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arXiv:quant-ph/0107047 · Zeitschrift für Naturforschung A

Brownian Motion: the Quantum Perspective

Bassano Vacchini

Published Feb 1, 2001• 5 citations
arXivHTMLPDF

Abstract

Abstract We briefly go through the problem of the quantum description of Brownian motion, concentrating on recent results about the connection between the dynamics of the particle and dynamic structure factor of the medium. - 05.40.Jc, 05.30.Fk, 05.30.Jp, 03.65.Yz
DOI
10.1515/zna-2001-0143

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These notes are based on a course of lectures given by Professor Nelson at Princeton during the spring term of 1966. The subject of Brownian motion has long been of interest in mathematical probability. In these lectures, Professor Nelson traces the history of earlier work in Brownian motion, both the mathematical theory, and the natural phenomenon with its physical interpretations. He continues through recent dynamical theories of Brownian motion, and concludes with a discussion of the relevance of these theories to quantum field theory and quantum statistical mechanics.
We first point out that nonrelativistic quantum mechanics formulated at imaginary time s = it can formally be recognized as the Fokker-Planck description of a classical Brownian motion, which occurs (in general) in a medium where particles are absorbed and emitted. We next offer a new formulation of quantum dynamics, which is basically the Langevin treatment of that Brownian motion. More explicitly, we derive a noise average representation of the transition probability W ( X", s"|X', s' ) in terms of the solutions to a Langevin equation with a Gaussian white noise. Upon analytic continuation back to real time W ( X", s"|X', s' ) becomes the propagator of the original Schrödinger equation, namely we have ⟨ X", t"|X', t' ⟩ = W ( X", it"|X', it' ). The main advantage of this approach is to permit a systematic application to quantum-dynamical problems of the mathematical techniques developed in the theory of classical stochastic processes, even when vector potentials and/or time-dependent potentials are present.
A fully quantum treatment of Einstein's Brownian motion is given, stressing in particular the role played by the two original requirements of translational invariance and connection between dynamics of the Brownian particle and atomic nature of the medium. The former leads to a clearcut relationship with a generator of translation-covariant quantum-dynamical semi-groups recently characterized by Holevo, the latter to a formulation of the fluctuation-dissipation theorem in terms of the dynamic structure factor, a two-point correlation function introduced in seminal work by Van Hove, directly related to density fluctuations in the medium and therefore to its atomistic, discrete nature. A microphysical expression for the generally temperature dependent friction coefficient is given in terms of the dynamic structure factor and of the interaction potential describing the single collisions. A comparison with the Caldeira-Leggett model is drawn, especially in view of the requirement of translational invariance, further characterizing general structures of reduced dynamics arising in the presence of symmetry under translations.