Transformation Relation of Two Descriptive Systems between Quantum Mechanics and Classical Statistical Mechanics and Dynamic Foundation of Classical Statistical Physics
Based on the concept of ensemble, it is proved in the manuscript that the probability amplitude function can also been used to describe the classical statistical system. The motion equations of probability amplitude functions of classical statistical system are obtained, which are similar to that in quantum mechanics. It is also proved in the meantime that microsystems that obey quantum mechanics can also be described in the forms of classical statistical mechanics and deterministic classical mechanics. The quantum revised formula of classical interaction force and the revised Liouville's equations are also obtained. In this way, the transformation of two descriptive forms between classical mechanics and quantum mechanics is achieved. A new and rational interpretation about quantum mechanics, including the meaning of wave function, the potential barrier penetration of microparticles, the Uncertainty relation, the wave-particle duality, the essence of spin and the Bell's inequality and so on, is provided in the paper. Based on the transformation, two fundamental hypotheses are put forward as the basic postulates of classical statistical physics. The equal probability hypothesis in the equilibrium states is given up. The united description of nonequilibrium state mechanics and equilibrium state statistical mechanics is reached, and the so-called reversibility paradox can also be eliminated.
Based on the concept of ensemble, it is proved in the manuscript that the probability amplitude function can also been used to describe the classical statistical system. The motion equations of probability amplitude functions of classical statistical system are obtained, which are similar to that in quantum mechanics. It is also proved in the meantime that microsystems that obey quantum mechanics can also be described in the forms of classical statistical mechanics and deterministic classical mechanics. The quantum revised formula of classical interaction force and the revised Liouville's equations are also obtained. In this way, the transformation of two descriptive forms between classical mechanics and quantum mechanics is achieved. A new and rational interpretation about quantum mechanics, including the meaning of wave function, the potential barrier penetration of microparticles, the Uncertainty relation, the wave-particle duality, the essence of spin and the Bell's inequality and so on, is provided in the paper. Based on the transformation, two fundamental hypotheses are put forward as the basic postulates of classical statistical physics. The equal probability hypothesis in the equilibrium states is given up. The united description of nonequilibrium state mechanics and equilibrium state statistical mechanics is reached, and the so-called reversibility paradox can also be eliminated.
We propose a new approach concerning the introduction of time-irreversibility in statistical mechanics. It is based on a transition function defined in terms of path integral and verifying a time-irreversible equation. We show first how dynamic processes may enter in the description of equilibrium states. In order to do that a characteristic time is associated with closed paths. For large isolated systems at equilibrium or for systems in contact with a thermostat our results are identical with those obtained with the Gibbs ensemble methods. For a model used in the microscopic approaches of the brownian motion no new basic assumption is required to predict a transition from a quantum state to a classical one exhibiting a time-irreversible behavior. This demonstration is sufficient to show that very well accepted approximations can lead to time-irreversible behaviors for a large class of systems. The difference between our work and the system+reservoir approaches is underlined. Here equilibrium states and irreversible processes are described on the same footing representing a progress in the question of time-irreversibility in statistical physics. The transition function is also used for describing a small system for which there is no thermodynamics. By adding to the transition function a second one characterizing the reverse motion we may describe time-reversible systems. In a simple case we replace two real valued transition functions by a complex function verifying a Schrodinger like equation. From this we see how to break the time-reversibility of this equation and how to investigate the connection quantum mechanics-thermodynamics from a very fundamental point of view.
