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arXiv:cond-mat/9805083 · Physical review. B, Condensed matter

Boundary and bulk phase transitions in the two-dimensional Q -state Potts model ( Q > 4 )

Ferenc Iglói, Enrico Carlon

Published Feb 1, 1999• 28 citations
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Abstract

The surface and bulk properties of the two-dimensional $Q>4$ state Potts model in the vicinity of the first-order bulk transition point have been studied by exact calculations and by density-matrix renormalization-group techniques. For the surface transition the complete analytical solution of the problem is presented in the $\stackrel{\ensuremath{\rightarrow}}{Q}\ensuremath{\infty}$ limit, including the critical and tricritical exponents, magnetization profiles, and scaling functions. We have shown in an accurate numerical study that the universality class of the surface transition is independent of the value of $Q>4.$ For the bulk transition we have numerically calculated the latent heat and the magnetization discontinuity and we have shown that the correlation lengths in the ordered and disordered phases are identical at the transition point.

DOI
10.1103/physrevb.59.3783

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The surface and bulk properties of the two-dimensional Q>4Q>4Q>4 state Potts model in the vicinity of the first-order bulk transition point have been studied by exact calculations and by density-matrix renormalization-group techniques. For the surface transition the complete analytical solution of the problem is presented in the Q\ensuremath→\ensuremath∞\stackrel{\ensuremath{\rightarrow}}{Q}\ensuremath{\infty}Q\ensuremath→​\ensuremath∞ limit, including the critical and tricritical exponents, magnetization profiles, and scaling functions. We have shown in an accurate numerical study that the universality class of the surface transition is independent of the value of Q>4.Q>4.Q>4. For the bulk transition we have numerically calculated the latent heat and the magnetization discontinuity and we have shown that the correlation lengths in the ordered and disordered phases are identical at the transition point.
Systems with a bulk first-order transition can display diverging correlation lengths close to a surface. This surface induced disordering yields a special type of surface criticality. Using extensive numerical simulations we study surface quantities in the two-dimensional Potts model with a large number of states qqq which undergoes a discontinuous bulk transition. The surface critical exponents are thereby found to depend on the value of qqq, which is in contrast to prior claims that these exponents should be universal and independent of qqq. It follows that surface-induced disordering at first-order transitions is characterized by exponents that depend on the details of the model.
We use the density matrix renormalization group (DMRG) to perform a detailed study of the critical properties of the two-dimensional QQQ state Potts model, including the magnetization and energy-density profiles, bulk and surface critical exponents, and the Casimir amplitudes. We apply symmetry breaking boundary conditions to a $L\ifmmode\times\else\texttimes\fi{}\ensuremath{\infty}$ strip and diagonalize the corresponding transfer matrix for a series of moderately large systems (L< 64)(L<~64)(L< 64) by the DMRG method. The numerically very accurate finite lattice results are then extrapolated by efficient sequence extrapolation techniques. The density profiles and the Casimir amplitudes at the critical point are found to follow precisely the conformal predictions for Q=2Q=2Q=2 and 333. Similarly, the bulk and surface critical exponents of the models are in very good agreement with the conformal and exact values: their accuracy has reached or even exceeded the accuracy of other available numerical methods. For the Q=4Q=4Q=4 model both the profiles and the critical exponents show strong logarithmic corrections, which are also studied.
\n \nUsing extensive Monte Carlo simulations, transfer matrix techniques \nand\nconformal invariance, ferromagnetic random\nq−q-q−state Potts models for 3leqle83\\le q\\le 83leqle8 are studied in the vicinity \nof the \ncritical temperature.\nIn particular the surface and bulk magnetization exponents beta1\\beta_1beta1​ \nand \nβ are found\nmonotonically increasing with q. At the critical temperature, \ndifferent \nmoments (n)\nof the magnetization profiles are calculated which are all found \nto accurately follow predictions of \nconformal invariance. The critical correlation functions \nshow multifractal behaviour, the decay exponents of the different \nmoments\nboth in the volume and at the surface, are n−n-n−dependent.\n \n\n
