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arXiv:cond-mat/9706159 · Journal of Physics A Mathematical and General

Surface critical exponents for a three-dimensional modified spherical model

D M Danchev, J G Brankov, M E Amin

Published Aug 21, 1997• 7 citations
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Abstract

A modified three-dimensional mean spherical model with a L-layer film geometry under Neumann - Neumann boundary conditions is considered. Two spherical fields are present in the model: a surface one fixes the mean square value of the spins at the boundaries at some , and a bulk one imposes the standard spherical constraint (the mean square value of the spins in the bulk equals 1). The surface susceptibility has been evaluated exactly. For we find that is finite at the bulk critical temperature , in contrast to the recently derived value of in the case of just one global spherical constraint. The result is only recovered if , where is the dimensionless critical coupling. When , diverges exponentially as . An effective Hamiltonian is also proposed which leads to an exactly solvable model with , the value for the limit of the corresponding model.

DOI
10.1088/0305-4470/30/16/009

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arXiv:cond-mat/0212362•Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics•May 27, 2003•8 citations
A modified three-dimensional mean spherical model with a L-layer film geometry under Neumann - Neumann boundary conditions is considered. Two spherical fields are present in the model: a surface one fixes the mean square value of the spins at the boundaries at some , and a bulk one imposes the standard spherical constraint (the mean square value of the spins in the bulk equals 1). The surface susceptibility has been evaluated exactly. For we find that is finite at the bulk critical temperature , in contrast to the recently derived value of in the case of just one global spherical constraint. The result is only recovered if , where is the dimensionless critical coupling. When , diverges exponentially as . An effective Hamiltonian is also proposed which leads to an exactly solvable model with , the value for the limit of the corresponding model.
Abstract. A modified three-dimensional mean spherical model with a L-layer film geometry under Neumann-Neumann boundary conditions is considered. Two spherical fields are present in the model: a surface one fixes the mean square value of the spins at the boundaries at some ρ> 0, and a bulk one imposes the standard spherical constraint (the mean square value of the spins in the bulk equals one). The surface susceptibility χ1,1 has been evaluated exactly. For ρ = 1 we find that χ1,1 is finite at the bulk critical temperature Tc, in contrast with the recently derived value γ1,1 = 1 in the case of just one global spherical constraint. The result γ1,1 = 1 is recovered only if ρ = ρc = 2 − (12Kc) −1, where Kc is the dimensionless critical coupling. When ρ> ρc, χ1,1 diverges exponentially as T → T + c. An effective hamiltonian which leads to an exactly solvable model with γ1,1 = 2, the value for the n → ∞ limit of the corresponding O(n) model, is proposed too.
The three-dimensional mean spherical model with a L-layer film geometry, under Neumann - Neumann and Neumann - Dirichlet boundary conditions is considered. Surafce fields and are supposed to act at the surfaces bounding the system. In the case of Neumann boundary conditions a new surface critical exponent is found. It is argued that this exponent corresponds to a special (surface - bulk) phase transition in the model. The Privman - Fisher scaling hypothesis for the free energy is verified and the corresponding scaling functions for both the Neumann - Neumann and Neumann - Dirichlet boundary conditions are explicitly derived. If the layer field is applied at some distance from the Dirichlet boundary, a family of critical exponents emerges: their values depend on the exponent defining how the distance scales with the finite size of the system, and interpolate continuously between the extreme cases and .
Exact results of the finite-size behaviour of the susceptibility in three-dimensional mean spherical model films under Dirichlet–Dirichlet, Dirichlet–Neumann and Neumann–Neumann boundary conditions are presented. The corresponding scaling functions are explicitly derived and their asymptotics close to, above and below the bulk critical temperature T c are obtained. The results can be incorporated in the framework of the finite-size scaling theory where the exponent λ characterizing the shift of the finite-size critical temperature with respect to T c is smaller than 1/ν, with ν being the critical exponent of the bulk correlation length.
A detailed analysis of the finite-size effects on the bulk critical behaviour of the d -dimensional mean spherical model confined to a film geometry with finite thickness L is reported. Along the finite direction different kinds of boundary conditions are applied: periodic ( p ), antiperiodic ( a ) and free surfaces with Dirichlet ( D ), Neumann ( N ) and a combination of Neumann and Dirichlet ( ND ) on both surfaces. A systematic method for the evaluation of the finite-size corrections to the free energy for the different types of boundary conditions is proposed. The free energy density and the equation for the spherical field are computed for arbitrary d . It is found, for 2 < d < 4, that the singular part of the free energy has the required finite-size scaling form at the bulk critical temperature only for ( p ) and ( a ). For the remaining boundary conditions the standard finite-size scaling hypothesis is not valid. At d = 3, the critical amplitude of the singular part of the free energy (related to the so-called Casimir amplitude) is estimated. We obtain Δ ( p ) = −2ζ(3)/(5π) = −0.153 051..., Δ ( a ) = 0.274 543... and Δ ( ND ) = 0.019 22..., implying a fluctuation-induced attraction between the surfaces for ( p ) and repulsion in the other two cases. For ( D ) and ( N ) we find a logarithmic dependence on L .
A detailed analysis of the finite–size effects on the bulk critical behaviour of the d–dimensional mean spherical model confined to a film geometry with finite thickness L is reported. Along the finite direction different boundary conditions are applied: periodic (p), antiperiodic (a) and free surfaces with Dirichlet (D), Neumann (N) and a combination of Neumann and Dirichlet (ND) on both surfaces. A systematic method for the evaluation of the finite–size corrections to the free energy for the different types of boundary conditions is proposed. The free energy density and the equation for the spherical field are computed for arbitrary d. It is found, for 2 < d < 4, that the singular part of the free energy has the required finite–size scaling form at the bulk critical temperature only for (p) and (a). For the remaining boundary conditions the standard finite–size scaling hypothesis is not valid. At d = 3, the critical amplitude (related to the so called Casimir amplitude) is estimated. We obtain
We calculate finite-size effects of the Gaussian model in a Lx(d-1) box geometry with free boundary conditions in one direction and periodic boundary conditions in d-1 directions for 2<d<4. We also consider film geometry (L--> infinity ). Finite-size scaling is found to be valid for d<3 and d>3 but logarithmic deviations from finite-size scaling are found for the free energy and energy density at the Gaussian upper borderline dimension d*=3. The logarithms are related to the vanishing critical exponent 1-alpha-nu=(d-3)/2 of the Gaussian surface energy density. The latter has a cusplike singularity in d>3 dimensions. We show that these properties are the origin of nonscaling finite-size effects in the mean spherical model with free boundary conditions in d > or =3 dimensions. At bulk T(c), in d=3 dimensions we find an unexpected nonlogarithmic violation of finite-size scaling for the susceptibility chi approximately L3 of the mean spherical model in film geometry, whereas only a logarithmic deviation chi approximately L2 ln L exists for box geometry. The result for film geometry is explained by the existence of the lower borderline dimension d(l)=3, as implied by the Mermin-Wagner theorem, that coincides with the Gaussian upper borderline dimension d*=3. For 3<d<4 we find a power-law violation of scaling chi approximately L(d-1) at bulk T(c) for box geometry and a nonscaling temperature dependence chi(surface) approximately xi(d) of the surface susceptibility above T(c). For 2<d<3 dimensions we show the validity of universal finite-size scaling for the susceptibility of the mean spherical model with free boundary conditions for both box and film geometry and calculate the corresponding universal scaling functions for T > or =T(c).