An attempt is made to investigate the relation between (diagonal) long-range order (LRO or spontaneous magnetization in spin systems) and off-diagonal long-range order (ODLRO or long-range correlation in spin systems). It is shown that ODLRO cannot exceed LRO in ideal ferromagnets under some plausible conditions. Several kinds of long-range order and their mutual relations are also discussed in ideal ferromagnets whose total spin commutes with the Hamiltonian. It is also argued that neither LRO or ordinary ODLRO exists in the two-dimensional ferromagnetic Heisenberg model. However, a possibility is proposed that other kinds of ODLRO exist in the case of higher spin for such a system. The Heisenberg model with long-range interaction is exemplified, and it is pointed out that the total spin, instead of the total magnetization, should be taken as an order parameter in phenomenological arguments of the Heisenberg model.
The quantum phases of one-dimensional spin
s=1/2 chains are discussed for models with two parameters, frustrating exchange
g=J2>0 between second neighbors and normalized nonfrustrating power-law exchange with exponent $\ensuremath{\alpha}$ and distance dependence ${r}^{\ensuremath{-}\ensuremath{\alpha}}$. The ground state (GS) at
g=0 has a long-range order (LRO) for $\ensuremath{\alpha}<2$ and long-range spin fluctuations for $\ensuremath{\alpha}>2$. The models conserve total spin
S=SA+SB, have singlet GS for any
g, $\ensuremath{\alpha}\ensuremath{\ge}0$ and decouple at
1/g=0 to linear Heisenberg antiferromagnets on sublattices
A and
B of odd- and even-numbered sites. Exact diagonalization of finite chains gives the sublattice spin $\ensuremath{\langle}{S}_{A}^{2}\ensuremath{\rangle}$, the magnetic gap
Em to the lowest triplet state, and the excitation ${E}_{\ensuremath{\sigma}}$ to the lowest singlet with opposite inversion symmetry to the GS. An analytical model that conserves sublattice spin has a first-order quantum transition at
gc=1/4ln2 from a GS with perfect LRO to a decoupled phase with
SA=SB=0 for $g\ensuremath{\ge}4/{\ensuremath{\pi}}^{2}$ and no correlation between spins in different sublattices. The model with $\ensuremath{\alpha}=1$ has a first-order transition to a decoupled phase that closely resembles the analytical model. The bond order wave (BOW) phase and continuous quantum phase transitions of finite models with $\ensuremath{\alpha}\ensuremath{\ge}2$ are discussed in terms of GS degeneracy where ${E}_{\ensuremath{\sigma}}(g)=0$, excited state degeneracy where ${E}_{\ensuremath{\sigma}}(g)={E}_{m}(g)$, and $\ensuremath{\langle}{S}_{A}^{2}\ensuremath{\rangle}$. The decoupled phase at large frustration has nondegenerate GS for any exponent $\ensuremath{\alpha}$ and excited states related to sublattice excitations.
The confluence of quantum mechanics and complexity, which leads to the emergence of rich, exotic states of matter, motivates the extension of our concepts of quantum ordering. The twin concepts of spontaneously broken symmetry, described in terms of a Landau order parameter, and of off-diagonal long-range order (ODLRO), are fundamental to our understanding of phases of matter. In electronic matter it has long been assumed that Landau order parameters involve an even number of electron fields, with integer spin and even charge, that are bosons. On the other hand, in low-dimensional magnetism, operators are known to fractionalize so that the excitations carry spin-1/2. Motivated by experiment, mean-field theory and computational results, we extend the concept of ODLRO into the time domain, proposing that in a broken symmetry state, quantum operators can fractionalize into half-integer order parameters. Using numerical renormalization group studies we show how such fractionalized order can be induced in quantum impurity models. We then conjecture that such order develops spontaneously in lattice quantum systems, due to positive feedback, leading to a new family of phases, manifested by a coincidence of broken symmetry and fractionalized excitations that can be detected by experiment.
Off-diagonal long-range order (ODLRO) which is believed to be one characteristic of superconductivity is a quantum phenomenon not describable in classical mechanical terms. The quantum state constructed by η-pairing demonstrates ODLRO. Entanglement is a key concept of the quantum information processing and has no classical counterpart. We study the entanglement property of the η-pairing quantum state by concurrence and entropy which are two measures of the entanglement. We show that the concurrence of entanglement between one-site and the rest sites is exactly the correlation function of the ODLRO for the η-pairing state in the thermodynamic limit. So, when the η-pairing state is entangled, it demonstrates ODLRO and is thus in the superconducting phase, if it is a separable state, there is no ODLRO. In the thermodynamical limit, the entanglement between the M -site and other sites of the η-pairing state does not vanish. Other types of ODLRO of the η-pairing state are presented. We show that the behaviour of the ODLRO correlation functions is equivalent to that of the entanglement of the η-pairing state. The scaling of the entropy of the entanglement for the η-pairing state is studied.