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arXiv:cond-mat/0507301 · Physical Review B

Frustrated ferromagnetic spin- 12 chain in a magnetic field

Д. В. Дмитриев, V. Ya. Krivnov

Published Jan 3, 2006• 55 citations
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Abstract

We study the ground state properties of the Heisenberg spin-$\frac{1}{2}$ chain with ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor interactions using two approximate methods. One of them is the Jordan-Wigner mean-field theory and another approach is based on the transformation of spin operators to Bose ones and on the variational treatment of bosonic Hamiltonian. Both approaches give close results for the ground state energy and the magnetization curve at $T=0$. It is proved that quantum fluctuations change the classical critical exponents in the vicinity of the transition point from the ferromagnetic to the singlet ground state. The magnetization processes display a different behavior in the regions near and far from the transition point. The relation of the obtained results to the experimental magnetization curve in ${\mathrm{Rb}}_{2}{\mathrm{Cu}}_{2}{\mathrm{Mo}}_{3}{\mathrm{O}}_{12}$ is discussed.

DOI
10.1103/physrevb.73.024402

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We study the ground state properties of the Heisenberg spin-12\frac{1}{2}21​ chain with ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor interactions using two approximate methods. One of them is the Jordan-Wigner mean-field theory and another approach is based on the transformation of spin operators to Bose ones and on the variational treatment of bosonic Hamiltonian. Both approaches give close results for the ground state energy and the magnetization curve at T=0T=0T=0. It is proved that quantum fluctuations change the classical critical exponents in the vicinity of the transition point from the ferromagnetic to the singlet ground state. The magnetization processes display a different behavior in the regions near and far from the transition point. The relation of the obtained results to the experimental magnetization curve in Rb2Cu2Mo3O12{\mathrm{Rb}}_{2}{\mathrm{Cu}}_{2}{\mathrm{Mo}}_{3}{\mathrm{O}}_{12}Rb2​Cu2​Mo3​O12​ is discussed.
The one-dimensional quantum spin-1/2 model with nearest-neighbor ferromagnetic and next-nearest-neighbor antiferromagnetic interaction is considered. The Hamiltonian is firstly rewritten in a form with rotated spin operators, then bosonized by using the linear spin wave approximation and then treated by using the Green function approach. An integral expression of the quantum correction to the classical ground state energy is derived. The critical behavior of the ground state energy in the vicinity of the transition point from the ferromagnetic to the singlet ground state is analyzed by numerical calculation and the result is −8γ 2 .
The one-dimensional quantum spin-1/2 model with nearest-neighbor ferromagnetic and next-nearest-neighbor antiferromagnetic interaction is considered. The Hamiltonian is first bosonized by using the linear spin wave approximation, and then is treated by using the Green's function approach. An integral expression of the quantum correction to the classical ground state energy is derived. The critical behavior of the ground state energy in the vicinity of the transition point from the ferromagnetic to the singlet ground state is analyzed by numerical calculation, and the result is −8γ2-8γ^2−8γ2.
The properties of the ferromagnetic frustrated spin-SSS one-dimensional Heisenberg model in the vicinity of the transition point from the ferromagnetic to the singlet ground state are studied using the perturbation theory (PT) in small parameter characterizing the deviation from the transition point. The critical exponents defining the behavior of the ground-state energy and spin correlation functions are determined using scaling estimates of infrared divergencies of the PT. It is shown that the quantum fluctuations for s=1∕2s=1∕2s=1∕2 are sufficiently strong to change the classical critical exponents, while for spin systems with $s\ensuremath{\geqslant}1$ the critical exponents remain classical. The dimerization in the singlet phase near the transition point is discussed.
