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arXiv:cond-mat/9708070 · The European Physical Journal B

Canonical and microcanonical ensemble approaches to Bose-Einstein condensation: The thermodynamics of particles in harmonic traps

K. C. Chase, Aram Z. Mekjian, L. Zamick

Published Mar 1, 1999• 31 citations
arXivHTMLPDF
DOI
10.1007/s100510050691

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We study fluctuations of the number of Bose condensed atoms in a weakly interacting homogeneous and trapped gases. For a homogeneous system we apply the particle-number-conserving formulation of the Bogoliubov theory and calculate the condensate fluctuations within the canonical and the microcanonical ensembles. We demonstrate that, at least in the low-temperature regime, predictions of the particle-number-conserving and traditional, nonconserving theory are identical, and lead to the anomalous scaling of fluctuations. Furthermore, the microcanonical fluctuations differ from the canonical ones by a quantity which scales normally in the number of particles, thus predictions of both ensembles are equivalent in the thermodynamic limit. We observe a similar behavior for a weakly interacting gas in a harmonic trap. This is in contrast to the trapped, ideal gas, where microcanonical and canonical fluctuations are different in the thermodynamic limit.
We discuss the exact particle number counting statistics of degenerate ideal Bose gases in the microcanonical, canonical, and grand-canonical ensemble, respectively, for various trapping potentials. We then invoke the Maxwell's Demon ensemble [Navez et el., Phys. Rev. Lett. (1997)] and show that for large total number of particles the root-mean-square fluctuation of the condensate occupation scales n0 / [T=Tc] r N s with scaling exponents r = 3=2, s = 1=2 for the3D harmonic oscillator trapping potential, and r = 1,s= 2=3 for the 3D box. We derive an explicit expression for r and s in terms of spatial dimension D and spectral index sigma of the single-particle energy spectrum. Our predictions also apply to systems where Bose-Einstein condensation does not occur. We point out that the condensate fluctuations in the microcanonical and canonical ensemble respect the principle of thermodynamic equivalence.
The choice of statistical ensemble has a measurable impact on the statistical description of Bose-Einstein condensates beyond the well-known grand canonical anomaly. We develop a segmented-contour approach for the ideal Bose gas, which refines the saddle-point approximation by including non-Gaussian corrections in the canonical and microcanonical ensembles. The method applies to a broad class of noninteracting spectra, and provides efficient access to condensate fluctuations, higher moments, and correlation functions. For a three-dimensional harmonic trap with fixed anisotropy, we find that the ratio of the maxima of the microcanonical and canonical condensate-number variances approaches the theoretically predicted asymptotic value 1−3ζ(3)2/[4ζ(2)ζ(4)]≈0.3911-3ζ(3)^2/[4ζ(2)ζ(4)]\approx 0.3911−3ζ(3)2/[4ζ(2)ζ(4)]≈0.391 only extremely slowly with increasing particle number. We also show that ensemble effects are visible in the second-order correlation function g(2)(x)g^{(2)}(x)g(2)(x) near the condensation crossover. After ballistic release from a three-dimensional harmonic trap, the time evolution of g(2)(x)g^{(2)}(x)g(2)(x) preserves the differences between statistical ensembles.