We study the time evolution of correlation functions in closed quantum systems for nonequilibrium ensembles of initial conditions. For a scalar quantum field theory we show that generic time-reversal invariant evolutions approach equilibrium at large times. The calculation provides a first principles justification that the large-time behavior of closed macroscopic quantum systems can be effectively described by thermal ensemble averages.
We study the time evolution of correlation functions in closed quantum systems for nonequilibrium ensembles of initial conditions. For a scalar quantum field theory we show that generic time-reversal invariant evolutions approach equilibrium at large times. The calculation provides a first principles justification that the large-time behavior of closed macroscopic quantum systems can be effectively described by thermal ensemble averages.
Thermalization of classical fields is investigated in a \\phi^4 scalar field theory in 1+1 dimensions, discretized on a lattice. We numerically integrate the classical equations of motion using initial conditions sampled from various nonequilibrium probability distributions. Time-dependent expectation values of observables constructed from the canonical momentum are compared with thermal ones. It is found that a closed system, evolving from one initial condition, thermalizes to high precision in the thermodynamic limit, in a time-averaged sense. For ensembles consisting of many members with the same energy, we find that expectation values become stationary - and equal to the thermal values - in the limit of infinitely many members. Initial ensembles with a nonzero (noncanonical) spread in the energy density or other conserved quantities evolve to noncanonical stationary ensembles. In the case of a narrow spread, asymptotic values of primary observables are only mildly affected. In contrast, fluctuations and connected correlation functions will differ substantially from the canonical values. This raises doubts on the use of a straightforward expansion in terms of 1PI-vertex functions to study thermalization.
The time evolution of the correlation functions of an ensemble of anharmonic N-component oscillators with O(N) symmetry is described by a flow equation, exact up to corrections of order 1/N2. We find effective irreversibility. Nevertheless, analytical and numerical investigation reveals that the system does not reach thermal equilibrium for large times, even when N→∞. Depending on the initial distribution, the dynamics is asymptotically stable or it exhibits growing modes which break the conditions for the validity of the 1/N expansion for large time. We investigate both classical and quantum systems, the latter being the limit of an O(N) symmetric scalar quantum field theory in zero spatial dimensions.
Quantum thermalization describes how closed quantum systems can effectively reach thermal equilibrium, resolving the apparent incongruity between the reversibility of Schrödinger's equation and the second law of thermodynamics. Despite its ubiquity and conceptual significance, the precise conditions that give rise to quantum thermalization are still not well understood. After nearly a century of efforts, we have yet to find a complete mathematical proof that an effective statistical description naturally emerges the underlying quantum dynamics in generic settings. Here, we prove that quantum thermalization must occur in any qubit system with local interactions under three conditions: (i) high effective temperature, (ii) translation invariance, and (iii) no perfect resonances in the energy spectrum. Specifically, we show that a typical, low-complexity pure state drawn from any ensemble with large entropy and well-defined effective temperature becomes locally indistinguishable from a Gibbs state upon unitary evolution. In this setting, our rigorous results prove the widely anticipated notion that statistical physics should be understood as an emergent phenomenon, explicitly derived from the first principles of quantum mechanics.
We investigate the time evolution of a classical ensemble of isolated periodic chains of O(N)-symmetric anharmonic oscillators. Our method is based on an exact evolution equation for the time dependence of correlation functions. We discuss its solutions in an approximation which retains all contributions in next-to-leading order in a 1/N expansion and preserves time reflection symmetry. We observe effective irreversibility and approximate thermalization. At large time the system approaches stationary solutions in the vicinity of, but not identical to, thermal equilibrium. The ensemble therefore retains some memory of the initial condition beyond the conserved total energy. Such behavior with incomplete thermalization is referred to as ``mesoscopic dynamics.'' It is expected for systems in a small volume. Surprisingly, we find that the nonthermal asymptotic stationary solutions do not change for large volume. This raises questions on Boltzmann's conjecture that macroscopic isolated systems thermalize.
There has been substantial progress in recent years in the quantitative understanding of the nonequilibrium time evolution of quantum fields. Important topical applications, in particular in high energy particle physics and cosmology, involve dynamics of quantum fields far away from the ground state or thermal equilibrium. In these cases, standard approaches based on small deviations from equilibrium, or on a sufficient homogeneity in time underlying kinetic descriptions, are not applicable. A particular challenge is to connect the far-from-equilibrium dynamics at early times with the approach to thermal equilibrium at late times. Understanding the ``link'' between the early- and the late-time behavior of quantum fields is crucial for a wide range of phenomena. For the first time questions such as the explosive particle production at the end of the inflationary universe, including the subsequent process of thermalization, can be addressed in quantum field theory from first principles. The progress in this field is based on efficient functional integral techniques, so-called n-particle irreducible effective actions, for which powerful nonperturbative approximation schemes are available. Here we give an introduction to these techniques and show how they can be applied in practice. Though we focus on particle physics and cosmology applications, we emphasize that these techniques can be equally applied to other nonequilibrium phenomena in complex many body systems.
There has been substantial progress in recent years in the quantitative understanding of the nonequilibrium time evolution of quantum fields. Important topical applications, in particular in high energy particle physics and cosmology, involve dynamics of quantum fields far away from the ground state or thermal equilibrium. In these cases, standard approaches based on small deviations from equilibrium, or on a sufficient homogeneity in time underlying kinetic descriptions, are not applicable. A particular challenge is to connect the far-from-equilibrium dynamics at early times with the approach to thermal equilibrium at late times. Understanding the ``link'' between the early- and the late-time behavior of quantum fields is crucial for a wide range of phenomena. For the first time questions such as the explosive particle production at the end of the inflationary universe, including the subsequent process of thermalization, can be addressed in quantum field theory from first principles. The progress in this field is based on efficient functional integral techniques, so-called n-particle irreducible effective actions, for which powerful nonperturbative approximation schemes are available. Here we give an introduction to these techniques and show how they can be applied in practice. Though we focus on particle physics and cosmology applications, we emphasize that these techniques can be equally applied to other nonequilibrium phenomena in complex many body systems.