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arXiv:cond-mat/9904100 · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Quantum statistical mechanics for nonextensive systems

Ervin Kaminski Lenzi, R. S. Mendes, A. K. Rajagopal

Published Feb 1, 1999• 45 citations
arXivHTMLPDF

Abstract

The traditional basis of description of many-particle systems in terms of Green functions is here generalized to the case when the system is nonextensive, by incorporating the Tsallis form of the density matrix indexed by a nonextensive parameter q. This is accomplished by expressing the many-particle q Green function in terms of a parametric contour integral over a kernel multiplied by the usual grand canonical Green function which now depends on this parameter. We study one- and two-particle Green functions in detail. From the one-particle Green function, we deduce some experimentally observable quantities such as the one-particle momentum distribution function and the one-particle energy distribution function. Special forms of the two-particle Green functions are related to physical dynamical structure factors, some of which are studied here. We deduce different forms of sum rules in the q formalism. A diagrammatic representation of the q Green functions similar to the traditional ones follows because the equations of motion for both of these are formally similar. Approximation schemes for one-particle q Green functions such as Hartree and Hartree-Fock schemes are given as examples. This extension enables us to predict possible experimental tests for the validity of this framework by expressing some observable quantities in terms of the q averages.

DOI
10.1103/physreve.59.1398

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Quantum Statistical Mechanics for Nonextensive Systems: Prediction for Possible Experimental Tests

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The traditional basis of description of the many-particle systems in terms of the Green functions is here generalized when the system is nonextensive by incorporating the Tsallis form of the density matrix, indexed by a nonextensive parameter, $q$. This extension enables us to predict possible experimental tests for the validity of this framework by expressing some observable quantities in terms of the $q$ averages.