We address the paradoxical transformation of a classical-mechanical particle motion when the space and time scales of observation pass below the uncertainty principle threshold. This is analyzed in the language of classical statistical mechanics, considering specifically many-particle systems inhomogeneous along one spatial direction. We employ the density functional formalism in its square-gradient form and find: (i) The macroscopic solution is analogous to the classical trajectory of a particle under a potential of force given by (minus) the free energy density. Whereas, (ii) fluctuations around the solution in (i) are equal to the quantum-mechanical wave functions of a particle under a potential given by the curvature of the free energy density. We illustrate this situation with three textbook examples: A particle in a box, the harmonic oscillator, and the hydrogen atom. We show that their time-independent Schrödinger equation wave functions describe, respectively, the fluctuations of a fluid interface, of critical point fluctuations, and of a confined ideal gas. At large scales, sharp probability distributions make fluctuations irrelevant; the vanishing of the first variation yields the macroscopically observable statistical-mechanical non-uniformity, equivalent to the classical particle trajectory. But at sufficiently small scales, with necessarily very few particles, distributions appear much wider, fluctuations dominate, and one obtains the Schrödinger equation (for the microscopic potential).
Based on the Bohr's correspondence principle it is shown that relativistic mechanics and quantum mechanics may be considered as generalizations of classical mechanics. A comparative description of relativistic and classical mechanics is given using three main principles: the definition of momentum, the main law of dynamics (Newton's second law) and the law of conservation of energy. The difference of relativistic mechanics from classical mechanics is due to the new definition of momentum that is proportional to energy and velocity. It is shown that new relativistic laws of dynamics make it necessary to change kinematical relations of classical mechanics such as the law of velocity composition, coordinate transformation etc. It is demonstrated that quantum mechanics may be considered as a rational statistical generalization of classical mechanics. Statistical conformities in quantum mechanics are fundamental and are not due to the incomplete information about the system. From all possible multi-parametric statistical models the root model is most remarkable. Constructing of a root multi-parametric statistical model leads to obtaining such frequencies and base functions in Fourier decomposition so that classical laws of motion are fulfilled in average. Root model leads to a consistent condition that connects eigenvectors and eigenvalues of a mechanical system that is described by a matrix equation of Heisenberg. Matrix equation of Heisenberg leads to an operator equation. The solution of the operator equation may be considered as the construction of Hamiltonian of the system and a move to the Schrodinger representation. The considered approach naturally leads to the notion of momentum operator, fundamental commutation relations, density matrix and Liouville equation construction etc.
A wave dynamics of fields φ(p, q; t) ∈ L2(Γ) over the phase space Γ(p, q) of a classical system 𝒮 is derived from the Liouville theorem. We define the energy contained in a given field φ(p, q; t). We show that for a special class of fields, selected on physical grounds, the energy spectrum is given by a time-independent Schrödinger equation. This allows us to associate with 𝒮 an ordinary quantum system Q such that the values of the quantized energy coincide for the fields in the phase space of 𝒮 and for Q. Then we make use of Wiener's stochastic integral based on the theory of Brownian motion to derive probabilities which are the same as those one would obtain through Born's statistical postulate of quantum theory. From this it follows that we can regard normalized fields φ(p, q; t) as ``probability amplitudes'' leading to a probability density function ρ(p, q; t) = φφ* in the sense of Gibbs' statistical mechanics. Our work therefore appears as a bridge between a statistical theory (in the sense of Gibbs) of a mechanical system 𝒮 and the usual quantum theory of the related quantum system Q.
