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arXiv:cond-mat/0610412 · Physical Review A

Bose-Einstein-condensation temperature of a gas of weakly dissociated diatomic molecules

Lars Melwyn Jensen, H. Mäkelä, C. J. Pethick

Published Mar 15, 2007• 7 citations
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Abstract

We consider the properties of a gas of bosonic diatomic molecules in the limit when few of the molecules are dissociated. Taking into account the effects of dissociation and scattering among molecules and atoms, we calculate the dispersion relation for a molecule, and the thermal depletion of the condensate. We calculate the dependence of the Bose-Einstein-condensation (BEC) temperature of a uniform gas on the atom-atom scattering length, and conclude that, for a broad Feshbach resonance, the condensation temperature increases as the molecular state becomes less strongly bound, thereby giving rise to a maximum in the transition temperature in the BEC-BCS crossover. We also argue on general grounds that, for a gas in a harmonic trap and for a narrow Feshbach resonance, the condensation temperature will decrease with increasing scattering length.

DOI
10.1103/physreva.75.033606

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We consider the properties of a gas of bosonic diatomic molecules in the limit when few of the molecules are dissociated. Taking into account the effects of dissociation and scattering among molecules and atoms, we calculate the dispersion relation for a molecule, and the thermal depletion of the condensate. We calculate the dependence of the Bose-Einstein-condensation (BEC) temperature of a uniform gas on the atom-atom scattering length, and conclude that, for a broad Feshbach resonance, the condensation temperature increases as the molecular state becomes less strongly bound, thereby giving rise to a maximum in the transition temperature in the BEC-BCS crossover. We also argue on general grounds that, for a gas in a harmonic trap and for a narrow Feshbach resonance, the condensation temperature will decrease with increasing scattering length.
In this paper, we study the phase diagram of a homogeneous Bose gas with a repulsive interaction near a wide Feshbach resonance at zero temperature. The Bose-Einstein-condensation (BEC) state of atoms is a metastable state. When the scattering length aaa exceeds a critical value depending on the atom density nnn, na3>0.035n{a}^{3}>0.035na3>0.035, the molecular excitation energy is imaginary and the atomic BEC state is dynamically unstable against molecule formation. The BEC state of diatomic molecules has lower energy, where the atomic excitation is gapped and the molecular excitation is gapless. However, when the scattering length is above another critical value, na3>0.0164n{a}^{3}>0.0164na3>0.0164, the molecular BEC state becomes an unstable coherent mixture of atoms and molecules. In both BEC states, the binding energy of diatomic molecules is reduced due to the many-body effect.
Bose-Einstein condensation (BEC) of Feshbach molecules in a homogeneous Bose gas is studied at finite temperatures in a single-channel mean-field approach where the Hartree-Fock energy and pairing gap are determined self-consistently. In the molecular-BEC state, the atomic excitation is gapped and the molecular excitation is gapless. The binding energy of Feshbach molecules is shifted from the vacuum value by many-body effects. When the scattering length as{a}_{s}as​ of the atoms is negative, the system is subject to mechanical collapse due to negative compressibility. The system is stable in most regions with positive scattering lengths. However, at low temperatures near the resonance, the molecular-BEC state vanishes, and the coherent mixture of atomic and molecular BEC is subject to mechanical collapse.
We investigate strong-coupling effects on the superfluid phase transition in a gas of Fermi atoms with a Feshbach resonance. The Feshbach resonance describes a composite quasiboson that can give rise to an additional pairing interaction between the Fermi atoms. This attractive interaction becomes stronger as the threshold energy $2\ensuremath{\nu}$ of the Feshbach resonance two-particle bound state is lowered. In a recent paper, we showed that in the uniform Fermi gas, this tunable pairing interaction naturally leads to a crossover from a BCS state to a Bose-Einstein condensate (BEC) of the Nozi\`eres and Schmitt-Rink kind, in which the BCS-type superfluid phase transition continuously changes into the BEC type as the threshold energy is decreased. In this paper, we extend our previous work by including the effect of a harmonic trap potential, treated within the local-density approximation. We also give results for both weak and strong coupling to the Feshbach resonance. We show that the BCS-BEC crossover phenomenon strongly modifies the shape of the atomic density profile at the superfluid phase-transition temperature Tc,{T}_{\mathrm{c}},Tc​, reflecting the change of the dominant particles going from Fermi atoms to composite bosons. In the BEC regime, these composite bosons are shown to first appear well above Tc.{T}_{\mathrm{c}}.Tc​. We also discuss the ``phase diagram'' above Tc{T}_{\mathrm{c}}Tc​ as a function of the tunable threshold energy $2\ensuremath{\nu}.$ We introduce a characteristic temperature ${T}^{*}(2\ensuremath{\nu})$ describing the effective crossover in the normal phase from a Fermi gas of atoms to a gas of stable molecules.
Preparation of molecular quantum gas promises novel applications including quantum control of chemical reactions, precision measurements, quantum simulation and quantum information processing. Experimental preparation of colder and denser molecular samples, however, is frequently hindered by fast inelastic collisions that heat and deplete the population. Here we report the formation of two-dimensional Bose-Einstein condensates (BECs) of spinning g−g-g−wave molecules by inducing pairing interactions in an atomic condensate. The trap geometry and the low temperature of the molecules help reducing inelastic loss to ensure thermal equilibrium. We determine the molecular scattering length to be +220(30)+220(30)+220(30)~Bohr and investigate the unpairing dynamics in the strong coupling regime. Our work confirms the long-sought transition between atomic and molecular condensates, the bosonic analog of the BEC-BCS (Bardeen-Cooper-Schieffer superfluid) crossover in a Fermi gas.
We show that in an atomic Fermi gas near a Feshbach resonance the crossover between a Bose-Einstein condensate of diatomic molecules and a Bose-Einstein condensate of Cooper pairs occurs at positive detuning, i.e., when the molecular energy level lies in the two-atom continuum. We determine the crossover temperature as a function of the applied magnetic field and find excellent agreement with the experiment of C. A. Regal et al. [Phys. Rev. Lett. 92, 040403 (2004)]] who has recently observed this crossover temperature.
A self-consistent theory is derived to describe the BCS--Bose-Einstein-condensate crossover for a strongly interacting Fermi gas with a Feshbach resonance. In the theory the fluctuation of the dressed molecules, consisting of both preformed Cooper pairs and ``bare'' Feshbach molecules, has been included within a self-consistent TTT-matrix approximation, beyond the Nozi\`eres and Schmitt-Rink strategy considered by Ohashi and Griffin. The resulting self-consistent equations are solved numerically to investigate the normal-state properties of the crossover at various resonance widths. It is found that the superfluid transition temperature Tc{T}_{c}Tc​ increases monotonically at all widths as the effective interaction between atoms becomes more attractive. Furthermore, a residue factor Zm{Z}_{m}Zm​ of the molecule's Green function and a complex effective mass have been determined to characterize the fraction and lifetime of Feshbach molecules at Tc{T}_{c}Tc​. Our many-body calculations of Zm{Z}_{m}Zm​ agree qualitatively well with recent measurments of the gas of 6Li^{6}\mathrm{Li}6Li atoms near the broad resonance at 834G834\phantom{\rule{0.3em}{0ex}}\mathrm{G}834G. The crossover from narrow to broad resonances has also been studied.