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arXiv:hep-th/9703006 · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Nonequilibrium time evolution in quantum field theory

CHRISTOF WETTERICH

Published Sep 1, 1997• 23 citations
arXivHTMLPDF

Abstract

The time development of equal-time correlation functions in quantum mechanics and quantum field theory is described by an exact evolution equation for generating functionals. This permits a comparison between classical and quantum evolution in nonequilibrium systems.
DOI
10.1103/physreve.56.2687

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We study nonequilibrium evolution in a self-interacting quantum field theory invariant under space translation only by using a canonical approach based on the recently developed Liouville--von Neumann formalism. The method is first used to obtain the correlation functions both in and beyond the Hartree approximation, for the quantum mechanical analogue of the ${\ensuremath{\varphi}}^{4}$ model. The technique involves representing the Hamiltonian in a Fock basis of annihilation and creation operators. By separating it into a solvable Gaussian part involving quadratic terms and a perturbation of quartic terms, it is possible to find the improved vacuum state to any desired order. The correlation functions for the field theory are then investigated in the Hartree approximation, and those beyond the Hartree approximation are obtained by finding the improved vacuum state corrected up to $O({\ensuremath{\lambda}}^{2}).$ These correlation functions take into account next-to-leading and next-to-next-to-leading order effects in the coupling constant. We also use the Heisenberg formalism to obtain the time evolution equations for the equal-time, connected correlation functions beyond the leading order. These equations are derived by including the connected four-point functions in the hierarchy. The resulting coupled set of equations form part of an infinite hierarchy of coupled equations relating the various connected n-point functions. The connection with other approaches based on the path integral formalism is established, and the physical implications of the set of equations are discussed with particular emphasis on thermalization.
The dynamics of a quantum system coupled to a classical environment and subject to constraints that drive it out of equilibrium are described. The evolution of the system is governed by the quantum-classical Liouville equation. Rather than evaluating the evolution of the mixed quantum-classical density operator, we derive exact equations of motion for the nonequilibrium average values of a set of operators or variables, along with correlation function expressions for the dissipative coefficients that enter these equations. These equations are obtained by requiring that the exact nonequilibrium averages are equal to local nonequilibrium averages that depend on auxiliary fields whose values satisfy evolution equations obtained using projection operator methods. The results are illustrated by deriving reaction-diffusion equations coupled to fluid hydrodynamic equations for a solution of quantum particles that can exist in two metastable states. Nonequilibrium steady states are discussed along with the reaction rate and diffusion correlation functions that characterize such states.
There has been substantial progress in recent years in the quantitative understanding of the nonequilibrium time evolution of quantum fields. Important topical applications, in particular in high energy particle physics and cosmology, involve dynamics of quantum fields far away from the ground state or thermal equilibrium. In these cases, standard approaches based on small deviations from equilibrium, or on a sufficient homogeneity in time underlying kinetic descriptions, are not applicable. A particular challenge is to connect the far-from-equilibrium dynamics at early times with the approach to thermal equilibrium at late times. Understanding the ``link'' between the early- and the late-time behavior of quantum fields is crucial for a wide range of phenomena. For the first time questions such as the explosive particle production at the end of the inflationary universe, including the subsequent process of thermalization, can be addressed in quantum field theory from first principles. The progress in this field is based on efficient functional integral techniques, so-called n-particle irreducible effective actions, for which powerful nonperturbative approximation schemes are available. Here we give an introduction to these techniques and show how they can be applied in practice. Though we focus on particle physics and cosmology applications, we emphasize that these techniques can be equally applied to other nonequilibrium phenomena in complex many body systems.
There has been substantial progress in recent years in the quantitative understanding of the nonequilibrium time evolution of quantum fields. Important topical applications, in particular in high energy particle physics and cosmology, involve dynamics of quantum fields far away from the ground state or thermal equilibrium. In these cases, standard approaches based on small deviations from equilibrium, or on a sufficient homogeneity in time underlying kinetic descriptions, are not applicable. A particular challenge is to connect the far-from-equilibrium dynamics at early times with the approach to thermal equilibrium at late times. Understanding the ``link'' between the early- and the late-time behavior of quantum fields is crucial for a wide range of phenomena. For the first time questions such as the explosive particle production at the end of the inflationary universe, including the subsequent process of thermalization, can be addressed in quantum field theory from first principles. The progress in this field is based on efficient functional integral techniques, so-called n-particle irreducible effective actions, for which powerful nonperturbative approximation schemes are available. Here we give an introduction to these techniques and show how they can be applied in practice. Though we focus on particle physics and cosmology applications, we emphasize that these techniques can be equally applied to other nonequilibrium phenomena in complex many body systems.
One of the major goals in the establishment of a quantum field theory for nonequilibrium systems is to study dynamical problems, following the evolution of the expectation value of a physical variable with respect to an in state. This is different from a scattering problem characterized by the transition amplitude between the in and out states, as is treated in every textbook on quantum field theory. This problem is usually coupled with how one could identify a relevant sector of the theory as the system (light fields vs. heavy fields, slow modes vs. fast modes, long wavelength modes vs. short ones, etc.) and determine the effect of its other sectors as the environment on this system, as we have discussed in the last chapter. Given a classical nonequilibrium system, described, for example, by a Langevin equation, there are essentially three possible strategies to follow. One may attempt to solve it, usually numerically. In the quantum field case, this gets difficult beyond the linear case. Second, one may try to transform it into an equation for the evolution of a probability distribution function in the system's configuration space. In the quantum field case the relevant object is the reduced density matrix, and the relevant equation is the Liouville-von Neumann equation. This is also infeasible beyond the linear case, unless under restrictive approximations (such as Gaussianity) which in fact reduce this approach to the third and coarsest.