Many condensed matter systems, ranging from adsorbed surfaces to bulk magnets, are microscopically modelled by interacting q-state Potts spins, arrayed in d dimensions. A changeover from second-order phase transitions at q≤qc(d) to first-order transitions at q≳qc can be understood as a condensation of effect vacancies, which are patches of local disorder favored by entropy. Accordingly, the renormalization-group treatment of Potts models is within context of Potts-lattice-gas models, where critical and tricritical fixed points occur at low q, but merge and annihilate at qc. This picture has led to exact tricritical exponents in two dimensions. It is also consistent with recent experimental results on intercalated systems in three dimensions. Effective vacancies in pure Potts models have also been studied by Monte Carlo simulation. Their effective chemical potential can be controlled by a four-point interaction, which proved useful in Monte Carlo renormalization-group studies.
Critical properties of the QQQ-state Potts model for dimensions $3\ensuremath{\le}d\ensuremath{\le}6$ are calculated by means of Wilson's exact momentum-space renormalization-group equation. The scaling-field method of Golner and Riedel is used to approximate the functional differential equation by a set of 11 ordinary coupled differential equations. For $d=4\ensuremath{-}\ensuremath{\epsilon}$, lines of critical and tricritical Potts fixed points are found as functions of QQQ that annihilate as QQQ approaches a critical value ${Q}_{c}=\frac{2+{\ensuremath{\epsilon}}^{2}}{a+O({\ensuremath{\epsilon}}^{3})}$. For Q>QcQ>{Q}_{c}Q>Qc​, the Potts transition is first order. Along these fixed lines the critical and tricritical exponents (upper and lower sign, respectively) are to leading order: $\frac{1}{\ensuremath{\nu}}=2\ensuremath{-}\frac{1}{6}[\ensuremath{\epsilon}\ifmmode\pm\else\textpm\fi{}{({\ensuremath{\epsilon}}^{2}\ensuremath{-}a\ensuremath{\delta})}^{\frac{1}{2}}]$, $\frac{\ensuremath{\varphi}}{\ensuremath{\nu}}=\ensuremath{\mp}{({\ensuremath{\epsilon}}^{2}\ensuremath{-}a\ensuremath{\delta})}^{\frac{1}{2}}$, and $\ensuremath{\eta}=\frac{{[\ensuremath{\epsilon}\ifmmode\pm\else\textpm\fi{}{({\ensuremath{\epsilon}}^{2}\ensuremath{-}a\ensuremath{\delta})}^{\frac{1}{2}}]}^{2}}{216}+b\ensuremath{\delta}$, where $\ensuremath{\epsilon}=4\ensuremath{-}d$, $\ensuremath{\delta}=Q\ensuremath{-}2$, and $\ensuremath{\delta}\ensuremath{\le}{\ensuremath{\delta}}_{c}=\frac{{\ensuremath{\epsilon}}^{2}}{a}+O({\ensuremath{\epsilon}}^{3})$. While the form of the $\ensuremath{\epsilon}$ and $\ensuremath{\delta}$ dependences is exact, the coefficients aaa and bbb cannot be obtained systematically by $\ensuremath{\epsilon}$ expansion, since the upper critical dimensionality of the Potts model is six when $Q\ensuremath{\ne}2$. In our truncation, a=6.52a=6.52a=6.52 and b=0.065b=0.065b=0.065. The results have been extended to dimensions $3.4\ensuremath{\le}d\ensuremath{\lesssim}4$ by solving the renormalization-group equations numerically. The percolation limit of the Potts model, Q=1Q=1Q=1, is also investigated and the critical exponents ${\ensuremath{\nu}}^{P},{\ensuremath{\varphi}}^{P}$, and ${\ensuremath{\eta}}^{P}$ determined as functions of dimension for $3\ensuremath{\le}d\ensuremath{\le}6$.
Using Monte Carlo techniques and finite-size analysis, we investigate several two-dimensional lattice models with open edges, including the Blume-Capel model and the q=1 and 3 Potts models with vacancies. At bulk tricriticality, we find that the open edges are dominated by the vacancies when the surface coupling K(s) and the chemical potential D(s) of the vacancies assume the bulk values. When K(s) and/or D(s) is sufficiently enhanced, an edge phase transition takes place, beyond which spontaneous one-dimensional order occurs on the edges. Edge phase transitions can also be induced by a surface magnetic field H(s) . We numerically determine a number of edge critical exponents and derive phase diagrams in terms of K(s) , D(s) , and H(s) . In the low-temperature region, we observe first-order transitions when K(s) and D(s) are varied; the associated hysteresis loops of surface quantities are remarkably asymmetric. Some further insight into these edge transitions is provided by the exact equivalence of the tricritical q=1 Potts model and the Ising model.