Recently, the possibility of investigating single molecule, or single spin observables, as well as the necessity of a better understanding of the mechanisms underlying quantum dynamics in order to obtain nanoscale devices and nanostructered materials suitable for quantum computing tasks, have revived the interest in foundational aspects of quantum statistical mechanics. This thesis aims to give a contribution to this field by re-considering the statistical characterization of a quantum system at the light of some paradigmatic changes in our understanding of quantum theory which have taken place in the last two decades. In particular the impressive development of quantum information theory has changed the perceptions of quantum entanglement: for a long time it has been considered a somewhat paradoxical property of the matter at the atomic scale, but now it is regarded as an essential and ubiquitous phenomenon whose consequences are affecting the very macroscopic world that we experience. Still the decoherence program has brought out the importance of considering a quantum system together with its environment in order to clarify some key aspects of quantum dynamics. Thus, we start from the idea that quantum correlations are ubiquitous and somewhat uncontrollable in systems with many degrees of freedom which are typically considered in statistical mechanics. As a consequence we assume the standpoint that quantum statistical mechanics has not to be based on the underlying idea of a collection of many, independent quantum systems but rather it has to emerge at the level of a global wavefunction (pure state) which describes the system as well as its environment as a whole. In order to investigate the consequences of these assumptions we study the equilibrium distribution of an isolated quantum system. This is defined, in analogy with the ergodic foundations of classical statistical mechanics, on the basis of the time evolution of the quantum state. Then, we study the emergence of thermodynamic properties in a quantum system by studying the probability distribution of some function of interests, as the entropy and the equilibrium state of a subsystem, on Ensembles of Pure States. Such a probability distribution is derived from the geometry of the Hilbert space, and the theoretical tools suitable for its characterization are developed. On the one hand we perform a numerical sampling of the ensemble distributions by employing Monte Carlo techniques, on the other hand simpler analytical approximation of the geometrical distributions are derived by means of a maximum entropy principle. Model systems composed of an ensemble of spins are chosen to illustrate the salient features which emerge from the developed theoretical framework: the main point is that the Ensemble Distributions of “thermodynamic observables” (entropy or equilibrium state of a subsystem) are sharply peaked around a typical value. From the analysis it emerges that each of the overwhelming majority of the wavefunctions which has appreciable weight in the considered ensemble, is characterized by the same value of the “macroscopic” functions. This is a striking evidence of the “typicality” of these properties. In the essence, our impossibility to know the state of the system in detail does not matter, just for the remarkable fact that almost all quantum states behave essentially in the same way. By virtue of this typicality the study of the behaviour of the typical values of the thermodynamic function become meaningful. Notably, under certain conditions, one recovers the results of standard statistical mechanics, that is, the equilibrium average of the state of a subsystem can be cast in the Boltzmann canonical form at the temperature given by the usual thermodynamical relation . In the second part of the thesis we consider the dynamical aspects of the equilibrium state of a subsystem interacting with its environment. The fluctuations around the equilibrium average critically depends on the entanglement between the system and the environment and on the form of the interaction Hamiltonian. The connection between the dynamics of the fluctuations of an observable at the equilibrium and the relaxation toward the equilibrium from a “non typical” initial value is also investigated with the aid of simple model systems. The study presented in this thesis was partly motivated by a critical analysis of the statistical methods available for the theoretical modelling of magnetic resonance experiments. One of these, the Stochastic Liouville Equation, has been employed in a work completed during the first year of my Ph.D. program in order to interpret some feature of a two dimensional electron spin resonance experiment, [Fresch B., Frezzato D., Moro G. J., Kothe G., Freed J. H.; J. Phys. Chem. B., 110, 24238, (2006)].
Statistical classical mechanics and quantum mechanics are developed and well-known theories that represent a basis for modern physics. Statistical classical mechanics enable the derivation of the properties of large bodies by investigating the movements of small atoms and molecules which comprise these bodies using Newton's classical laws. Quantum mechanics defines the laws of movement of small particles at small atomic distances by considering them as probability waves. The laws of quantum mechanics are described by the Schrödinger equation. The laws of such movements are significantly different from the laws of movement of large bodies, such as planets or stones. The two described theories are well known and have been well studied. As these theories contain numerous paradoxes, many scientists doubt their internal consistencies. However, these paradoxes can be resolved within the framework of the existing physics without the introduction of new laws. To clarify the paper for the inexperienced reader, we include certain necessary basic concepts of statistical physics and quantum mechanics in this paper without the use of formulas. Exact formulas and explanations are included in the Appendices. The text is supplemented by illustrations to enhance the understanding of the paper. The paradoxes underlying thermodynamics and quantum mechanics are also discussed. The approaches to the solutions of these paradoxes are suggested. The first approach is dependent on the influence of the external observer (environment), which disrupts the correlations in the system. The second approach is based on the limits of the self-knowledge of the system for the case in which both the external observer and the environment are included in the considered system. The concepts of observable dynamics, ideal dynamics, and unpredictable dynamics are introduced. The phenomenon of complex (living) systems is contemplated from the point of view of these dynamics.