environment as a whole. In order to investigate the consequences of these assumptions we study the equilibrium distribution of an isolated quantum system. This is defined, in analogy with the ergodic foundations of classical statistical mechanics, on the basis of the time evolution of the quantum state. Then, we study the emergence of thermodynamic properties in a quantum system by studying the probability distribution of some function of interests, as the entropy and the equilibrium state of a subsystem, on Ensembles of Pure States. Such a probability distribution is derived from the geometry of the Hilbert space, and the theoretical tools suitable for its characterization are developed. On the one hand we perform a numerical sampling of the ensemble distributions by employing Monte Carlo techniques, on the other hand simpler analytical approximation of the geometrical distributions are derived by means of a maximum entropy principle. Model systems composed of an ensemble of spins are chosen to illustrate the salient features which emerge from the developed theoretical framework: the main point is that the Ensemble Distributions of “thermodynamic observables” (entropy or equilibrium state of a subsystem) are sharply peaked around a typical value. From the analysis it emerges that each of the overwhelming majority of the wavefunctions which has appreciable weight in the considered ensemble, is characterized by the same value of the “macroscopic” functions. This is a striking evidence of the “typicality” of these properties. In the essence, our impossibility to know the state of the system in detail does not matter, just for the remarkable fact that almost all quantum states behave essentially in the same way. By virtue of this typicality the study of the behaviour of the typical values of the thermodynamic function become meaningful. Notably, under certain conditions, one recovers the results of standard statistical mechanics, that is, the equilibrium average of the state of a subsystem can be cast in the Boltzmann canonical form at the temperature given by the usual thermodynamical relation . In the second part of the thesis we consider the dynamical aspects of the equilibrium state of a subsystem interacting with its environment. The fluctuations around the equilibrium average critically depends on the entanglement between the system and the environment and on the form of the interaction Hamiltonian. The connection between the dynamics of the fluctuations of an observable at the equilibrium and the relaxation toward the equilibrium from a “non typical” initial value is also investigated with the aid of simple model systems. The study presented in this thesis was partly motivated by a critical analysis of the statistical methods available for the theoretical modelling of magnetic resonance experiments. One of these, the Stochastic Liouville Equation, has been employed in a work completed during the first year of my Ph.D. program in order to interpret some feature of a two dimensional electron spin resonance experiment, [Fresch B., Frezzato D., Moro G. J., Kothe G., Freed J. H.; J. Phys. Chem. B., 110, 24238, (2006)].
We stress the notion of statistical experiment, which is mandatory for quantum mechanics, and recall Ludwig's foundation of quantum mechanics, which provides the most general framework to deal with statistical experiments giving evidence for particles. In this approach particles appear as interaction carriers between preparation and registration apparatuses. We further briefly point out the more modern and versatile formalism of quantum theory, stressing the relevance of probabilistic concepts in its formulation. At last we discuss the role of macrosystems, focusing on quantum field theory for their description and introducing objective state parameters for them.