The Rigged Hilbert Space (RHS) theory of resonance scattering and decay is reviewed and contrasted with the standard Hilbert space (HS) theory of quantum mechanics. The main difference is in the choice of boundary conditions. Whereas the conventional theory allows for the in-states
ϕ+ and the out-states (observables)
ψ− of the S-matrix elements
(ψ−,ϕ+)=(ψout,Sϕin) any elements of the HS $\H$,
{ψ−}={ϕ+}(=)˝, the RHS theory chooses the boundary conditions~:
ϕ+∈Φ−⊂⊂˝Φ−×,
ψ−∈Φ+⊂⊂˝Φ+×, where
Φ− (
Φ+) are Hardy class spaces associated to the lower (upper) half-plane of the second sheet of the analytically continued S-matrix. This can be phenomenologically justified by causality. The two RHS's for states
ϕ+ and observables
ψ− provide new vectors which are not in $\H$, e.g. the Dirac-Lippmann-Schwinger kets
∣E±∈Φ∓× (solutions of the Lippmann-Schwinger equation with
±iε respectively) and the Gamow vectors
∣ER−iΓ/2±∈Φ∓×. The Gamow vectors
∣ER−iΓ/2− have all the properties that one heuristically needs for quasistable states. In addition, they give rise to asymmetric time evolution expressing irreversibility on the microphysical level.
Quantum mechanics in the Rigged Hilbert Space formulation describes quasistationary phenomena mathematically rigorously in terms of Gamow vectors. We show that these vectors exhibit microphysical irreversibility, related to an intrinsic quantum mechanical arrow of time, which states that preparation of a state has to precede the registration of an observable in this state. Moreover, the Rigged Hilbert Space formalism allows the derivation of an exact golden rule describing the transition of a pure Gamow state into a mixture of interaction-free decay products.
After a summary of the Rigged Hilbert space formulation of quantum mechanics and a brief statement of its advantages over von Neumann’s formulation, a mathematically correct definition of Gamow’s exponentially decaying vectors as generalized energy eigenvectors is suggested. It is shown that exponentially decaying vectors are obtained from the S-matrix poles in the lower half of the second sheet and exponentially growing vectors from the S-matrix poles in the upper half of the second sheet. Decaying ’’state’’ vectors are defined as functionals over half of the space of physical states and growing ’’state’’ vectors are defined as functionals over the other half. On functionals over these subspaces, the dynamical group of time development splits into two semigroups, one for t ≳ 0 and the other for t < 0. The generalized basis system connected with the spectrum of the Hamiltonian is transformed into a new basis system in which the exponentially decaying component of the density matrix is separated.
A quantum theory that applies to the (closed) universe needs to be time asymmetric because of the cosmological arrow of time. The preparation $\ensuremath{\Rightarrow}$ registration arrow of time (a state must be prepared before an observable can be detected in it) of the quantum mechanics of measured systems provides a phenomenological reason for an asymmetric semigroup time evolution. The standard theory in the Hilbert space (HS) is inadequate for either since the mathematics of the HS allows only reversible unitary group evolution and time symmetric boundary conditions. The mathematical theory that describes time-asymmetric quantum physics in addition to providing the mathematics for the Dirac kets is the rigged Hilbert space (RHS) theory. It uses a pair of RHS's of Hardy class with complementary analyticity property, one for the prepared states (``in states'') and the other for the registered observables (``out states''). The RHS's contain Gamow kets which have all the properties needed to represent decaying states and resonances. Gamow kets have only asymmetric time evolution. The neutral kaon system is used to show that quasistationary microphysical systems can be experimentally isolated if their time of preparation can be accurately identified. The theoretical predictions for a Gamow ket have the same features as the observed decay probabilities, including the time ordering. This time ordering is the same as the time ordering in the probabilities of histories for the quantum universe. The fundamental quantum mechanical arrow of time represented by the semigroup in the RHS is therefore the same as the cosmological arrow of time, assuming that the universe can be considered a closed quantum system.
We review some results in the theory of non-relativistic quantum unstable systems. We account for the most important definitions of quantum resonances that we identify with unstable quantum systems. Then, we recall the properties and construction of Gamow states as vectors in some extensions of Hilbert spaces, called Rigged Hilbert Spaces. Gamow states account for the purely exponential decaying part of a resonance; the experimental exponential decay for long periods of time physically characterizes a resonance. We briefly discuss one of the most usual models for resonances: the Friedrichs model. Using an algebraic formalism for states and observables, we show that Gamow states cannot be pure states or mixtures from a standard view point. We discuss some additional properties of Gamow states, such as the possibility of obtaining mean values of certain observables on Gamow states. A modification of the time evolution law for the linear space spanned by Gamow shows that some non-commuting observables on this space become commuting for large values of time. We apply Gamow states for a possible explanation of the Loschmidt echo.
We review the mathematical tools that are suitable for a formulation of time asymmetry in quantum mechanics. In particular, Hardy functions on a half plane and rigged Hilbert spaces constructed with a subclass of Hardy functions. This time asymmetry often appears in quantum scattering and, in particular, in resonance scattering. We review the construction of Gamow vectors, often considered Gamow states for resonances. A brief summary of the fundamental ideas of time asymmetric quantum mechanics is presented in a last section.