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arXiv:cond-mat/9206007 · Physical Review Letters

New fermionic description of quantum spin liquid state

Alexei M. Tsvelik

Published Oct 5, 1992• 88 citations
arXivHTMLPDF

Abstract

A novel approach to S=1/2 antiferromagnets with strong quantum fluctuations based on the representation of spin-1/2 operators as bilinear forms of real (Majorana) fermions is suggested. This representation does not contain unphysical states and thus does not require the imposition of constraints on the fermionic Hilbert space. This property allows one to construct a simple and effective mean field theory of the spin liquid state. As an example illustrating the basic properties of this state I consider a model of Kondo lattice. It is shown that this model has a singlet ground state; elementary excitations have a spectral gap and are S=1 real (Majorana) fermions.

DOI
10.1103/physrevlett.69.2142

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A novel approach to S=1/2 antiferromagnets with strong quantum fluctuations based on the representation of spin-1/2 operators as bilinear forms of real (Majorana) fermions is suggested. This representation does not contain unphysical states and thus does not require the imposition of constraints on the fermionic Hilbert space. This property allows one to construct a simple and effective mean field theory of the spin liquid state. As an example illustrating the basic properties of this state I consider a model of Kondo lattice. It is shown that this model has a singlet ground state; elementary excitations have a spectral gap and are S=1 real (Majorana) fermions.
The fermion representation for S=12S=\frac{1}{2}S=21​ spins is generalized to spins with arbitrary magnitudes. The symmetry properties of the representation is analyzed where we find that the particle-hole symmetry in the spinon Hilbert space of S=12S=\frac{1}{2}S=21​ fermion representation is absent for S>12S>\frac{1}{2}S>21​. As a result, different path-integral representations and mean-field theories can be formulated for spin models. In particular, we construct a Lagrangian with restored particle-hole symmetry, and apply the corresponding mean-field theory to one-dimensional (1D) S=1S=1S=1 and S=3/2S=3/2S=3/2 antiferromagnetic (AFM) Heisenberg models, with results that agree with Haldane's conjecture. For a S=1S=1S=1 open chain, we show that Majorana fermion edge states exist in our mean-field theory. The generalization to spins with arbitrary magnitude SSS is discussed. Our approach can be applied to higher dimensional spin systems. As an example, we study the geometrically frustrated S=1S=1S=1 AFM on triangular lattice. Two spin liquids with different pairing symmetries are discussed: the gapped px+ipy{p}_{x}+i{p}_{y}px​+ipy​-wave spin liquid and the gapless fff-wave spin liquid. We compare our mean-field result with the experiment on NiGa2S4{\text{NiGa}}_{2}{\text{S}}_{4}NiGa2​S4​, which remains disordered at low temperature and was proposed to be in a spin-liquid state. Our fermionic mean-field theory provide a framework to study S>12S>\frac{1}{2}S>21​ spin liquids with fermionic spinon excitations.
We revisit the fermionic parton approach to S=1/2S=1/2S=1/2 quantum spin liquids with SU(2)\mathrm{SU}(2)SU(2) spin-rotation symmetry, and the associated projective symmetry group (PSG) classification. We point out that the existing PSG classification is incomplete; upon completing it, we find spin-liquid states with S=1S=1S=1 and S=0S=0S=0 Majorana fermion excitations coupled to a deconfined Z2{Z}_{2}Z2​ gauge field. The crucial observation leading us to this result is that, like space group and time-reversal symmetries, spin rotations can act projectively on the fermionic partons; that is, a spin rotation may be realized by simultaneous SU(2)\mathrm{SU}(2)SU(2) spin and gauge rotations. We show that there are only two realizations of spin rotations acting on fermionic partons: the familiar naive realization where spin rotation is not accompanied by any gauge transformation, and a single type of projective realization. We discuss the PSG classification for states with projective spin rotations. To illustrate these results, we show that there are four such PSGs on the two-dimensional square lattice. We study the properties of the corresponding states, finding that one---with gapless Fermi points---is a stable phase beyond mean-field theory. In this phase, depending on parameters, a small Zeeman magnetic field can open a partial gap for the Majorana fermion excitations. Moreover, there are nearby gapped phases supporting Z2{Z}_{2}Z2​ vortex excitations obeying non-Abelian statistics. We conclude with a discussion of various open issues, including the challenging question of where such S=1S=1S=1 Majorana spin liquids may occur in models and in real systems.
