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arXiv:cond-mat/0703816

Does Fulleride Superconductivity Crossover Contain a Feshbach Resonance?

Richard H. Squire, Norman Henry March

Published Mar 30, 2007• 0 citations
arXivHTMLPDF

Abstract

The pioneering works by Eagles, Leggett, and Nozieres/Schmitt-Rink (reviewed and augmented by Randeria) emphasize that in the limits of the models studied both at T = 0 and, the cross-over from a BCS-type to a BEC-type superconductor is continuous. The BCS and BEC end points seem to be well-established. However, in the intermediate region, home to fulleride and high temperature superconductors, considerable extrapolation of the models must be done as there still is no exact theory. Yet, considerable current literature is devoted to what appears to be more singular-type phenomena such as quantum critical points, stripe formation, insulator to superconductor phase transitions, loss of validity of the Fermi liquid theory, etc. Using a connection we have made with cold atom Fermion-Boson crossover theory, we can establish that the resonance previously discussed is a result of the crossing of the Fermion band by the Boson band. While the ground and singly excited states appear to remain continuous, the collective modes due to the resonance transform the nature of the superconductivity. We discuss features of the resonance and the experimentally observed pre-formed BEC Cooper pair formation in fullerides, essential to the Boson-Fermion resonance theory. In addition some of the various singular phenomena discussed above can be put into perspective. PACS numbers: 61.48.+c, 74.20.-z, 81.05Tp

DOI
10.48550/arxiv.cond-mat/0703816

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Abstract The pioneering works by Eagles, Leggett, and Nozieres/Schmitt‐Rink [Eagles, Phys Rev, 1969, 186, 456; Leggett, In: Modern Trends in the Theory of Condensed Matter, Springer‐Verlag: Berlin, 1980; Nozieres and Schmitt‐Rink, Low Temp Phys, 1985, 59, 980] (reviewed and augmented by Randeria [Randeria, Bose‐Einstein Condensation, Cambridge University Press, Cambridge, 1995, p 255]) emphasize that in the limits of the models studied both at T = 0 and T ≠ 0, the “cross‐over” from a BCS‐type to a BEC‐type superconductor is continuous. The BCS and BEC “end points” seem to be well‐established. However, in the intermediate region—home to fulleride and high temperature superconductors—considerable extrapolation of the models must be done as there still is no exact theory. Yet, considerable current literature is devoted to what appears to be more “singular‐type phenomena” such as quantum critical points, “stripe” formation, insulator to superconductor phase transitions, loss of validity of the Fermi liquid theory, etc. Using a connection we have made with “cold” atom fermion‐boson crossover theory [Chen, Stajic, Levin, 2005, e‐print cond‐mat/0508603], we can establish that the resonance previously discussed [Squire and March, Int J Quant Chem, 2006, 106, 3343] is a result of the crossing of the fermion band by the boson band. While the ground state appears to remain continuous, the paired energy gap becomes transformed. We discuss features of the resonance and the experimentally observed pre‐formed “BEC Cooper pair” formation, essential to the boson‐fermion resonance theory. In addition some of the various singular phenomena discussed above can be put more into perspective. Finally, in both limits the relation of characteristic lengths to the inverse Fermi momentum is strongly emphasized, as is the role of the chemical potential near the pseudogap regime. © 2007 Wiley Periodicals, Inc. Int J Quantum Chem, 2007

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Quantum Phase Transition Induced by a Preformed Pair in a Boson-Fermion Model of Fulleride Superconductivity

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There continues to be enormous interest in the BCS to BEC transition as there still is no exact theory. We recently reported a revealing reinterpretation of the condensed phase Boson-Fermion Model (BFM) by comparing it to a cold atom formulation [1]. While the ground and singly excited states appear to remain continuous in all models we have examined, the collective modes contain a singularity due to a Feshbach resonance (tuned by doping) causing a breakdown of the Migdal theorem. As a result of vertex corrections, there is a fundamental change in the nature of the superconductivity due to the formation of preformed pairs as the previously suggested location [1] of a quantum critical point in the fulleride phase diagram is passed. The result is a quantum phase transition (QPT) between BCS and BEC-like (or Feshbach resonance) superconductivity (SC). We discuss features of the resonance and the role of the experimentally observed preformed pair formation in fullerides, essential to the Boson-Fermion Model (BFM), and often speculated since the work of Nozieres and Schmitt-Rink [17]. Here, we present arguments to establish a model of the preformed pair which can be favorably compared to a circular charge density wave (CDW) isolated on a fulleride molecule. The binding is much larger than a Cooper pair. The CDW seems to be stabalized by splitting of the Jahn-Teller active vibrational modes to reduce Coulomb repulsions. Our conclusions are: 1) the doping of two electrons into triply degenerate orbitals results in the experimentally observed singlet state (CDW); and 2) this CDW (preformed pair) has a dual role as doping is varied: suppression of BCS SC and enabling a Feshbach resonance form of SC.

