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arXiv:physics/0409148 · Physical Review A

Ultracold collisions of fermionic OD radicals

А. V. Avdeenkov, John L. Bohn

Published Feb 11, 2005• 29 citations
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Abstract

We discuss consequences of Fermi exchange symmetry on collisions of polar molecules at low temperatures (below 1 K), considering the OD radical as a prototype. At low fields and low temperatures, Fermi statistics can stabilize a gas of OD molecules against state-changing collisions. We find, however, that this stability does not extend to temperatures high enough to assist with evaporative cooling. In addition, we establish that a novel ``field-linked'' resonance state of OD dimers exists, in analogy with the similar states predicted for bosonic OH.

DOI
10.1103/physreva.71.022706

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We discuss consequences of Fermi exchange symmetry on collisions of polar molecules at low temperatures (below 1 K), considering the OD radical as a prototype. At low fields and low temperatures, Fermi statistics can stabilize a gas of OD molecules against state-changing collisions. We find, however, that this stability does not extend to temperatures high enough to assist with evaporative cooling. In addition, we establish that a novel ``field-linked'' resonance state of OD dimers exists, in analogy with the similar states predicted for bosonic OH.
The collisions at ultracold temperatures between 1Σ state diatomic polar molecules in a microwave field with a circular polarization are theoretically analyzed. We demonstrate the possibility of trapping polar molecules in the standing-wave electromagnetic field and a successful evaporative cooling not only for samples of molecules in their absolute ground states but in some rotationally excited states in the appropriate regions of frequencies of a field. Here we only discuss fermionic polar molecules at ultralow temperatures(1μK), considering RbK as a prototype.
Collisions at ultracold temperatures between ${}^{1}\phantom{\rule{-0.16em}{0ex}}\ensuremath{\Sigma}$-state diatomic polar molecules in a circularly polarized microwave field are theoretically analyzed. We demonstrate that elastic and inelastic collisions of polar molecules at ultracold temperatures are affected by an external microwave field and that they are enhanced at resonance frequencies. We show that the collision dynamics of polar molecules in a microwave field is largely determined by the long-range dipole-dipole interaction. Through this interaction, two polar molecules can resonantly exchange internal energy by undergoing a transition between neighboring rotational levels. This process may stabilize the system and enable the successive evaporative cooling of molecules. This paper discusses fermionic polar molecules at ultralow temperatures (1 $\ensuremath{\mu}$K).
Ultracold collisions of polar OH molecules are considered in the presence of an electrostatic field. The field exerts a strong influence on both elastic and state-changing inelastic collision rate constants, leading to clear experimental signatures that should help disentangle the theory of cold molecule collisions. Based on the collision rates, we discuss the prospects for evaporative cooling of electrostatically trapped OH. We also find that the scattering properties at ultralow temperatures prove to be remarkably independent of the details of the short-range interaction, owing to avoided crossings in the long-range adiabatic potential curves. The behavior of the scattering rate constants is qualitatively understood in terms of a novel set of long-range states of the [OH]2[\mathrm{OH}{]}_{2}[OH]2​ dimer.
We predict that pairs of polar molecules can be weakly bound together in an ultracold environment, provided that a dc electric field is present. The field that links the molecules together also strongly influences the basic properties of the resulting dimer, such as its binding energy and predissociation lifetime. Because of their long-range character, these dimers will be useful in disentangling cold collision dynamics of polar molecules. As an example, we estimate the microwave photoassociation yield for OH-OH cold collisions.
We predict the existence of stable bound states between pairs of ultracold diatomic molecules with the aid of a static electric field and 1D harmonic confinement. We focus on collisions of NaK-NaK identical fermions, for which we find that currently achievable experimental parameters allow the observation of these confinement-induced field-linked bound states as scattering resonances. The bound state is highly stable with lifetimes estimated to be tens of seconds long. With the diatomic molecules bound at distances a fraction of the dipolar length scale, these complexes allow for explorations of polyatomic chemistry and Fermi gas superfluid pairing.