Motivated by recent experiments on the material Ba3{}_{3}3​NiSb2{}_{2}2​O9{}_{9}9​, we consider a spin-one quantum antiferromagnet on a triangular lattice with the Heisenberg bilinear and biquadratic exchange interactions and a single-ion anisotropy. Using a fermionic ``triplon'' representation for spins, we study the phase diagram within mean-field theory. In addition to a fully gapped spin-liquid ground state, we find a state where one gapless triplon mode with a Fermi surface coexists with d+idd+idd+id topological pairing of the other triplons. Despite the existence of a Fermi surface, this ground state has fully gapped bulk spin excitations. Such a state has linear in-temperature specific heat and constant in-plane spin susceptibility, with an unusually high Wilson ratio.
Due to strong geometric frustration and quantum fluctuation, the S=1/2S=1/2S=1/2 quantum Heisenberg antiferromagnet on the kagome\text{kagome}kagome lattice has long been considered as an ideal platform to realize a spin liquid (SL), a phase exhibiting fractionalized excitations without any symmetry breaking. A recent numerical study (Yan et al., e-print arXiv:1011.6114) of the Heisenberg S=1/2,kagomeS=1/2,\text{kagome}S=1/2,kagome lattice model (HKLM) shows, in contrast to earlier results, that the ground state is a singlet-gapped SL with signatures of Z2{\mathbb{Z}}_{2}Z2​ topological order. Motivated by this numerical discovery, we use the projective symmetry group to classify all 20 possible Schwinger fermion mean-field states of Z2{\mathbb{Z}}_{2}Z2​ SLs on the kagome\text{kagome}kagome lattice. Among them we found only one gapped Z2{\mathbb{Z}}_{2}Z2​ SL (which we call the ${\mathbb{Z}}_{2}[0,\ensuremath{\pi}]\ensuremath{\beta}$ state) in the neighborhood of the U(1) Dirac SL state. Since its parent state, i.e., the U(1) Dirac SL, was found [Ran et al., Phys. Rev. Lett. 98, 117205 (2007)] to be the lowest among many other candidate U(1) SLs, including the uniform resonating-valence-bond states, we propose this ${\mathbb{Z}}_{2}[0,\ensuremath{\pi}]\ensuremath{\beta}$ state to be the numerically discovered SL ground state of the HKLM.
In this paper, we generalize the fermionic representation for S=1/2S=1/2S=1/2 spins to arbitrary spins. Within a mean field theory we obtain several spin liquid states for spin S=1S=1S=1 antiferromagnets on triangular lattices, including gapless fff-wave spin liquid and topologically nontrivial px+ipy{p}_{x}+i{p}_{y}px​+ipy​ spin liquid. After considering different competing orders, we construct a phase diagram for the ${J}_{1}\ensuremath{-}{J}_{3}\ensuremath{-}K$ model. The application to recently discovered material NiGa2S4{\text{NiGa}}_{2}{\text{S}}_{4}NiGa2​S4​ is discussed.
We determine the phase diagrams of anisotropic Kitaev-Heisenberg models on the honeycomb lattice using parton mean-field theories based on different Majorana fermion representations of the S=1/2 spin operators. First, we use a two-dimensional Jordan-Wigner transformation (JWT) involving a semi-infinite snake string operator. To ensure that the fermionized Hamiltonian remains local, we consider the limit of extreme Ising exchange anisotropy in the Heisenberg sector. Second, we use the conventional Kitaev representation in terms of four Majorana fermions subject to local constraints, which we enforce through Lagrange multipliers. For both representations, we self-consistently decouple the interaction terms in the bond and magnetization channels and determine the phase diagrams as a function of the anisotropy of the Kitaev couplings and the relative strength of the Ising exchange. While both mean-field theories produce identical phase boundaries for the topological phase transition between the gapless and gapped Kitaev quantum spin liquids, the JWT fails to correctly describe the magnetic instability and finite-temperature behavior. Our results show that the magnetic phase transition is first order at low temperatures but becomes continuous above a certain temperature. At this energy scale, we also observe a finite-temperature crossover on the quantum-spin-liquid side, from a fractionalized paramagnet at low temperatures, in which gapped flux excitations are frozen out, to a conventional paramagnet at high temperatures. Published by the American Physical Society 2024