It is shown that statistical mechanics is applicable to quantum systems with finite numbers of particles, such as complex atoms, atomic clusters, etc., where the residual two-body interaction is sufficiently strong. This interaction mixes the unperturbed shell-model basis states and produces ``chaotic'' many-body eigenstates. As a result, an interaction-induced equilibrium emerges in the system, and temperature can be introduced. However, the interaction between the particles and their finite number can lead to prominent deviations of the equilibrium occupation numbers distribution from the Fermi-Dirac shape. For example, this takes place in the cerium atom with four valence electrons, which was used to compare the theory with realistic numerical calculations.
It is shown that statistical mechanics is applicable to isolated quantum systems with finite numbers of particles, such as complex atoms, atomic clusters, or quantum dots in solids, where the residual two-body interaction is sufficiently strong. This interaction mixes the unperturbed shell-model (Hartree-Fock) basis states and produces chaotic many-body eigenstates. As a result, an interaction-induced statistical equilibrium emerges in the system. This equilibrium is due to the off-diagonal matrix elements of the Hamiltonian. We show that it can be described by means of temperature introduced through the canonical-type distribution. However, the interaction between the particles can lead to prominent deviations of the equilibrium distribution of the occupation numbers from the Fermi-Dirac shape. Besides that, the off-diagonal part of the Hamiltonian gives rise to an increase of the effective temperature of the system (statistical effect of the interaction). For example, this takes place in the cerium atom, which has four valence electrons and which is used in our work to compare the theory with realistic numerical calculations.
A theory of strongly interacting Fermi systems of a few particles is developed.At high excitation energies (a few times the single-particle level spacing) these systems are characterized by an extreme degree of complexity due to strong mixing of the shell-model-based many-particle basis states by the residual twobody interaction.This regime can be described as many-body quantum chaos.Practically, it occurs when the excitation energy of the system is greater than a few single-particle level spacings near the Fermi energy.Physical examples of such systems are compound nuclei, heavy open shell atoms (e.g.rare earths) and multicharged ions, molecules, clusters and quantum dots in solids.The main quantity of the theory is the strength function which describes spreading of the eigenstates over many-particle basis states (determinants) constructed using the shell-model orbital basis.A nonlinear equation for the strength function is derived, which enables one to describe the eigenstates without diagonalization of the Hamiltonian matrix.We show how to use this approach to calculate mean orbital occupation numbers and matrix elements between chaotic eigenstates and introduce typically statistical variables such as temperature in an isolated microscopic Fermi system of a few particles.
A theory of strongly interacting Fermi systems of a few particles is developed. At high excitation energies (a few times the single-particle level spacing) these systems are characterized by an extreme degree of complexity due to strong mixing of the shell-model-based many-particle basis states by the residual two-body interaction. This regime can be described as many-body quantum chaos. Practically, it occurs when the excitation energy of the system is greater than a few single-particle level spacings near the Fermi energy. Physical examples of such systems are compound nuclei, heavy open shell atoms (e.g. rare earths) and multicharged ions, molecules, clusters and quantum dots in solids. The main quantity of the theory is the strength function which describes spreading of the eigenstates over many-particle basis states (determinants) constructed using the shell-model orbital basis. A nonlinear equation for the strength function is derived, which enables one to describe the eigenstates without diagonalization of the Hamiltonian matrix. We show how to use this approach to calculate mean orbital occupation numbers and matrix elements between chaotic eigenstates and introduce typically statistical variables such as temperature in an isolated microscopic Fermi system of a few particles.
In this review the problem of statistical description of isolated quantum systems of interacting particles is discussed. Main attention is paid to a recently developed approach which is based on chaotic properties of compound states in the basis of non-interacting particles. In order to demonstrate the most important aspects of this approach, the matrix model of two-body random interaction between Fermi-particles has been used. Different problems have been considered such as the onset of chaos and statistical equilibrium, the relation between the structure of eigenstates and distribution of occupation numbers, the emergence of the Fermi-Dirac distribution in isolated systems of finite number of particles and many others. The application of the approach to dynamical systems with the classical limit is discussed as well.
Embedded random matrix ensembles operating in nuclear shell model spaces, with nucleons occupying a finite set of single particle orbits and interacting via a two-body interaction, form the basis for statistical shell model. With sufficiently strong interaction, the level densities in shell model spaces take close to a Gaussian form and transition strength distributions close to a bivariate Gaussian form. In practice, partitioning via spherical configurations (
m~) and angular momentum
J (also isospin where appropriate) are essential. The resulting statistical spectroscopy or statistical shell model was applied successfully in the past in some studies of nuclear level densities, orbit occupancies,
β-decay matrix elements and so on. Going beyond these, recently it is recognized that embedded ensembles, in a better approximation, generate in-fact
q-normal form (
q=1 gives Gaussian and
q=0 Wigner's semi-circle) for density of eigenvalues, bivariate
q-normal form for transition strengths and conditional
q-normal form for strength functions. These then allow us to develop statistical shell model with
q-normal forms. These new developments in embedded ensembles and statistical shell model are briefly reviewed in this paper. Also described, using some examples, is the role of the
q parameter in generating statistical properties of general quantum many-particle systems.