Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:nlin/0702026

Quantization of the Smoluchowski equation and the problem of quantum tunneling at zero temperature

A. O. Bolivar

Published Feb 14, 2007• 0 citations
arXivHTMLPDF

Abstract

In this article we address the problem of quantum tunneling of a non-Markovian Brownian particle away from thermal equilibrium. We calculate the Kramers escape rate at low temperature (including the zero temperature case) in the Smoluchowski limit (strong friction regime). Our main findings are: (i) our quantum escape rate is valid far from the thermal equilibrium and is non-Markovian, but it becomes Markovian as the correlation time vanishes; (ii) at thermodynamic equilibrium we obtain a non-Markovian quantum rate that predicts a superfluidity phenomenon in the Markovian limit at low and zero temperatures.

DOI
10.48550/arxiv.nlin/0702026

Related papers

Dynamical quantization of the non-Markovian Smoluchowski equation and the quantum tunneling phenomenon

A. O. Bolivar

Based on the dynamical quantization method we derive a quantum phase-space non-Markovian Smoluchowski equation describing the non-inertial Brownian motion of a harmonic oscillator immersed in a generic environment. In the long-time regime we investigate the tunneling phenomenon by evaluating the quantum Kramers escape rate of a Brownian particle over a potential barrier. As far as a quantum thermal reservoir is concerned, it is found that our steady quantum Kramers rate may depend upon no friction constant in the strong friction domain. This preposterous feature may suggest the existence of non-dissipative quantum tunneling at the low-temperature range, including the zero temperature case. Lastly, we predict that our quantum escape rate non-exponentially decays on the edge of the breakdown of the dissipation-fluctuation relation.

arXiv:1003.3958•Mar 21, 2010•0 citations

Quantum Tunneling at Zero Temperature in the Strong Friction Regime

A. O. Bolivar

In the large damping limit we derive a Fokker-Planck equation in configuration space (the so-called Smoluchowski equation) describing a Brownian particle immersed into a thermal environment and subjected to a nonlinear external force. We quantize this stochastic system and survey the problem of escape over a double-well potential barrier. Our finding is that the quantum Kramers rate does not depend on the friction coefficient at low temperatures; i.e., we predict a superfluidity phenomenon in overdamped open systems. Moreover, at zero temperature we show that the quantum escape rate does not vanish in the strong friction regime. This result, therefore, is in contrast with the work by Ankerhold et al. [Phys. Rev. Lett. 87, 086802 (2001)]] in which no quantum tunneling is predicted at zero temperature.

Physical Review Letters•Jan 20, 2005•9 citations

Quantum Smoluchowski equation: Escape from a metastable state

Dhruba Banerjee, Bidhan Chandra Bag, Ra Bag B +2 more

We develop a quantum Smoluchowski equation in terms of a true probability distribution function to describe quantum Brownian motion in configuration space in large friction limit at arbitrary temperature and derive the rate of barrier crossing and tunneling within a unified scheme. The present treatment is independent of path integral formalism and is based on canonical quantization procedure.

•Jan 1, 2002•12 citations

Non-Markovian quantum Brownian motion: a non-Hamiltonian approach

A. O. Bolivar

We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.

arXiv:1503.07951•Mar 27, 2015•1 citation

Quantum Smoluchowski equation for a spin bath

Sudarson Sekhar Sinha, Arnab Ghosh, Deb Shankar Ray

We derive the quantum mechanical description of overdamped Brownian motion of a particle in a spin bath of two-level atoms. The resulting Smoluchowski equation is used to calculate the rate of escape of the particle from a metastable state. At 0 K the decay rate is finite. We show that while quantization enhances the decay rate, higher temperatures induce thermal saturation, resulting in effective a reduction of the system-bath coupling. The role of coherence is examined.

