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arXiv:math-ph/9807031

Exponential Estimates in Adiabatic Quantum Evolution

Alain Joye, Charles‐Edouard Pfister

Published Jul 24, 1998• 18 citations
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Abstract

We review recent results concerning the exponential behaviour of transition probabilities across a gap in the adiabatic limit of the time-dependent Schrödinger equation. They range from an exponential estimate in quite general situations to asymptotic Landau-Zener type formulae for finite dimensional systems, or systems reducible to this case.

DOI
10.48550/arxiv.math-ph/9807031

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We review recent results concerning the exponential behaviour of transition probabilities across a gap in the adiabatic limit of the time-dependent Schrödinger equation. They range from an exponential estimate in quite general situations to asymptotic Landau-Zener type formulae for finite dimensional systems, or systems reducible to this case.
This paper presents analytic formulas for various transition times in the Landau-Zener model. Considerable differences are found between the transition times in the diabatic and adiabatic bases, and between the jump time (the time for which the transition probability rises to the region of its asymptotic value) and the relaxation time (the characteristic damping time of the oscillations which appear in the transition probability after the crossing). These transition times have been calculated by using the exact values of the transition probabilities and their derivatives at the crossing point and approximations to the time evolutions of the transition probabilities in the diabatic basis, derived earlier [N. V. Vitanov and B. M. Garraway, Phys. Rev. A 53, 4288 (1996)], and similar results in the adiabatic basis, derived in the present paper.
We obtain probabilities at a crossing of two linearly time-dependent potentials that are constantly coupled to the other by solving a time-dependent Schrödinger equation. We find that the system which was initially localized at one state evolves to split into both states at the crossing. The probability splitting depends on the coupling strength V0V_0V0​ such that the system stays at the initial state in its entirety when V0V_0V0​ = 0 while it is divided equally in both states when V0→∞V_0 \rightarrow {\infty}V0​→∞ . For a finite coupling the probability branching at the crossing is not even and thus a complete probability transfer at t→∞t \rightarrow {\infty}t→∞ is not achieved in the linear potential crossing problem. The Landau-Zener formula for transition probability at t→∞t \rightarrow {\infty}t→∞ is expressed in terms of the probabilities at the crossing.
We expand upon the standard quantum adiabatic theorem, examining the time-dependence of quantum evolution in the near-adiabatic limit. We examine a Hamiltonian that evolves along some fixed trajectory from H^0\hat{H}_0H^0​ to H^1\hat{H}_1H^1​ in a total evolution-time τττ, and our goal is to determine how the final state of the system depends on τττ. If the system is initialized in a non-degenerate ground state, the adiabatic theorem says that in the limit of large τττ, the system will stay in the ground state. We examine the near-adiabatic limit where the system evolves slowly enough that most but not all of the final state is in the ground state, and we find that the probability of leaving the ground state oscillates in τττ with a frequency determined by the integral of the spectral gap along the trajectory of the Hamiltonian, so long as the gap is big. If the gap becomes exceedingly small, the final probability is the sum of oscillatory behavior determined by the integrals of the gap before and after the small gap. We confirm these analytic predictions with numerical evidence from barrier tunneling problems in the context of quantum adiabatic optimization.
We describe the effect of pure dephasing upon the time-dependent dynamics of two-state quantum systems in the framework of a Lindblad equation for the time evolution of the density matrix. A uniform approximate formula is derived, which modifies the corresponding lossless transition probability by an exponential factor containing the dephasing rate and the interaction parameters. This formula is asymptotically exact in both the diabatic and adiabatic limits; comparison with numerical results shows that it is highly accurate also in the intermediate range. Several two-state models are considered in more detail, including the Landau-Zener, Rosen-Zener, Allen-Eberly, and Demkov-Kunike models, along with several other models, such as a Gaussian model and a Landau-Zener model with a pulsed coupling.