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•Apr 15, 2021•0 citations
The traditional basis of description of many-particle systems in terms of Green functions is here generalized to the case when the system is nonextensive, by incorporating the Tsallis form of the density matrix indexed by a nonextensive parameter q. This is accomplished by expressing the many-particle q Green function in terms of a parametric contour integral over a kernel multiplied by the usual grand canonical Green function which now depends on this parameter. We study one- and two-particle Green functions in detail. From the one-particle Green function, we deduce some experimentally observable quantities such as the one-particle momentum distribution function and the one-particle energy distribution function. Special forms of the two-particle Green functions are related to physical dynamical structure factors, some of which are studied here. We deduce different forms of sum rules in the q formalism. A diagrammatic representation of the q Green functions similar to the traditional ones follows because the equations of motion for both of these are formally similar. Approximation schemes for one-particle q Green functions such as Hartree and Hartree-Fock schemes are given as examples. This extension enables us to predict possible experimental tests for the validity of this framework by expressing some observable quantities in terms of the q averages.
The traditional basis of description of the many-particle systems in terms of the Green functions is here generalized when the system is nonextensive by incorporating the Tsallis form of the density matrix, indexed by a nonextensive parameter, qqq. This extension enables us to predict possible experimental tests for the validity of this framework by expressing some observable quantities in terms of the qqq averages.
We extend the formalism of the thermodynamic two-time Green's functions to nonextensive quantum statistical mechanics. Working in the optimal Lagrangian multiplier representation, the q -spectral properties and the methods for a direct calculation of the two-time q Green's functions and the related q -spectral density ( q measures the nonextensivity degree) for two generic operators are presented in strict analogy with the extensive (q=1) counterpart. Some emphasis is devoted to the nonextensive version of the less known spectral density method whose effectiveness in exploring equilibrium and transport properties of a wide variety of systems has been well established in conventional classical and quantum many-body physics. To check how both the equations of motion and the spectral density methods work to study the q -induced nonextensivity effects in nontrivial many-body problems, we focus on the equilibrium properties of a second-quantized model for a high-density Bose gas with strong attraction between particles for which exact results exist in extensive conditions. Remarkably, the contributions to several thermodynamic quantities of the q -induced nonextensivity close to the extensive regime are explicitly calculated in the low-temperature regime by overcoming the calculation of the q grand-partition function.
This is the first of a series of papers dealing with many-particle systems from a unified, nonperturbative point of view. It contains derivations and discussions of various field-theoretical techniques which will be applied in subsequent papers. In a short introduction the general method of approach is summarized, and its relationship to other field-theoretic problems indicated. In the second section the macroscopic properties of the spectra of many-particle systems are described. Asymptotic evaluations are performed which characterize these macroscopic features in terms of intensive parameters, and the relationship of these parameters to thermodynamics is discussed. The special characteristics of the ground state are shown to follow as a limiting case of the asymptotic evaluations. The third section is devoted to the time-dependent field correlation functions, or Green's functions, which describe the microscopic behavior of a multiparticle system. These functions are defined, and related to intensive macroscopic variables when the energy and number of particles are large. Spectral representations and other properties of various one-particle Green's functions are derived. In the fourth section the treatment of non-equilibrium processes is considered. As a particular example, the electromagnetic properties of a system are expressed in terms of the special two-particle Green's function which describes current correlation. The discussion yields specifically a fluctuation-dissipation theorem, a sum rule for conductivity, and certain dispersion relations. The fifth section deals with the differential equations which determine the Green's functions. The boundary conditions that characterize the Green's function equations are exhibited without reference to adiabatic decoupling. A method for solving the equations approximately, by treating the correlations among successively larger numbers of particles, is considered. The first approximation in this sequence is shown to yield a generalized Hartree-like equation. A related, but rigorous, identity for the single-particle Green's function is then derived. A second approximation, which takes certain two-particle correlations into account, is shown to produce various additional effects: The interaction between particles is altered in a manner characterized by the intensive macroscopic parameters, and the modification and spread of the energy-momentum relation come into play. In the final section compact formal expressions for the Green's functions and other physical quantities are derived. Alternative equations and systematic approximations for the Green's functions are obtained.
For a small system at a low temperature, thermal fluctuation and quantum effect play important roles in quantum thermodynamics. Starting from micro-canonical ensemble, we generalize the Boltzmann–Gibbs statistical factor from infinite to finite systems, no matter the interactions between particles are considered or not. This generalized factor, similar to Tsallis’s q-form as a power-law distribution, has the restriction of finite energy spectrum and includes the nonextensivities of the small systems. We derive the exact expression for distribution of average particle numbers in the interacting classical and quantum nonextensive systems within a generalized canonical ensemble. This expression in the almost independent or elementary excitation quantum finite systems is similar to the corresponding ones obtained from the conventional grand-canonical ensemble. In the reconstruction for the statistical theory of the small systems, we present the entropy of the equilibrium systems and equation of total thermal energy. When we investigate the thermodynamics for the interacting nonextensive systems, we obtain the system–bath heat exchange and “uncompensated heat” which are in the thermodynamical level and independent on the detail of the system–bath coupling. For ideal finite systems, with different traps and boundary conditions, we calculate some thermodynamic quantities, such as the specific heat, entropy, and equation of state, etc. Particularly at low temperatures for the small systems, we predict some novel behaviors in the quantum thermodynamics, including internal entropy production, heat exchanges between the system and its surroundings and finite-size effects on the free energy.
Abstract The functional integral representation of the density matrix at thermal equilibrium in non-relativistic quantum mechanics (QM) with many degrees of freedom, in the grand canonical formulation is introduced. In QM, Hamiltonians H(p,q) can be also expressed in terms of creation and annihilation operators, a method adapted to the study of perturbed harmonic oscillators. In the holomorphic formalism, quantum operators act by multiplication and differentiation on a vector space of analytic functions. Alternatively, they can also be represented by kernels, functions of complex variables that correspond in the classical limit to a complex parametrization of phase space. The formalism is adapted to the description of many-body boson systems. To this formalism corresponds a path integral representation of the density matrix at thermal equilibrium, where paths belong to complex spaces, instead of the more usual position–momentum phase space. A parallel formalism can be set up to describe systems with many fermion degrees of freedom, with Grassmann variables replacing complex variables. Both formalisms can be generalized to quantum gases of Bose and Fermi particles in the grand canonical formulation. Field integral representations of the corresponding quantum partition functions are derived.