Physical Review E•Sep 16, 2011•10 citations

Energy of a free Brownian particle coupled to thermal vacuum

Jakub Spiechowicz, J. Łuczka

Experimentalists have come to temperatures very close to absolute zero at which physics that was once ordinary becomes extraordinary. In such a regime quantum effects and fluctuations start to play a dominant role. In this context we study the simplest open quantum system, namely, a free quantum Brownian particle coupled to thermal vacuum, i.e. thermostat in the limiting case of absolute zero temperature. We analyze the average energy [Formula: see text] of the particle from a weak to strong interaction strength c between the particle and thermal vacuum. The impact of various dissipation mechanisms is considered. In the weak coupling regime the energy tends to zero as [Formula: see text] while in the strong coupling regime it diverges to infinity as [Formula: see text]. We demonstrate it for selected examples of the dissipation mechanisms defined by the memory kernel [Formula: see text] of the Generalized Langevin Equation. We reveal how at a fixed value of c the energy E(c) depends on the dissipation model: one has to compare values of the derivative [Formula: see text] of the dissipation function [Formula: see text] at time [Formula: see text] or at the memory time [Formula: see text] which characterizes the degree of non-Markovianity of the Brownian particle dynamics. The impact of low temperature is also presented.

arXiv:2003.13567•Scientific Reports•Feb 18, 2021•17 citations
In this article we address the problem of quantum tunneling of a non-Markovian Brownian particle away from thermal equilibrium. We calculate the Kramers escape rate at low temperature (including the zero temperature case) in the Smoluchowski limit (strong friction regime). Our main findings are: (i) our quantum escape rate is valid far from the thermal equilibrium and is non-Markovian, but it becomes Markovian as the correlation time vanishes; (ii) at thermodynamic equilibrium we obtain a non-Markovian quantum rate that predicts a superfluidity phenomenon in the Markovian limit at low and zero temperatures.
Based on the dynamical quantization method we derive a quantum phase-space non-Markovian Smoluchowski equation describing the non-inertial Brownian motion of a harmonic oscillator immersed in a generic environment. In the long-time regime we investigate the tunneling phenomenon by evaluating the quantum Kramers escape rate of a Brownian particle over a potential barrier. As far as a quantum thermal reservoir is concerned, it is found that our steady quantum Kramers rate may depend upon no friction constant in the strong friction domain. This preposterous feature may suggest the existence of non-dissipative quantum tunneling at the low-temperature range, including the zero temperature case. Lastly, we predict that our quantum escape rate non-exponentially decays on the edge of the breakdown of the dissipation-fluctuation relation.
In the large damping limit we derive a Fokker-Planck equation in configuration space (the so-called Smoluchowski equation) describing a Brownian particle immersed into a thermal environment and subjected to a nonlinear external force. We quantize this stochastic system and survey the problem of escape over a double-well potential barrier. Our finding is that the quantum Kramers rate does not depend on the friction coefficient at low temperatures; i.e., we predict a superfluidity phenomenon in overdamped open systems. Moreover, at zero temperature we show that the quantum escape rate does not vanish in the strong friction regime. This result, therefore, is in contrast with the work by Ankerhold et al. [Phys. Rev. Lett. 87, 086802 (2001)]] in which no quantum tunneling is predicted at zero temperature.
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.
Experimentalists have come to temperatures very close to absolute zero at which physics that was once ordinary becomes extraordinary. In such a regime quantum effects and fluctuations start to play a dominant role. In this context we study the simplest open quantum system, namely, a free quantum Brownian particle coupled to thermal vacuum, i.e. thermostat in the limiting case of absolute zero temperature. We analyze the average energy [Formula: see text] of the particle from a weak to strong interaction strength c between the particle and thermal vacuum. The impact of various dissipation mechanisms is considered. In the weak coupling regime the energy tends to zero as [Formula: see text] while in the strong coupling regime it diverges to infinity as [Formula: see text]. We demonstrate it for selected examples of the dissipation mechanisms defined by the memory kernel [Formula: see text] of the Generalized Langevin Equation. We reveal how at a fixed value of c the energy E(c) depends on the dissipation model: one has to compare values of the derivative [Formula: see text] of the dissipation function [Formula: see text] at time [Formula: see text] or at the memory time [Formula: see text] which characterizes the degree of non-Markovianity of the Brownian particle dynamics. The impact of low temperature is also presented.