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arXiv:quant-ph/0208123 · Physical review. D. Particles, fields, gravitation, and cosmology/Physical review. D. Particles and fields

Weisskopf-Wigner decay theory for the energy-driven stochastic Schrödinger equation

Stephen L. Adler

Published Jan 17, 2003• 33 citations
arXivHTMLPDF

Abstract

We generalize the Weisskopf-Wigner theory for the line shape and transition rates of decaying states to the case of the energy-driven stochastic Schr\"odinger equation that has been used as a phenomenology for state vector reduction. Within the standard approximations used in the Weisskopf-Wigner analysis, and assuming that the perturbing potential inducing the decay has vanishing matrix elements within the degenerate manifold containing the decaying state, the stochastic Schr\"odinger equation linearizes. Solving the linearized equations, we find no change from the standard analysis in the line shape or the transition rate per unit time. The only effect of the stochastic terms is to alter the early time transient behavior of the decay, in a way that eliminates the quantum Zeno effect. We apply our results to estimate experimental bounds on the parameter governing the stochastic effects. In addition, elegant stochastic-theoretic methods suggested by Di\'osi are used to rederive the principal results, without the assumptions needed to linearize the stochastic equation, and to give analogous results for the Rabi oscillations of a two-level system.

DOI
10.1103/physrevd.67.025007

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We generalize the Weisskopf-Wigner theory for the line shape and transition rates of decaying states to the case of the energy-driven stochastic Schr"odinger equation that has been used as a phenomenology for state vector reduction. Within the standard approximations used in the Weisskopf-Wigner analysis, and assuming that the perturbing potential inducing the decay has vanishing matrix elements within the degenerate manifold containing the decaying state, the stochastic Schr"odinger equation linearizes. Solving the linearized equations, we find no change from the standard analysis in the line shape or the transition rate per unit time. The only effect of the stochastic terms is to alter the early time transient behavior of the decay, in a way that eliminates the quantum Zeno effect. We apply our results to estimate experimental bounds on the parameter governing the stochastic effects. In addition, elegant stochastic-theoretic methods suggested by Di'osi are used to rederive the principal results, without the assumptions needed to linearize the stochastic equation, and to give analogous results for the Rabi oscillations of a two-level system.
It is pointed out that the usual Heisenberg equations-of-motion or Liouvillian superoperator perturbation-theory approaches to systems with arbitrary statistical ensembles can give spurious, nonconvergent results when attempts are made to calculate the expectation value for certain operators which commute with the zeroth-order Hamiltonian. The non-Markovian, long-time tail of the Weisskopf-Wigner spontaneous-emission decay of a two-level atom is presented as an example of this failure. The general reason for such failures is elucidated and a new method applicable to arbitrary equilibrium or nonequilibrium statistical ensembles is formulated. The new method is applied to the same example of spontaneous emission to derive the correct short- and long-time behavior. The physical model of a two-level atom is discussed and some mathematical techniques of general usefulness are presented. The present results are also briefly discussed in the context of previous work on nonexponential decay. A fully quantum-mechanical definition of time-dependent spectral line shape is given in terms of the response of a two-level---atom detector with variable frequency interacting with electromagnetic radiation. The non-Lorentzian line shape recorded by such a detector for the spontaneous emission of a source two-level atom is calculated as another example of a problem for which the usual methods give incorrect results. The extension of the present method to Liouvillian or master-equation approaches is discussed.
There exists the well-known approximate expression describing the large time behavior of matrix elements of the evolution operator in quantum theory: < U(t)>≃ exp (at). This expression plays the crucial role in considerations of problems of quantum decoherence, radiation, decay, scattering theory, stochastic limit, derivation of master and kinetic equations etc. This expression was obtained in the Weisskopf–Wigner approximation and in the van Hove (stochastic) limit. We derive the exact general formula which includes the higher order corrections to the above approximate expression: <U(t)>= exp (At+B+C(t)). The constants A and B and the oscillating function C(t) are computed in perturbation theory. The method of perturbation of spectra and renormalized wave operators is used. The formula is valid for a general class of Hamiltonians used in statistical physics and quantum field theory.
