A quantum system $\s$ interacts in a successive way with elements $\ee$ of a chain of identical independent quantum subsystems. Each interaction lasts for a duration $τ$ and is governed by a fixed coupling between $\s$ and $\ee$. We show that the system, initially in any state close to a reference state, approaches a {\it repeated interaction asymptotic state} in the limit of large times. This state is $τ$--periodic in time and does not depend on the initial state. If the reference state is chosen so that $\s$ and $\ee$ are individually in equilibrium at positive temperatures, then the repeated interaction asymptotic state satisfies an average second law of thermodynamics.
A quantum system \s interacts in a successive way with elements \ee of a chain of identical independent quantum subsystems. Each interaction lasts for a duration τ and is governed by a fixed coupling between \s and \ee. We show that the system, initially in any state close to a reference state, approaches a {\it repeated interaction asymptotic state} in the limit of large times. This state is τ--periodic in time and does not depend on the initial state. If the reference state is chosen so that \s and \ee are individually in equilibrium at positive temperatures, then the repeated interaction asymptotic state satisfies an average second law of thermodynamics.
Consider a quantum system $\cS$ that interacts sequentially with a chain (environment) of identical probes ${\cal C} = \cP+\cP+...$, with each interaction governed by a fixed interaction time τ and operator V. It is known how to construct the asymptotic state (large times) if the initial states of $\cP$ belong to a class of so-called reference states. We generalize the analysis to a broader class of initial states, including the physically important situation of pure states. This is done by a simple modification to the effective dynamics generator.
We consider a quantum system S interacting sequentially with independent systems Em, m = 1, 2,... Before interacting, each Em is in a possibly random state, and each interaction is characterized by an interaction time and an interaction operator, both possibly random. We prove that any initial state converges to an asymptotic state almost surely in the ergodic mean, provided the couplings satisfy a mild effectiveness condition. We analyze the macroscopic properties of the asymptotic state and show that it satisfies a second law of thermodynamics. We solve exactly a model in which S and all the Em are spins: we find the exact asymptotic state, in case the interaction time, the temperature, and the excitation energies of the Em vary randomly. We analyze a model in which S is a spin and the Em are thermal fermion baths and obtain the asymptotic state by rigorous perturbation theory, for random interaction times varying slightly around a fixed mean, and for small values of a coupling constant. 1
The second law of thermodynamics places constraints on state transformations. It applies to systems composed of many particles, however, we are seeing that one can formulate laws of thermodynamics when only a small number of particles are interacting with a heat bath. Is there a second law of thermodynamics in this regime? Here, we find that for processes which are approximately cyclic, the second law for microscopic systems takes on a different form compared to the macroscopic scale, imposing not just one constraint on state transformations, but an entire family of constraints. We find a family of free energies which generalize the traditional one, and show that they can never increase. The ordinary second law relates to one of these, with the remainder imposing additional constraints on thermodynamic transitions. We find three regimes which determine which family of second laws govern state transitions, depending on how cyclic the process is. In one regime one can cause an apparent violation of the usual second law, through a process of embezzling work from a large system which remains arbitrarily close to its original state. These second laws are relevant for small systems, and also apply to individual macroscopic systems interacting via long-range interactions. By making precise the definition of thermal operations, the laws of thermodynamics are unified in this framework, with the first law defining the class of operations, the zeroth law emerging as an equivalence relation between thermal states, and the remaining laws being monotonicity of our generalized free energies.
The rather new field of quantum thermodynamics intends to derive thermodynamics from quantum mechanics, as well as to study thermodynamical behavior of quantum systems. It turns out that, indeed, thermalization can be obtained even for very small quantum systems due to the interaction with an appropriate environment. The consideration of an ensemble, as in statistical mechanics, is not necessary. However, the total system - consisting of system and environment - in quantum thermodynamics is usually considered to be closed. In particular, there exists no interaction with an external observer. Since quantum measurements typically influence the measured system, one may wonder which influence such an observation will have in the quantum thermodynamical setting. In this thesis, we study this influence of measurements in quantum thermodynamical systems. It turns out that various concepts known from statistical mechanics arise from such a "quantum thermodynamics under observation", although they do not have any meaning in the isolated quantum thermodynamical setting. The model discussed in the first part consists of a two-level system coupled to a large spin environment, the magnetization of which is measured periodically. This leads to quasi-classical trajectories for the system and - as in statistical mechanics - thermalization and temperature only have a meaning in terms of an ensemble average or a long-time average. Calculating these averages, we prove the ergodicity of the system. Interestingly, the entropy of the obtained attractor state depends on the time between the measurements and can be shown to be connected with the subjective lack of knowledge of the observer. In case of optimal measurements, the ensemble averaged state of the system under periodic measurements equals the state of the system in the quantum thermodynamical model without measurements. Introducing a detuning between system and environment, we find that the system can be prepared in almost arbitrary thermal states due to the periodic measurements. Even the creation of inversion becomes possible. As shown in numerical simulations, our results, which were analytically obtained for large environments, are even applicable to describe the behavior of the system coupled to small environments consisting of only a few spins. Besides measurements of the environment, we also study direct projective measurements of the system, as well as measurements with finite duration, obtaining that the dynamics of the system is almost independent of the concrete realization of the measurements. In the second part of the thesis, we discuss the meaning of temperature fluctuations in quantum thermodynamical systems. In statistical mechanics, there exist different approaches to the problem of temperature fluctuations, which lead to the well-known temperature fluctuation formula. The nature and operational accessibility of these fluctuations, however, remains rather unclear. We argue that according to quantum thermodynamics a system relaxes into a quasi-stationary thermal state and therefore the temperature does not fluctuate. However, since temperature is not an observable, it can only be determined indirectly. For modular systems, we show that the fluctuations of the temperature estimate obtained from a single energy measurement, indeed, are given by the temperature fluctuation formula derived in statistical mechanics, but only within a certain temperature range. The validity range of this formula increases with increasing size of the system. Thus, one can conclude that these "temperature fluctuations" can be interpreted as representing a fundamental limit for the instantaneous determination of temperature.
The circumstances under which a system reaches thermal equilibrium, and how to derive this from basic dynamical laws, has been a major question from the very beginning of thermodynamics and statistical mechanics. Despite considerable progress, it remains an open problem. Motivated by this issue, we address the more general question of equilibration. We prove, with virtually full generality, that reaching equilibrium is a universal property of quantum systems: almost any subsystem in interaction with a large enough bath will reach an equilibrium state and remain close to it for almost all times. We also prove several general results about other aspects of thermalization besides equilibration, for example, that the equilibrium state does not depend on the detailed microstate of the bath.
We present a theory to describe thermalization mechanism for time-periodic finite isolated interacting quantum systems. The long time asymptote of natural observables in Floquet states is directly related to averages of these observables governed by a time-independent effective Hamiltonian. We prove that if the effective system is nonintegrable and satisfies eigenstate thermalization hypothesis, quantum states of such time-periodic isolated systems will thermalize. After a long time evolution, system will relax to a stationary state, which only depends on an initial energy of the effective Hamiltonian and follows a generalized eigenstate thermalization hypothesis. A numerical test for the periodically modulated Bose-Hubbard model, with the extra nearest neighbor interaction on the bosonic lattice, agrees with the theoretical predictions.