Thermodynamics is a macroscopic physical theory whose two very general laws are independent of any underlying dynamical laws and structures. Nevertheless, its generality enables us to understand a broad spectrum of phenomena in physics, information science and biology. Does thermodynamics then imply any results in quantum information theory? Taking accessible information in a system as an example, we show that thermodynamics implies a weaker bound on it than the quantum mechanical one (the Holevo bound). In other words, if any post-quantum physics should allow more information storage it could still be under the umbrella of thermodynamics.
Thermodynamics is a macroscopic physical theory whose two very general laws are independent of any underlying dynamical laws and structures. Nevertheless, its generality enables us to understand a broad spectrum of phenomena in physics, information science and biology. Does thermodynamics then imply any results in quantum information theory? Taking accessible information in a system as an example, we show that thermodynamics implies a weaker bound on it than the quantum mechanical one (the Holevo bound). In other words, if any post-quantum physics should allow more information storage it could still be under the umbrella of thermodynamics.
We review a general theory of thermodynamics of information processing. The background of this topic is the recently-developed nonequilibrium statistical mechanics and quantum (and classical) information theory. These theories are closely related to the modern technologies to manipulate and observe small systems; for example, macromolecules and colloidal particles in the classical regime, and quantum-optical systems and quantum dots in the quantum regime. First, we review a generalization of the second law of thermodynamics to the situations in which small thermodynamic systems are subject to quantum feedback control. The generalized second law is expressed in terms of an inequality that includes the term of information obtained by the measurement, as well as the thermodynamic quantities such as the free energy. This inequality leads to the fundamental upper bound of the work that can be extracted by a “Maxwell's demon”, which can be regarded as a feedback controller with a memory that stores measurement outcomes. Second, we review generalizations of the second law of thermodynamics to the measurement and information erasure processes of the memory of the demon that is a quantum system. The generalized second laws consist of inequalities that identify the lower bounds of the energy costs that are needed for the measurement and the information erasure. The inequality for the erasure leads to the celebrated Landauer's principle for a special case. Moreover, these inequalities enable us to reconcile Maxwell's demon with the second law of thermodynamics. In these inequalities, thermodynamic quantities and information contents are treated on an equal footing. In fact, the inequalities are model-independent, so that they can be applied to a broad class of information processing. Therefore, these inequalities can be called the second law of “information thermodynamics”.
Thermodynamics is a highly successful macroscopic theory widely used across the natural sciences and for the construction of everyday devices, from car engines to solar cells. With thermodynamics predating quantum theory, research now aims to uncover the thermodynamic laws that govern finite size systems which may in addition host quantum effects. Recent theoretical breakthroughs include the characterisation of the efficiency of quantum thermal engines, the extension of classical non-equilibrium fluctuation theorems to the quantum regime and a new thermodynamic resource theory has led to the discovery of a set of second laws for finite size systems. These results have substantially advanced our understanding of nanoscale thermodynamics, however putting a finger on what is genuinely quantum in quantum thermodynamics has remained a challenge. Here we identify information processing tasks, the so-called projections, that can only be formulated within the framework of quantum mechanics. We show that the physical realisation of such projections can come with a non-trivial thermodynamic work only for quantum states with coherences. This contrasts with information erasure, first investigated by Landauer, for which a thermodynamic work cost applies for classical and quantum erasure alike. Repercussions on quantum work fluctuation relations and thermodynamic single-shot approaches are also discussed.
Thermodynamics is a highly successful macroscopic theory widely used across the natural sciences and for the construction of everyday devices, from car engines to solar cells. With thermodynamics predating quantum theory, research now aims to uncover the thermodynamic laws that govern finite size systems which may in addition host quantum effects. Recent theoretical breakthroughs include the characterisation of the efficiency of quantum thermal engines, the extension of classical non-equilibrium fluctuation theorems to the quantum regime and a new thermodynamic resource theory has led to the discovery of a set of second laws for finite size systems. These results have substantially advanced our understanding of nanoscale thermodynamics, however putting a finger on what is genuinely quantum in quantum thermodynamics has remained a challenge. Here we identify information processing tasks, the so-called projections, that can only be formulated within the framework of quantum mechanics. We show that the physical realisation of such projections can come with a non-trivial thermodynamic work only for quantum states with coherences. This contrasts with information erasure, first investigated by Landauer, for which a thermodynamic work cost applies for classical and quantum erasure alike. Repercussions on quantum work fluctuation relations and thermodynamic single-shot approaches are also discussed.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Generalized probabilistic theories (GPTs) provide a unified framework for describing probabilistic physical theories, encompassing classical and quantum theories as well as hypothetical theories beyond quantum mechanics. Since most GPTs are highly unrealistic and far removed from known physical theories, it is important to constrain them by physically reasonable principles. One of the most important such principles is consistency with thermodynamics, which has been extensively studied through toy models involving semipermeable membranes (SPMs) implementing measurements. On the other hand, information thermodynamics, which plays a central role in understanding the relationship between measurement and thermodynamics in classical and quantum theory, has remained largely undeveloped in GPTs. In this work, we construct information thermodynamics in GPTs and provide a unified framework for analyzing the relationship between measurement, feedback, information erasure, and the second law of thermodynamics. We also formulate a general framework for SPM models and analyze the thermodynamic cost of measurements implemented by SPMs. As a result, we show that no work can be extracted in contradiction with the second law as long as the measurement processes are consistent with entropy nondecrease, and derive sufficient conditions for this property for several entropy definitions proposed in GPTs. Moreover, by considering measurement processes violating these conditions, we construct explicit GPT systems realizing isothermal SPM cycles from which positive work can be extracted. These results demonstrate that violations of the second law can arise from the lack of fundamental entropy properties or discrepancies between entropy definitions, and provide a unified and model-independent foundation for understanding the relationship between thermodynamics and measurement in GPTs.
The purpose of this paper is to discuss the hypothesis that the second law of thermodynamics and its corollaries are manifestations of microscopic quantum effects of the same nature but more general than those described by the Heisenberg uncertainty principle. This hypothesis is new to physics. Energy is a property of matter that has unified our understanding of physical phenomena. It appears prominently in both mechanical and thermodynamic theories. It is defined by the first law of thermodynamics, and its conservation is one of the keystones of analyses of both microscopic and macroscopic phenomena. Adiabatic availability--the amount of work that can be extracted from a system adiabatically--is also a property of matter but has not been accepted with the same unanimity as energy. Experience, especially with large bodies, indicates that not all the energy of a system is available in the form of work. For a given system, say atoms