The description of an open quantum system's decay almost always requires several approximations so as to remain tractable. In this Letter, we first revisit the meaning, domain, and seeming contradictions of a few of the most widely used of such approximations: (semigroup) Markovianity, linear response theory, Wigner-Weisskopf approximation, and rotating-wave approximation. Second, we derive an effective time-dependent decay theory and corresponding generalized quantum regression relations for an open quantum system linearly coupled to an environment. This theory covers all timescales and subsumes the Markovian and linear-response results as limiting cases. Finally, we apply our theory to the phenomenon of quantum friction.
This work is about a quantum-mechanical generalisation of transition rate theory that accounts for temperature-dependent quantum-dynamical effects. The starting point of this investigation is a formulation of the classical transmission coefficient where the activated dynamics is needed to obtain the time evolution of the classical state function and the rate is expressed as an average flux in momentum space. Traditional approaches to quantum transition rate theory are briefly discussed, with emphasis on the fact that these do not generally require knowledge of the open quantum dynamics. The latter can be studied by means of the Lindblad equation for mixed states, which is shown to be analogous to an average over realisations of a certain type of stochastic Schrödinger dynamics. The stochastic evolution in Hilbert space is used in combination with an ansatz for the wave function as a Gaussian wave packet to show that under appropriate assumptions the stochastic Schrödinger equation converges to the classical Langevin equation. A novel formulation of the quantum transmission coefficient is presented which features a quantum-mechanical version of the state function obtained via the density operator, so that the activated quantum dynamics can be taken into account by solving the Lindblad equation. A numerical investigation of the quantum transmission coefficient thus obtained for different temperatures is carried out, along with a comparison to the classical results. The quantum-mechanical transmission coefficient is found to display some expected features, such as vanishing in the limit as t → 0, displaying a “plateau” value for certain values of the temperature, and decaying to zero exponentially fast when the fundamental assumptions of TRT do not hold. Additionally the plateau value of the quantum transmission coefficient is found to be smaller than the classical counterpart in all regimes, and to approach the corresponding classical value in the limit of large temperatures.
Abstract This paper presents a comprehensive investigation of the problem of a harmonic oscillator with time-depending frequencies in the framework of the Vlasov theory and the Wigner function apparatus for quantum systems in the phase space. A new method is proposed to find an exact solution of this problem using a relation of the Vlasov equation chain with the Schrödinger equation and with the Moyal equation for the Wigner function. A method of averaging the energy function over the Wigner function in the phase space can be used to obtain time-dependent energy spectrum for a quantum system. The Vlasov equation solution can be represented in the form of characteristics satisfying the Hill equation. A particular case of the Hill equation, namely the Mathieu equation with unstable solutions, has been considered in details. An analysis of the dynamics of an unstable quantum system shows that the phase space square bounded with the Wigner function level line conserves in time, but the phase space square bounded with the energy function line increases. In this case the Vlasov equation characteristic is situated on the crosspoint of the Wigner function level line and the energy function line. This crosspoint moves in time with a trajectory that represents the unstable system dynamics. Each such trajectory has its own energy, and the averaging of these energies by the Wigner function results in time-dependent discreet energy spectrum for the whole system. An explicit expression has been obtained for the Wigner function of the 4th rank in the generalized phase space x , p , p ̇ , p ̈ .
A method is presented by which the stochastic Schrodinger equation can be derived for systems coupled to a reservoir in cases in which the system-reservoir interaction is non-Markovian, and under the condition that the initial system reservoir state is decorrelated. The method is based on a Heisenberg equation of motion approach applied in conjunction with a technique of dealing with system-reservoir interactions introduced by Mollow in his treatment of the AC Stark effect. The general Diosi-Strunz stochastic Schrodinger equation is regained, but the method developed here offers a different perspective on obtaining the final form of this equation for specific applications. The method is illustrated for a damped two level atom, a driven damped harmonic oscillator, and quantum Brownian motion.