We make three remarks about the quantum theory of a charged particle moving in a time-independent, uni-directional magnetic field (which we take to be parallel to the z-axis). First, when the field is uniform, we comment on the relation between the wave-function on the one hand if it is chosen to be an eigenstate of momentum (leaving aside the trivial z-dependence) and hence non-normalizable, and on the other hand if it is chosen to be an eigenstate of angular momentum. Second, we discuss the form of the wave-function when the magnetic field had a weak z-dependence. Finally, we make a short comment on the derivation of the diamagnetism of a free electron gas.
Different classical limits of quantum mechanics are discussed in the setting of a simple example, the two-dimensional motion of a spinless electron in a uniform magnetic field. Both the time-independent energy eigenstates and the time-dependent states developing from initial localized states are exactly solvable. In the first example, an ℏ→0 limit with fixed energy leads to a simple ensemble of classical orbits. In the second, ℏ→0 with fixed initial mean position and momentum leads to a unique classical orbit.
A thorough unified treatment is given of the quantum-mechanical operators and wave functions for a molecular system (composed of
N moving charged particles) in static uniform electric and magnetic fields
E and
B. The treatment is rigorous within the nonrelativistic approximation. The system may either be neutral or charged. The fields may have arbitrary intensities and orientations. Close correspondence is maintained between the classical and quantum-mechanical treatments. The wave functions are expressed both in the time-independent energy representation and in time-dependent wave packets. Three types of momentum play important roles. For single-particle systems they are the canonical momentum
P, the mechanical momentum $\mathit{\ensuremath{\Pi}}=\mathit{P}\ensuremath{-}(\frac{e}{c})\mathit{A}=M\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{R}$, and the pseudomomentum $\mathcal{K}=\mathit{\ensuremath{\Pi}}\ensuremath{-}(\frac{e}{c})\mathit{R}\ifmmode\times\else\texttimes\fi{}\mathit{B}\ensuremath{-}e\mathit{E}t$. The pseudomomentum is a constant of the motion. Except in the absence of magnetic fields, not all of the components of either $\mathit{\ensuremath{\Pi}}$ or
K commute. This complicates the quantum-mechanical formalism. The components of the pseudomomentum have simple classical interpretations, and in quantum mechanics they are related to the operator which performs a boost to a reference frame moving with constant velocity
v. In this moving frame, the electric field intensity is ${\mathit{E}}^{\ensuremath{'}}=\mathit{E}+(\frac{\mathit{v}}{c})\ifmmode\times\else\texttimes\fi{}\mathit{B}$. Thus, in a frame moving with the drift velocity ${\mathit{v}}_{d}=(\frac{c}{{B}^{2}})\mathit{E}\ifmmode\times\else\texttimes\fi{}\mathit{B}$, the components of the electric field intensity perpendicular to
B vanish. In this paper, the velocity boost operators are used to show the relationships between wave functions expressed in reference frames moving with repsect to each other. The dynamics of the
N-particle systems are simplified by making the Power-Zienau-Woolley transformation (which reduces as a special case to a unitary transformation used by Lamb) and by using center-of-mass and internal coordinates. Generalizing previous works, it is shown how the pseudomomentum is involved in separating these degrees of freedom for
N particles in both
E and
B. For neutral molecules, the Schr\"odinger equation is "pseudoseparated" and the internal degrees of freedom are coupled to the center of mass motion only by the "motional Stark Effect," which involves the constant of motion
K. For ionic systems, only one component of the center of mass is coupled to the internal motion. Quantitative estimates of the weak center-of-mass coupling are made for both neutral and ionic
n=1 and
n=2 quantum states of two-body systems by perturbation expansions in powers of the field strengths. In the usual nonrigorous treatments of systems in magnetic fields, no distinction is made between $\mathit{\ensuremath{\Pi}}$ and
K and both are approximated by $M\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{R}$, where
M is the mass of the molecule and
R is taken to be the classical orbital position of a single particle having the same mass and charge. This is an excellent approximation for ground-state molecules and ions in weak fields. However, the resulting errors can be much larger if the system is in either intense fields or high-lying states (e.g., Rydberg levels). These are the conditions under which the rigorous formalism should be most useful. The determination of the wave functions and energy levels for many-particle ionic systems is complicated due to the coupling with the center of mass. The suggestion is made that it might be useful to boost the reference frame so that it moves with the velocity $\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{R}$ of a single classical particle. The Schr\"odinger equation in this frame could serve as a more suitable basis for perturbative or variational treatments.
We study the valence electron of an alkaline atom or a general charged particle with arbitrary spin and with magnetic moment moving in a rotating magnetic field. By using a time-dependent unitary transformation, the Schr\"odinger equation with the time-dependent Hamiltonian can be reduced to a Schr\"odinger-like equation with a time-independent effective Hamiltonian. Eigenstates of the effective Hamiltonian correspond to cyclic solutions of the original Schr\"odinger equation. The nonadiabatic geometric phase of a cyclic solution can be expressed in terms of the expectation value of the component of the total angular momentum along the rotating axis, regardless of whether the solution is explicitly available. For the alkaline atomic electron and a strong magnetic field, the eigenvalue problem of the effective Hamiltonian is completely solved, and the geometric phase turns out to be a linear combination of two solid angles. For a weak magnetic field, the same problem is solved partly. For a general charged particle, the problem is solved approximately in a slowly rotating magnetic field, and the geometric phases are also calculated.
Application of the Bohr–Wilson–Sommerfeld quantization condition to a charged particle in a uniform magnetic field requires knowledge of the canonical momentum of such a particle, which in turn requires students to know about the vector potential. The canonical momentum in this situation is conventionally obtained by introducing an appropriate additional term involving the corresponding vector potential in the Lagrangian. In this work, we take a different approach to this problem by analyzing it with Maupertuis's principle of least action. We show that satisfying this principle for a charged particle moving in a uniform magnetic field requires that a term proportional to the flux passing through the area enclosed by the particle's trajectory be included in its action. This additional term accomplishes two tasks. First, it facilitates applying the Bohr–Wilson–Sommerfeld quantum condition for a charged particle moving in a uniform magnetic field without using the Lagrangian approach, and, second, it gives the appropriate canonical momentum and Lagrangian for a charged particle in a general electromagnetic field in a straightforward manner.