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arXiv:math/0312326 · Springer eBooks

Some Jump Processes in Quantum Field Theory

Roderich Tumulka, Hans-Otto Georgii

Published Oct 28, 2005• 17 citations
arXivHTMLPDF
DOI
10.1007/3-540-27110-4_4

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Recently, the coherent modified Redfield theory (CMRT) has been widely used to simulate the excitation-energy-transfer (EET) processes in photosynthetic systems. However, the numerical simulation of the CMRT is computationally expensive when dealing with large-scale systems, e.g. photosystem I (PSI) and II (PSII). On the other hand, the chemical reaction and fluorescence loss traditionally treated by the non-Hermitian Hamiltonian approach may result in significantly error in a wide range of parameters. To address these issues, we introduce a quantum jump approach (QJA) based on the CMRT to simulate the evolution of photosynthetic complexes including both the chemical reaction and fluorescence loss. The QJA shows higher accuracy and efficiency in simulating the EET processes. The QJA-CMRT approach may provide a powerful tool to design and optimize artificial photosynthetic systems, which benefits future innovation in the field of energy.

physics.chem-phCross-listedarXiv:2511.16984•Nov 24, 2025
We consider the time-inhomogeneous Markovian jump process introduced by John S. Bell [Phys.Rep. 137, 49] for a lattice quantum field theory, which runs on the associated configuration space. Its jump rates, tailored to give the process the quantum distribution ∣Ψt∣2|Ψ_t|^2∣Ψt​∣2 at all times ttt, typically exhibit singularities. We establish the existence of a unique such process for all times, under suitable assumptions on the Hamiltonian or the initial state vector Ψ0Ψ_0Ψ0​. The proof of non-explosion takes advantage of the special role of the ∣Ψt∣2|Ψ_t|^2∣Ψt​∣2 distribution.
Recently, the coherent modified Redfield theory (CMRT) has been widely used to simulate the excitation-energy-transfer (EET) processes in photosynthetic systems. However, the numerical simulation of the CMRT is computationally expensive when dealing with large-scale systems, e.g. photosystem I (PSI) and II (PSII). On the other hand, the chemical reaction and fluorescence loss traditionally treated by the non-Hermitian Hamiltonian approach may result in significantly error in a wide range of parameters. To address these issues, we introduce a quantum jump approach (QJA) based on the CMRT to simulate the evolution of photosynthetic complexes including both the chemical reaction and fluorescence loss. The QJA shows higher accuracy and efficiency in simulating the EET processes. The QJA-CMRT approach may provide a powerful tool to design and optimize artificial photosynthetic systems, which benefits future innovation in the field of energy.