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arXiv:cond-mat/0611394 · Physical Review Letters

Quantum Phase Transitions of Polar Molecules in Bilayer Systems

Daw-Wei Wang

Published Feb 7, 2007• 58 citations
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Abstract

We investigate the quantum phase transitions of bosonic polar molecules in a two-dimensional double layer system. We show that an interlayer bound state of dipoles (dimers) can be formed when the dipole strength is above a critical value, leading to a zero-energy resonance in the interlayer s-wave scattering channel. In the positive detuning side of the resonance, the strong repulsive interlayer pseudopotential can drive the system into a maximally entangled state, where the wave function is a superposition of two states that have all molecules in one layer and none in the other. We discuss how the zero-energy resonance, dimer states, and the maximally entangled state can be measured in time-of-flight experiments.

DOI
10.1103/physrevlett.98.060403

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We investigate the quantum phase transitions of bosonic polar molecules in a two-dimensional double layer system. We show that an interlayer bound state of dipoles (dimers) can be formed when the dipole strength is above a critical value, leading to a zero-energy resonance in the interlayer s-wave scattering channel. In the positive detuning side of the resonance, the strong repulsive interlayer pseudopotential can drive the system into a maximally entangled state, where the wave function is a superposition of two states that have all molecules in one layer and none in the other. We discuss how the zero-energy resonance, dimer states, and the maximally entangled state can be measured in time-of-flight experiments.
Recent experimental progress in producing ultracold polar molecules with a net electric dipole moment opens up possibilities for realizing quantum phases governed by the long-range and anisotropic dipole-dipole interactions. In this work we predict the existence of experimentally observable broken-symmetry states with spontaneous interlayer coherence in cold polar molecule bilayers. These exotic states, which are manifestations of collective bilayer quantum entanglement, appear due to strong repulsive interlayer interactions and exhibit properties of superfluids, ferromagnets, and excitonic condensates.
The exploration of cold polar molecules in different geometries is a rapidly developing experimental and theoretical pursuit. Recently, the implementation of optical lattices has enabled confinement in stacks of planes, the number of which is also controllable. Here we consider the bound state structure of two polar molecules confined in two adjacent planes as function of the polarization angle of the dipole moment of the molecules. We prove analytically and present numerical evidence for the existence of bound states for arbitrary dipole moments and polarization directions in this two-dimensional geometry. The spatial structure of the bound states is dominated by two-dimensional s- and p-waves, where the latter exceeds 40 percent over a large range of polarization angles for intermediate or strong dipole strength. Finally, we consider the influence of the dimer bound states on the potential many-body ground-state of the system.
We investigate the quantum and thermal phase diagram of fermionic polar molecules loaded in a bilayer trapping potential with perpendicular dipole moment. We use both a BCS-theory approach that is most reliable at weak coupling and a strong-coupling approach that considers the two-body bound dimer states with one molecule in each layer as the relevant degree of freedom. The system ground state is a Bose-Einstein condensate (BEC) of dimer bound states in the low-density limit and a paired superfluid (BCS) state in the high-density limit. At zero temperature, the intralayer repulsion is found to broaden the regime of BCS-BEC crossover and can potentially induce system collapse through the softening of roton excitations. The BCS theory and the strongly coupled dimer picture yield similar predictions for the parameters of the crossover regime. The Berezinskii-Kosterlitz-Thouless transition temperature of the dimer superfluid is also calculated. The crossover can be driven by many-body effects and is strongly affected by the intralayer interaction which was ignored in previous studies.
We study the ground state of a bilayer system of dipolar bosons with dipoles oriented by an external field perpendicularly to the two parallel planes. By decreasing the interlayer distance, for a fixed value of the strength of the dipolar interaction, the system undergoes a quantum phase transition from an atomic to a pair superfluid. We investigate the excitation spectrum on both sides of this transition by using two microscopic approaches. Quantum Monte Carlo methods are employed to obtain the static structure factors and intermediate scattering functions in imaginary time. The dynamic response is calculated using both the correlated basis functions (CBF) method and the approximate inversion of the Laplace transform of the quantum Monte Carlo imaginary time data. In the atomic phase, both the density and spin excitations are gapless. However, in the pair-superfluid phase a gap opens in the excitation energy of the spin mode. For small separation between layers, the minimal spin excitation energy equals the binding energy of a dimer and is twice the gap value.
We consider fermionic polar molecules in a bilayer geometry where they are oriented perpendicularly to the layers, which permits both low inelastic losses and superfluid pairing. The dipole-dipole interaction between molecules of different layers leads to the emergence of interlayer superfluids. The superfluid regimes range from BCS-like fermionic superfluidity with a high Tc to Bose-Einstein (quasi-)condensation of interlayer dimers, thus exhibiting a peculiar BCS-Bose-Einstein condensation crossover. We show that one can cover the entire crossover regime under current experimental conditions.
Ultracold Fermi molecules lying in 2D square optical lattices bilayers with its dipole moment perpendicularly aligned to the layers, having interlayer finite range s‐wave interactions, are shown to form superfluid phases, both, in the Bardeen, Cooper and Schrieffer (BCS) regime of Cooper pairs, and in the condensate regime of bound dimeric molecules. We demonstrate this result using a functional integral scheme within the Ginzburg‐Landau theory. For the deep Berezinskii‐Kosterlitz‐Thouless (BKT) phase transition, we predict critical temperatures around 5nK and 20nK for 23Na40K and OH molecules, which are within reach of current experiments [J. W. Park, S. Will and M. Zwierlein, Phys. Rev. Lett. 114, 205302 (2015)]. image