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BEC, BCS and BCS-Bose Crossover Theories in Superconductors and Superfluids

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For the Cooper/BCS model interaction in superconductors (SCs) it is shown: a) how BCS-Bose crossover picture transition temperatures Tc, defined self-consistently by both the gap and fermion-number equations, require unphysically large couplings to differ significantly from the Tc of ordinary BCS theory defined without the number equation since here the chemical potential is assumed equal to the Fermi energy; how although ignoring either hole- or electron-Cooper-pairs in the recent "complete boson-fermion model": b) one obtains the precise BCS gap equation for all temperatures T, but c) only half the zero-temperature BCS condensation energy emerges. Results (b) and (c) are also expected to hold for neutral-fermion superfluids (SFs)--such as liquid $^3$He, neutron matter and trapped ultra-cold fermion atomic gases--where the pair-forming two-fermion interaction of course differs from the Cooper/BCS one for SCs.

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The pioneering works by Eagles, Leggett, and Nozieres/Schmitt-Rink (reviewed and augmented by Randeria) emphasize that in the limits of the models studied both at T = 0 and, the cross-over from a BCS-type to a BEC-type superconductor is continuous. The BCS and BEC end points seem to be well-established. However, in the intermediate region, home to fulleride and high temperature superconductors, considerable extrapolation of the models must be done as there still is no exact theory. Yet, considerable current literature is devoted to what appears to be more singular-type phenomena such as quantum critical points, stripe formation, insulator to superconductor phase transitions, loss of validity of the Fermi liquid theory, etc. Using a connection we have made with cold atom Fermion-Boson crossover theory, we can establish that the resonance previously discussed is a result of the crossing of the Fermion band by the Boson band. While the ground and singly excited states appear to remain continuous, the collective modes due to the resonance transform the nature of the superconductivity. We discuss features of the resonance and the experimentally observed pre-formed BEC Cooper pair formation in fullerides, essential to the Boson-Fermion resonance theory. In addition some of the various singular phenomena discussed above can be put into perspective. PACS numbers: 61.48.+c, 74.20.-z, 81.05Tp
Abstract The pioneering works by Eagles, Leggett, and Nozieres/Schmitt‐Rink [Eagles, Phys Rev, 1969, 186, 456; Leggett, In: Modern Trends in the Theory of Condensed Matter, Springer‐Verlag: Berlin, 1980; Nozieres and Schmitt‐Rink, Low Temp Phys, 1985, 59, 980] (reviewed and augmented by Randeria [Randeria, Bose‐Einstein Condensation, Cambridge University Press, Cambridge, 1995, p 255]) emphasize that in the limits of the models studied both at T = 0 and T ≠ 0, the “cross‐over” from a BCS‐type to a BEC‐type superconductor is continuous. The BCS and BEC “end points” seem to be well‐established. However, in the intermediate region—home to fulleride and high temperature superconductors—considerable extrapolation of the models must be done as there still is no exact theory. Yet, considerable current literature is devoted to what appears to be more “singular‐type phenomena” such as quantum critical points, “stripe” formation, insulator to superconductor phase transitions, loss of validity of the Fermi liquid theory, etc. Using a connection we have made with “cold” atom fermion‐boson crossover theory [Chen, Stajic, Levin, 2005, e‐print cond‐mat/0508603], we can establish that the resonance previously discussed [Squire and March, Int J Quant Chem, 2006, 106, 3343] is a result of the crossing of the fermion band by the boson band. While the ground state appears to remain continuous, the paired energy gap becomes transformed. We discuss features of the resonance and the experimentally observed pre‐formed “BEC Cooper pair” formation, essential to the boson‐fermion resonance theory. In addition some of the various singular phenomena discussed above can be put more into perspective. Finally, in both limits the relation of characteristic lengths to the inverse Fermi momentum is strongly emphasized, as is the role of the chemical potential near the pseudogap regime. © 2007 Wiley Periodicals, Inc. Int J Quantum Chem, 2007
There continues to be enormous interest in the BCS to BEC transition as there still is no exact theory. We recently reported a revealing reinterpretation of the condensed phase Boson-Fermion Model (BFM) by comparing it to a cold atom formulation [1]. While the ground and singly excited states appear to remain continuous in all models we have examined, the collective modes contain a singularity due to a Feshbach resonance (tuned by doping) causing a breakdown of the Migdal theorem. As a result of vertex corrections, there is a fundamental change in the nature of the superconductivity due to the formation of preformed pairs as the previously suggested location [1] of a quantum critical point in the fulleride phase diagram is passed. The result is a quantum phase transition (QPT) between BCS and BEC-like (or Feshbach resonance) superconductivity (SC). We discuss features of the resonance and the role of the experimentally observed preformed pair formation in fullerides, essential to the Boson-Fermion Model (BFM), and often speculated since the work of Nozieres and Schmitt-Rink [17]. Here, we present arguments to establish a model of the preformed pair which can be favorably compared to a circular charge density wave (CDW) isolated on a fulleride molecule. The binding is much larger than a Cooper pair. The CDW seems to be stabalized by splitting of the Jahn-Teller active vibrational modes to reduce Coulomb repulsions. Our conclusions are: 1) the doping of two electrons into triply degenerate orbitals results in the experimentally observed singlet state (CDW); and 2) this CDW (preformed pair) has a dual role as doping is varied: suppression of BCS SC and enabling a Feshbach resonance form of SC.
