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arXiv:physics/0307094 · Optics Letters

Precise frequency measurements of atomic transitions by use of a Rb-stabilized resonator

Ayan Banerjee, Dipankar Das, Vasant Natarajan A

Published Sep 1, 2003• 42 citations
arXivHTMLPDF

Abstract

We demonstrate a technique for frequency measurements of atomic transitions with a precision of 30 kHz. The frequency is measured with a ring-cavity resonator whose length is calibrated against a reference laser locked to the D2 line of 87Rb, the frequency of which is known with 10-kHz accuracy. We have used this method to measure the hyperfine structure in the 5P(3/2) state of 85Rb. We obtain precise values for the hyperfine constants, A = 25.041(6) MHz and B = 26.013(25) MHz, and a value of 77.992(20) MHz for the isotope shift in the D2 line.

DOI
10.1364/ol.28.001579

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Solitary resonance observed in the saturated absorption spectrum of the 87 Rb D 2 line

Normand Cyr, M. Têtu

In recent years, much work has been done in experimental studies to frequency lock laser diodes to atomic or molecular resonances.1 By such techniques it is possible to improve greatly the laser frequency stability and to define precisely its nominal value. For laser sources operating in the 0.8-μm range, rubidium is the preferred specie and each isotope offers two resonance lines, one at 780 nm (D2 line) and one at 795 nm (D1 line). Both linear and saturated absorption have been used, and laser frequency charcteristics are published.2,3

•Apr 24, 1989•1 citation
We demonstrate a technique for frequency measurements of atomic transitions with a precision of 30 kHz. The frequency is measured with a ring-cavity resonator whose length is calibrated against a reference laser locked to the D2 line of 87Rb, the frequency of which is known with 10-kHz accuracy. We have used this method to measure the hyperfine structure in the 5P(3/2) state of 85Rb. We obtain precise values for the hyperfine constants, A = 25.041(6) MHz and B = 26.013(25) MHz, and a value of 77.992(20) MHz for the isotope shift in the D2 line.
High-resolution (few MHz) absorption spectroscopy was demonstrated by using an atomic beam and a laser. The Doppler absorption width of natural-abundance Rb was reduced from ≈570 to 15 MHz (5.7-MHz natural width) by using an atomic beam. A magnetic field of about 75 kOe was used to scan the six 85Rb and four 87Rb mI components of the D1 line ( 52S12 to 52P12; 7947.64 Å in zero field) into coincidence with the 7944.66-Å 1-μs 202Hg ii laser pulses. From the known ground- and excited-state hyperfine constants and the Breit–Rabi formula, we conclude that the 87Rb absorption spectrum is shifted up by 77±3 MHz relative to that of 85Rb. This uncorrected isotope shift can be compared with previous measurements of 105±15 and 77.7±2.1 MHz. Improved stability and a narrower atomic beam would permit reduction of the isotope-shift and hyperfine-constant errors to below 1 MHz.
Abstract We report a measurement of the hyperfine-structure constants of the 85Rb 4 D 3 / 2 state using two-photon optical spectroscopy of the 5 S 1 / 2 → 4 D 3 / 2 transition. The spectra are acquired by measuring the transmission of the low-power 795 nm lower-stage laser beam through a cold-atom sample as a function of laser frequency, with the frequency of the upper-stage, 1476 nm laser fixed. All 4 hyperfine components of the 4 D 3 / 2 state are well-resolved in the experimental data. The dominant systematic is the light shift from the 1476 nm laser, which is addressed by extrapolating line positions measured for a set of 1476 nm laser powers to zero laser power. The analysis of our experimental data yields both the magnetic-dipole and electric-quadrupole constants for the 85Rb 4 D 3 / 2 level, without using earlier hyperfine measurements of other atomic levels. The respective results, A = 7.419(35) MHz and B = 4.19(19) MHz, are discussed in context with previous works. Our investigation may be useful for optical atomic clocks for precision metrology and emerging atom-based quantum technologies, all-infrared excitation of Rb Rydberg levels, and molecular physics.
We have measured the absolute frequency of the excited state transition 5P(3/2)-4D(5/2) in a (87)Rb atom with a femtosecond frequency comb, utilizing the recently developed spectroscopic technique of the double resonance optical pumping method. The absolute energy level of the 4D(5/2) state is determined by measuring the absolute frequency of the 5S(1/2)-5P(3/2) transition simultaneously. The hyperfine structure constants of the 4D(5/2) state are obtained by using the measured frequency. The magnetic dipole constant, A, is determined to be (-16.747+/-0.010) MHz with an uncertainty reduced 60-fold compared with a previous result. The electric quadrupole constant, B, is determined, for what is to our knowledge the first time, to be (4.149+/-0.059) MHz.
We demonstrate a technique for directly measuring the fine-structure interval in alkali atoms using two frequency-stabilized diode lasers. Each laser has a linewidth of order 1 MHz and precise tunability: one laser is tuned to a hyperfine transition in the D1 line, and the other laser to a hyperfine transition in the D2 line. The outputs of the lasers are fed into a scanning Michelson interferometer that measures the ratio of their wavelengths accurately. To illustrate the technique, we measure the fine-structure interval in Rb, and obtain a value of 237.6000(3)(5) cm−1 for the hyperfine-free 5P3/2–5P1/2 interval.
Abstract Using a Rb cell and a wavemeter, with a Doppler-free two-photon transition near 993 nm, we have measured the four hyperfine components (two isotopes, Δ F = 0) of the 5S–6S transition, finding the absolute energies of those transitions to a spectral resolution of 0.002 cm −1 = 60 MHz. We find the (87 minus 85) isotope shift of the 5S–6S transition to be +94(12) MHz. Using our single frequency cw laser with focused intensity up to 10 4 W cm −2 at the cell, we find no AC Stark or light shift of the lines at 6 MHz spectral resolution. We find no density shift of the lines at 6 MHz spectral resolution, for a range of Rb atom densities from 3 × 10 11 to 5 × 10 13 atoms/cm 3 .
In recent years, much work has been done in experimental studies to frequency lock laser diodes to atomic or molecular resonances.1 By such techniques it is possible to improve greatly the laser frequency stability and to define precisely its nominal value. For laser sources operating in the 0.8-μm range, rubidium is the preferred specie and each isotope offers two resonance lines, one at 780 nm (D2 line) and one at 795 nm (D1 line). Both linear and saturated absorption have been used, and laser frequency charcteristics are published.2,3