The frustrated ferromagnetic spin-1∕21∕21∕2 Heisenberg chain is studied by means of a low-energy field theory as well as the density-matrix renormalization group and exact diagonalization methods. First, we study the ground-state phase diagram in a magnetic field and find an ``even-odd'' (EO) phase characterized by bound pairs of magnons in the region of two weakly coupled antiferromagnetic chains. A jump in the magnetization curves signals a first-order transition at the boundary of the EO phase, but otherwise the curves are smooth. Second, we discuss thermodynamic properties at zero field, where we confirm a double-peak structure in the specific heat for moderate frustrating next-nearest-neighbor interactions.
The ground state phase diagram of the frustrated ferromagnetic spin- chain is investigated using the exact diagonalization technique. It is shown that there is a jump in the spontaneous magnetization and the ground state of the system undergoes a phase transition from a ferromagnetic phase to a phase with dimer ordering between next-nearest-neighbor spins. Near the quantum transition point, the critical behavior of the ground state energy is analyzed numerically. Using a practical finite-size scaling approach, the critical exponent of the ground state energy is computed. Our numerical results are in good agreement with the results obtained with other theoretical approaches.
We study the ground-state (GS) properties of the frustrated spin-12\frac{1}{2}21​ J1{J}_{1}J1​--J2{J}_{2}J2​--J3{J}_{3}J3​ Heisenberg model on the two-dimensional honeycomb lattice with ferromagnetic nearest-neighbor (${J}_{1}=\ensuremath{-}1$) exchange and frustrating antiferromagnetic next-nearest-neighbor (J2>0{J}_{2}>0J2​>0) and next-next-nearest-neighbor (J3>0{J}_{3}>0J3​>0) exchanges, for the case J3=J2{J}_{3}={J}_{2}J3​=J2​. We use the coupled-cluster method implemented to high orders of approximation, complemented by the Lanczos exact diagonalization of a large finite lattice with 32 sites, in order to calculate the GS energy, magnetic order parameter, and spin-spin correlation functions. In one scenario we find a quantum phase transition point between regions characterized by ferromagnetic order and a form of antiferromagnetic (``striped'') collinear order at ${J}_{2}^{c}\ensuremath{\approx}0.1095\ifmmode\pm\else\textpm\fi{}0.0005$, which is below the corresponding hypothetical transition point at J2cl=17{J}_{2}^{\mathrm{cl}}=\frac{1}{7}J2cl​=71​ ($\ensuremath{\approx}0.143$) for the classical version of the model, in which we momentarily ignore the intervening noncollinear spiral phase in the region 110<J2<15\frac{1}{10}<{J}_{2}<\frac{1}{5}101​<J2​<51​. Hence we see that quantum fluctuations appear to stabilize somewhat the collinear antiferromagnetic order in preference to the ferromagnetic order in this model. We compare results for the present ferromagnetic case (with ${J}_{1}=\ensuremath{-}1$) to previous results for the corresponding antiferromagnetic case (with J1=+1{J}_{1}=+1J1​=+1). The magnetic order parameter is found to behave similarly for the ferromagnetic and the antiferromagnetic models for large values of the frustration parameter J2{J}_{2}J2​. However, there are considerable differences in the behavior of the order parameters for the two models for ${J}_{2}/|{J}_{1}|\ensuremath{\lesssim}0.6$. For example, the quasiclassical collinear magnetic long-range order for the antiferromagnetic model (with J1=+1{J}_{1}=+1J1​=+1) breaks down at ${J}_{2}^{{c}_{2}}\ensuremath{\approx}0.60$, whereas the ``equivalent'' point for the ferromagnetic model (with ${J}_{1}=\ensuremath{-}1$) occurs at ${J}_{2}^{c}\ensuremath{\approx}0.11$. Unlike in the antiferromagnetic model (with J1=+1{J}_{1}=+1J1​=+1), where a plaquette valence-bond crystal phase intrudes between the two corresponding quasiclassical antiferromagnetic phases (with N\'eel and striped order) for J2c1<J2<J2c2{J}_{2}^{{c}_{1}}<{J}_{2}<{J}_{2}^{{c}_{2}}J2c1​​<J2​<J2c2​​, with ${J}_{2}^{{c}_{1}}\ensuremath{\approx}0.47$, we find no clear indications at all in the ferromagnetic model for an intermediate magnetically disordered phase between the corresponding phases exhibiting ferromagnetic and striped order. Instead the evidence for the ferromagnetic model (with ${J}_{1}=\ensuremath{-}1$) points to one of two scenarios: either there is a direct first-order transition between the two magnetically ordered phases, as mentioned above; or there exists an intervening phase between them in the very narrow range $0.10\ensuremath{\lesssim}{J}_{2}\ensuremath{\lesssim}0.12$, which is probably a remnant of the spiral phase that exists in the classical counterpart of the model over the larger range 110<J2<15\frac{1}{10}<{J}_{2}<\frac{1}{5}101​<J2​<51​.