We discuss the BCS-BEC crossover in a degenerate Fermi gas of two hyperfine states interacting close to a Feshbach resonance. We show that, by including fluctuation contributions to the free energy similar to that considered by Nozières and Schmitt-Rink, the character of the superfluid phase transition continuously changes from the BCS-type to the BEC-type, as the threshold of the quasimolecular band is lowered. In the BEC regime, the superfluid phase transition is interpreted in terms of molecules associated with both the Feshbach resonance and Cooper pairing.
We theoretically investigate the superfluid properties of a two-band gas of 173Yb^{173}\mathrm{Yb}173Yb Fermi atoms with an orbital Feshbach resonance (OFR). To describe the BCS-BEC crossover region, we include superfluid fluctuations caused by interband and intraband pairing interactions associated with OFR by extending the strong-coupling theory developed by Nozi\`eres and Schmitt-Rink to the two-band case below the superfluid phase transition temperature; however, the effects of an experimentally inaccessible deep bound state are removed to model a real 173Yb^{173}\mathrm{Yb}173Yb Fermi gas near OFR. We show that the condensate fraction in the upper closed channel gradually becomes smaller than that in the lower open channel as one moves from the strong- to the weak-coupling regime, because the OFR-pairing mechanism tunes the interaction strengths by adjusting the energy difference between the two bands. However, even when the closed-channel band is much higher in energy than the open-channel band in the weak-coupling regime, the magnitude of the superfluid order parameter in the closed channel is found to be still comparable to that in the open channel. As the reason for this, we point out a pair-tunneling effect by the OFR-induced interband interaction. In addition to these superfluid quantities, we also examine collective modes, such as the Goldstone mode, the Schmid (Higgs) mode, and Leggett mode, to clarify how they appear in the spectral weights of pair-correlation functions in each band. Since the realization of a multiband superfluid Fermi gas is a crucial issue in cold Fermi gas physics, our results would contribute to the basic understanding of this type of Fermi superfluid in the BCS-BEC crossover region.
This article gives a detailed review of our current theoretical understanding of the crossover from cooperative Cooper pairing to independent bound-state formation and Bose–Einstein condensation in Fermi systems with increasing attractive interactions. Introduction There are two well-known paradigms for understanding the phenomena of superconductivity and superfluidity: (I) BCS theory [1], in which the normal state is a degenerate Fermi liquid that undergoes a pairing instability at a temperature T c ≪ ε f , the degeneracy scale. The formation of Cooper pairs and their condensation (macroscopic occupation of a single quantum state) both occur simultaneously at the transition temperature T c . (II) Bose–Einstein condensation (BEC) of bosons at a T c of the order of their degeneracy temperature. At a fundamental level these bosons (for example, 4 He or excitons) are invariably composite objects made up of an even number of fermions. The composite particles form at some very high temperature scale of the order of their dissociation temperature T dissoc , and these “pre-formed” bosons then condense at the BEC T c ≪ T dissoc . In most cases of experimental interest the system under consideration clearly falls into one category or the other. For instance, 3 He is a Fermi superfluid described by (I) whereas 4 He is a Bose superfluid (II). Essentially all cases of superconductivity in metals that we understand reasonably well are much closer to (I) than to (II), as evidenced by the existence of fermionic quasiparticles above T c .
For the Cooper/BCS model interaction in superconductors (SCs) it is shown: a) how BCS-Bose crossover picture transition temperatures Tc, defined self-consistently by both the gap and fermion-number equations, require unphysically large couplings to differ significantly from the Tc of ordinary BCS theory defined without the number equation since here the chemical potential is assumed equal to the Fermi energy; how although ignoring either hole- or electron-Cooper-pairs in the recent "complete boson-fermion model": b) one obtains the precise BCS gap equation for all temperatures T, but c) only half the zero-temperature BCS condensation energy emerges. Results (b) and (c) are also expected to hold for neutral-fermion superfluids (SFs)--such as liquid 3^33He, neutron matter and trapped ultra-cold fermion atomic gases--where the pair-forming two-fermion interaction of course differs from the Cooper/BCS one for SCs.